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Nonionic Tenside Ligands and its Application in Biphasic Catalysis

Dedicated to Professor B. Fell on the occasion of his 75th birthday
  • Jin Zilin , Feng Cuilan and Wang Yanhua
Published/Copyright: May 8, 2013
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Tenside Surfactants Detergents
From the journal Tenside Surfactants Detergents Volume 41 Issue 6

Abstract

This review article mainly surveys our research results of biphasic catalysis with nonionic tenside ligands. Emphasis is given to the synthesis and property of cloud point of the nonionic tenside ligands, the general principles of thermoregulated phase-transfer catalysis (TRPTC) and thermoregulated phase-separable catalysis (TPSC). It also explores the applications of TRPTC and TPSC in the hydroformylation of higher olefins and CO selective reduction of nitroarenes. The introduction of TRPTC to biphasic systemis free from the shortcomings of classical aqueous/organic two-phase catalysis, in which the application scope is restrained by the water solubility of the organic substrate. The biphasic catalysis with nonionic tenside ligands was characterized by homogeneous catalysis coupled with convenient biphasic separation.

Kurzfassung

In dieser Übersichtsarbeit wird über die Forschungsergebnisse zur Zweiphasenkatalyse unter Einsatz von Übergangsmetallkomplexkatalysatoren mit nichtionischen Tensidphosphanliganden berichtet. Besondere Aufmerksamkeit wird dabei der Synthese und dem Löslichkeitsverhalten (Trübungspunkt) der nichtionischen Tensidliganden sowie den allgemeinen Prinzipien der so bezeichneten temperaturgesteuerten Phasentransferkatalyse (TRPTC) und der von temperaturgesteuerten Übergangsmetall-Niotensidphosphan-Komplexkatalysatoren (TPSC) gewidmet. Am Beispiel der Hydroformulierung höhermolekularer Olefine sowie der selektiven Reduktion von Nitroaromaten werden die Anwendungsmöglichkeiten der TRPTC- und der TPSC-Methode aufgezeigt. Mittels der TRPTC-Methode werden die Nachteile der klassischen Zweiphasenkatalyse in wässrig-organischen Systemen, die auf wasserlösliche organische Substrate beschränkt ist, überwunden. Niotensidphosphanliganden koppeln also den “normalen” Verlauf der Homogenkatalyse im einphasigen System mit der einfachen, temperaturgesteuerten Abscheidung des Katalysatorsystems durch Phasentrennung, bzw. Ausfällung.

Keywords:: Nonionic tenside ligands; Thermoregulated phase-transfer catalysis; Thermoregulated phase-separable catalysis; Hydroformylation of higher olefins
Schlüsselwörter: Nichtionische Tensidphosphanliganden; temperaturgesteuerte Phasentransferkatalyse; temperaturgesteuerter Übergangsmetall-Niotensidphosphan-Komplexkatalysator; Hydroformulierung höhermolekularer Olefine
1Prof. Dr. Zilin Jin, State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116012, P.R. China, Tel.: (+86)41–88 99 38 54, Fax: (+86)41–88 99 38 54, E-mail:

Zilin Jin, born in 1936 in Suzhou/China, studied macromolecular chemistry at the Dalian University of Technology (DUT). He received his PhD in 1981 under the guidance of professor B. Fell at the Institute fuer Technische und Petrolchemie at the RWTH Aachen. In 1984 he accepted the position of Professor and vice president of the school of Chemical Engineering at the DUT. Since 1994 he is professor at State Key Laboratory of Fine Chemicals. His research activities include homogeneous and biphasic catalysis, carbonylation and ethoxylation. He is the author around 100 pubilcations. His scientific achievement have recently been recognized with the “nature science award” of the ministry of education, China.

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Received: 2004-9-28
Published Online: 2013-05-08
Published in Print: 2004-12-01

© 2004, Carl Hanser Publisher, Munich

Articles in the same Issue

  1. Contents/Inhalt
  2. Contents
  3. Abstracts
  4. Abstracts
  5. Application
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  7. Detergent Ingredient
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https://doi.org/10.3139/113.100231
Keywords for this article
Nonionic tenside ligands; Thermoregulated phase-transfer catalysis; Thermoregulated phase-separable catalysis; Hydroformylation of higher olefins

Articles in the same Issue

  1. Contents/Inhalt
  2. Contents
  3. Abstracts
  4. Abstracts
  5. Application
  6. Nonionic Tenside Ligands and its Application in Biphasic Catalysis
  7. Detergent Ingredient
  8. Synthesis of δ Layered Sodium Disilicate with High Framework Stability
  9. Novel Surfactants
  10. Cleavable Ortho Ester Type Surfactants
  11. GDCH Special Group Meeting
  12. Development and Analytic of Odor Absorber
  13. Enzymatic Production of Care Specialties Based on Fatty Acid Esters
  14. Are Oxygen Demands Relevant for Today's Environmental Assessment of Detergents?
  15. 30th Anniversary of the Expert Group Detergent Chemistry: From an Isolated Problem Solving to Sustainable Responsibility
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