Microwave-assisted oxidation of alcohols by hydrogen peroxide catalysed by tetrabutylammonium decatungstate
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Mateusz Galica
,
Wiktor Kasprzyk
Abstract
This work deals with catalytic activity of tetrabutylammonium decatungstate(VI) in the oxidation of selected alcohols with hydrogen peroxide as an oxidant using 1,2-dichloroethane/water or acetonitrile/water as a solvent system. Different forms of heating were compared. The highest conversions of substrates were achieved in the two phase system acetonitrile/water using microwave irradiation combined with elevated pressure. Finally, optimum parameters for these reactions in a microwave pressurised reactor were established and discussed.
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© 2013 Institute of Chemistry, Slovak Academy of Sciences
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Articles in the same Issue
- Evaluation of waste products in the synthesis of surfactants by yeasts
- Investigation of CO2 and ethylethanolamine reaction kinetics in aqueous solutions using the stopped-flow technique
- Alkali pre-treatment of Sorghum Moench for biogas production
- Modelling of kinetics of microbial degradation of simulated leachate from tobacco dust waste
- Model predictive control-based robust stabilization of a chemical reactor
- Decomposition of meta- and para-phenylphenol during ozonation process
- Treatment of effluents from a membrane bioreactor by nanofiltration using tubular membranes
- Zeolite and potting soil sorption of CO2 and NH3 evolved during co-composting of grape and tobacco waste
- Liquid-solid equilibrium for the NaCl-NaHCO3-Na2CO3-H2O system at 45°C. Validation of mixed solvent electrolyte model
- Investigation of turbulent flow field in a Kenics static mixer by Laser Doppler Anemometry
- Effect of flow-rate on ethanol separation in membrane distillation process
- Preparation of aluminium ammonium calcium phosphates using microwave radiation
- Continuous dehydrochlorination of 1,3-dichloropropan-2-ol to epichlorohydrin: process parameters and by-products formation
- Preparation of sterically stabilized gold nanoparticles for plasmonic applications
- Synthesis and spectroscopic characterisation of (E)-2-(2-(9-(4-(1H-1,2,4-triazol-1-yl)butyl)-9H-carbazol-3-yl)vinyl)-3-ethylbenzo[d]thiazol-3-ium, a new ligand and potential DNA intercalator
- Microwave-assisted oxidation of alcohols by hydrogen peroxide catalysed by tetrabutylammonium decatungstate
- Dynamic shape and wall correction factors of cylindrical particles falling vertically in a Newtonian liquid
- Selective oxidation of metallic single-walled carbon nanotubes
