Continuous dialysis of sulphuric acid in the presence of zinc sulphate
-
Zdeněk Palatý
and
Helena Bendová
Abstract
Transport of sulphuric acid in the presence of zinc sulphate through the anion-exchange membrane Neosepta-AFN (Astom Corporation, Japan) was studied in a two-compartment counter-current dialyzer with single passes at steady state. The following characteristics were used to characterize the dialysis process: recovery yield of acid, rejection coefficient of salt, and permeability coefficient of the membrane. In case of the H2SO4 + ZnSO4 mixture, permeability of the membrane was quantified by four phenomenological coefficients which are functions of acid and salt concentrations in the feed. They were determined by numerical integration of differential equations describing the concentration profiles of both components in both compartments, which was combined with an optimizing procedure.
[1] Akgemci, E. G., Ersöz, M., & Atalay, T. (2004). Transport of formic acid through anion-exchange membranes by diffusion dialysis and electro-electro dialysis. Separation Science and Technology, 39, 165–184. DOI: 10.1081/SS-120027407. http://dx.doi.org/10.1081/SS-12002740710.1081/SS-120027407Search in Google Scholar
[2] Alkan-Sungur, A., & Özdural, A. R. (2009). Prediction of overall mass transfer coefficients in continuous dialyzer: comparison of pseudo steady state approximation and unsteady state solution. Desalination, 240, 64–70. DOI:10.1016/j.desal.2007.10.089. http://dx.doi.org/10.1016/j.desal.2007.10.08910.1016/j.desal.2007.10.089Search in Google Scholar
[3] Andrussow, L., & Schramm, B. (1969). Eigenschaften der Materie in ihren Aggregatzuständen, 5. Teil, Bandteil a, Transport Phänomene I (Viskozität und Diffusion). Berlin, Germany: Springer. Search in Google Scholar
[4] Elmidaoui, A., Cherif, A. T., Molenat, J., & Gavach, C. (1995). Transfer of H2SO4, Na2SO4 and ZnSO4 by dialysis through an anion exchange membrane. Desalination, 101, 39–46. DOI: 10.1016/0011-9164(95)00006-N. http://dx.doi.org/10.1016/0011-9164(95)00006-N10.1016/0011-9164(95)00006-NSearch in Google Scholar
[5] Elmidaoui, A., Molenat, J., & Gavach, C. (1991). Competitive diffusion of hydrochloric acid and sodium chloride through an acid dialysis membrane. Journal of Membrane Science, 55, 79–98. DOI: 10.1016/S0376-7388(00)82328-5. http://dx.doi.org/10.1016/S0376-7388(00)82328-510.1016/S0376-7388(00)82328-5Search in Google Scholar
[6] Jeong, J., Kim, M.-S., Kim, B.-S., Kim, S.-K., Kim, W.-B.,& Lee, J.-C. (2005). Recovery of H2SO4 from waste acid solution by a diffusion dialysis method. Journal of Hazardous Materials, 124, 230–235. DOI: 10.1016/j.jhazmat.2005.05.005. http://dx.doi.org/10.1016/j.jhazmat.2005.05.00510.1016/j.jhazmat.2005.05.005Search in Google Scholar
[7] Luo, J., Wu, C., Wu, Y., & Xu, T. (2010). Diffusion dialysis of hydrochloride acid at different temperatures using PPO-SiO2 hybrid anion exchange membranes. Journal of Membrane Science, 347, 240–249. DOI: 10.1016/j.memsci.2009.10.029. http://dx.doi.org/10.1016/j.memsci.2009.10.02910.1016/j.memsci.2009.10.029Search in Google Scholar
[8] Narębska, A., & Staniszewski, M. (2008). Separation of carboxylic acids from carboxylates by diffusion dialysis. Separation Science and Technology, 43, 490–501. DOI: 10.1080/01496390701787388. http://dx.doi.org/10.1080/0149639070178738810.1080/01496390701787388Search in Google Scholar
[9] Narębska, A., & Staniszewski, M. (1997). Separation of fermentation products by membrane techniques. I. Separation of lactic acid/lactates by diffusion dialysis. Separation Science and Technology, 32, 1669–1682. DOI: 10.1080/01496399708000727. http://dx.doi.org/10.1080/0149639970800072710.1080/01496399708000727Search in Google Scholar
[10] Narębska, A., & Warszawski, A. (1992). Diffusion dialysis. Effect of membrane composition on acid/salt separation. Separation Science and Technology, 27, 703–715. DOI:10.1080/01496399208019719. http://dx.doi.org/10.1080/0149639920801971910.1080/01496399208019719Search in Google Scholar
[11] Oh, S. J., Moon, S.-H., & Davis, T. (2000). Effects of metal ions on diffusion dialysis of inorganic acids. Journal of Membrane Science, 169, 95–105. DOI: 10.1016/S0376-7388(99)00333-6. http://dx.doi.org/10.1016/S0376-7388(99)00333-610.1016/S0376-7388(99)00333-6Search in Google Scholar
[12] Özdural, A. R., & Alkan, A. (2003). Derivation of a new explicit equation for the determination of overall mass transfer coefficients in continuous dialyzers. Journal of Membrane Science, 223, 49–57. DOI: 10.1016/S0376-7388(03)00289-8. http://dx.doi.org/10.1016/S0376-7388(03)00289-810.1016/S0376-7388(03)00289-8Search in Google Scholar
[13] Palaty, Z., & Žakova, A. (2007). Separation of HCl + FeCl2 mixture by diffusion dialysis. Separation Science and Technology, 42, 1965–1983. DOI: 10.1080/15363830701313362. http://dx.doi.org/10.1080/1536383070131336210.1080/15363830701313362Search in Google Scholar
[14] Palaty, Z., Žakova, A., & Petřík, P. (2006). A simple treatment of mass transfer data in continuous dialyzer. Chemical Engineering and Processing, 45, 806–811. DOI: 10.1016/j.cep.2006.03.009. http://dx.doi.org/10.1016/j.cep.2006.03.00910.1016/j.cep.2006.03.009Search in Google Scholar
[15] Palaty, Z., Žakova, A., & Prchal, P. (2007). Continuous dialysis of carboxylic acids. Permeability of Neosepta-AMH membrane. Desalination, 216, 345–355. DOI: 10.1016/j.desal.2006.09.029. 10.1016/j.desal.2006.09.029Search in Google Scholar
[16] Palaty, Z., Žakova, A., Stoček, P., & Bendova, H. (2008). Continuous dialysis of citric acid. Solubility and diffusivity in Neosepta-AMH membrane. Chemical and Biochemical Engineering Quaterly, 22, 169–177. Search in Google Scholar
[17] Xu, J., Fu, D., & Lu, S. (2009a). The recovery of sulphuric acid from the waste anodic aluminium oxidation solution by diffusion dialysis. Separation and Purification Technology, 69, 168–173. DOI: 10.1016/j.seppur.2009.07.015. http://dx.doi.org/10.1016/j.seppur.2009.07.01510.1016/j.seppur.2009.07.015Search in Google Scholar
[18] Xu, J., Lu, S., & Fu, D. (2009b). Recovery of hydrochloric acid from waste acid solution by diffusion dialysis. Journal of Hazardous Materials, 165, 832–837. DOI: 10.1016/j.jhazmat.2008.10.064. http://dx.doi.org/10.1016/j.jhazmat.2008.10.06410.1016/j.jhazmat.2008.10.064Search in Google Scholar
[19] Xu, T., & Yang, W. (2004). Tuning the diffusion dialysis performance by surface cross-linking of PPO anionexchange membranes—simultaneous recovery of sulfuric acid and nickel from electrolysis spent liquor of relatively low acid concentration. Journal of Hazardous Materials, 109, 157–164. DOI: 10.1016/j.jhazmat.2004.03.016. http://dx.doi.org/10.1016/j.jhazmat.2004.03.01610.1016/j.jhazmat.2004.03.016Search in Google Scholar
[20] Xu, T., & Yang, W. (2003). Industrial recovery of mixed acid (HF + HNO3) from the titanium spent leaching solutions by diffusion dialysis with a new series of anion exchange membranes. Journal of Membrane Science, 220, 89–95. DOI:10.1016/S0376-7388(03)00218-7. http://dx.doi.org/10.1016/S0376-7388(03)00188-110.1016/S0376-7388(03)00218-7Search in Google Scholar
[21] Xu, T., & Yang, W. (2001). Sulfuric acid recovery from titanium white (pigment) waste liquor using diffusion dialysis with a new series of anion exchange membranes — static runs. Journal of Membrane Science, 183, 193–200. DOI:10.1016/S0376-7388(00)00590-1. http://dx.doi.org/10.1016/S0376-7388(00)00590-110.1016/S0376-7388(00)00590-1Search in Google Scholar
[22] Yeh, H.-M. (2010). Analysis of dialysis in cross-flow parallel-plate membrane modules with feed-stream recycle for improved performance. Chemical Engineering Communications, 197, 455–465. DOI: 10.1080/00986440903288104. http://dx.doi.org/10.1080/0098644090328810410.1080/00986440903288104Search in Google Scholar
[23] Yeh, H. M. (2009). Numerical analysis of mass transfer in double-pass parallel-plate dialyzer with external recycle. Computers & Chemical Engineering, 33, 815–821. DOI:10.1016/j.compchemeng.2008.12.006. http://dx.doi.org/10.1016/j.compchemeng.2008.12.00610.1016/j.compchemeng.2008.12.006Search in Google Scholar
[24] Yeh, H. M., & Chang, Y. H. (2005). Mass transfer for dialysis through parallel-flow double-pass rectangular membrane modules. Journal of Membrane Science, 260, 1–9. DOI:10.1016/j.memsci.2005.03.003. http://dx.doi.org/10.1016/j.memsci.2005.03.00310.1016/j.memsci.2005.03.003Search in Google Scholar
[25] Yeh, H.-M., & Hsieh, M.-J. (2003). Analysis of membrane dialysis through rectangular mass exchangers. Journal of the Chinese Institute of Chemical Engineers, 34, 381–386. Search in Google Scholar
© 2011 Institute of Chemistry, Slovak Academy of Sciences
Articles in the same Issue
- Mechanisms controlling lipid accumulation and polyunsaturated fatty acid synthesis in oleaginous fungi
- Predicting retention indices of aliphatic hydrocarbons on stationary phases modified with metallocyclams using quantitative structure-retention relationships
- New SPME fibre for analysis of mequinol emitted from DVDs
- Continuous production of citric acid from raw glycerol by Yarrowia lipolytica in cell recycle cultivation
- Enhancing the production of gamma-linolenic acid in Hansenula polymorpha by fed-batch fermentation using response surface methodology
- Process characteristics for a gas—liquid system agitated in a vessel equipped with a turbine impeller and tubular baffles
- Kinetic study of pyrolysis of waste water treatment plant sludge
- Transport phenomena in an agitated vessel with an eccentrically located impeller
- Membrane extraction of 1-phenylethanol from fermentation solution
- Theoretical study on transesterification in a combined process consisting of a reactive distillation column and a pervaporation unit
- Wall effects on terminal falling velocity of spherical particles moving in a Carreau model fluid
- The effect of the physical properties of the liquid phase on the gas-liquid mass transfer coefficient in two- and three-phase agitated systems
- Effectiveness of nitric oxide ozonation
- Modelling of nanocrystalline iron nitriding process — influence of specific surface area
- Effect of CeO2 and Sb2O3 on the phase transformation and optical properties of photostable titanium dioxide
- Carnauba wax microparticles produced by melt dispersion technique
- Complexation studies of 3-substituted β-diketones with selected d- and f-metal ions
- Influence of the solvent donor number on the O/W partition ratio of Cu(II) complexes of 1,2-dialkylimidazoles
- Continuous dialysis of sulphuric acid in the presence of zinc sulphate
- Differences in affinity of arylstilbazolium derivatives to tetraplex structures
- Fast ferritin immunoassay on PDMS microchips
Articles in the same Issue
- Mechanisms controlling lipid accumulation and polyunsaturated fatty acid synthesis in oleaginous fungi
- Predicting retention indices of aliphatic hydrocarbons on stationary phases modified with metallocyclams using quantitative structure-retention relationships
- New SPME fibre for analysis of mequinol emitted from DVDs
- Continuous production of citric acid from raw glycerol by Yarrowia lipolytica in cell recycle cultivation
- Enhancing the production of gamma-linolenic acid in Hansenula polymorpha by fed-batch fermentation using response surface methodology
- Process characteristics for a gas—liquid system agitated in a vessel equipped with a turbine impeller and tubular baffles
- Kinetic study of pyrolysis of waste water treatment plant sludge
- Transport phenomena in an agitated vessel with an eccentrically located impeller
- Membrane extraction of 1-phenylethanol from fermentation solution
- Theoretical study on transesterification in a combined process consisting of a reactive distillation column and a pervaporation unit
- Wall effects on terminal falling velocity of spherical particles moving in a Carreau model fluid
- The effect of the physical properties of the liquid phase on the gas-liquid mass transfer coefficient in two- and three-phase agitated systems
- Effectiveness of nitric oxide ozonation
- Modelling of nanocrystalline iron nitriding process — influence of specific surface area
- Effect of CeO2 and Sb2O3 on the phase transformation and optical properties of photostable titanium dioxide
- Carnauba wax microparticles produced by melt dispersion technique
- Complexation studies of 3-substituted β-diketones with selected d- and f-metal ions
- Influence of the solvent donor number on the O/W partition ratio of Cu(II) complexes of 1,2-dialkylimidazoles
- Continuous dialysis of sulphuric acid in the presence of zinc sulphate
- Differences in affinity of arylstilbazolium derivatives to tetraplex structures
- Fast ferritin immunoassay on PDMS microchips
