Investigation of the solid samples evaporation from the auxiliary DC arc discharge in the atomic emission spectroscopy
-
S. Ružičková
,
L. Koller
Abstract
Efficiency of the suggested tandem technique of Marinković burner was studied in terms of the influence of the PC-controlled DC arc of the different intensities (10 A, 15 A, 20 A, 25 A) on the evaporation process. Higher intensities than 25 A did not allow to use the given experimental equipment since they cause plasma instability and periodic plasma quenching. The suggested method was evaluated by the determination of the half (t 50%) and total (t 100%) evaporation time and by determination of the signal/background ratio for the chosen elements (Al, Ca, Cr, Fe, Mg, Ni, Si, and V) in the model graphite matrix.
[1] Caroli, S., Sample Introduction in Atomic Spectroscopy, p. 225. Elsevier, Amsterdam, 1990. 10.1016/B978-0-444-88229-5.50016-7Search in Google Scholar
[2] Kántor, T., Spectrochim. Acta, Part B 56, 1523 (2001). http://dx.doi.org/10.1016/S0584-8547(01)00266-X10.1016/S0584-8547(01)00266-XSearch in Google Scholar
[3] Marinković, M. and Antonijević, V. G., Spectrochim. Acta, Part B 35, 129 (1980). http://dx.doi.org/10.1016/0584-8547(80)80060-710.1016/0584-8547(80)80060-7Search in Google Scholar
[4] Ružičková, S., Jankovská, E., Koller, L., and Matherny, M., Trans. Uni. Košice 1, 13 (2003). Search in Google Scholar
[5] Ružičková, S., Jankovská, E., Koller, L., and Matherny, M., Chem. Pap. 57, 204 (2003). Search in Google Scholar
[6] Koller, L. and Matherny, M., Magy. Kem. Foly. 108, 79 (2002). Search in Google Scholar
[7] Vainstein, E. E. and Belayev, Yu. I., Int. J. Radiat. Isotopes 4, 179 (1959). http://dx.doi.org/10.1016/0020-708X(59)90191-710.1016/0020-708X(59)90191-7Search in Google Scholar
[8] Rubeška, I., Collect. Czech. Chem. Commun. 30, 1202 (1965). Search in Google Scholar
[9] Kántor, T., Fodor, P., Youssef, Y. S., and Pungor, E., Hung. Sci. Instruments 36, 19 (1976). Search in Google Scholar
[10] Kántor, T., Fodor, P., and Pungor, E., Anal. Chim. Acta 102, 15 (1978). http://dx.doi.org/10.1016/S0003-2670(01)93457-910.1016/S0003-2670(01)93457-9Search in Google Scholar
[11] Perzel, P. R., Direct-Current Arc DCA 301. Product information. No. 96/5. Search in Google Scholar
[12] Plško, E., Pure Appl. Chem. 48, 69 (1976). Search in Google Scholar
[13] Kántor, T. and Pungor, E., Spectrochim. Acta, Part B 29, 139 (1974). http://dx.doi.org/10.1016/0584-8547(74)80018-210.1016/0584-8547(74)80018-2Search in Google Scholar
[14] Ružičková, S., Koller, L., and Matherny, M., Trans. Uni. Košice 2, 59 (2004). Search in Google Scholar
[15] Möller, H., Mazurkiewicz, H., and Nickel, H., KFA, Juel-Report, 1449 (1977). Search in Google Scholar
[16] Nickel, H., Spectrochim. Acta 21, 363 (1960). http://dx.doi.org/10.1016/0371-1951(65)80128-X10.1016/0371-1951(65)80128-XSearch in Google Scholar
© 2006 Institute of Chemistry, Slovak Academy of Sciences
Articles in the same Issue
- Chemistry for the design and better understanding of cement-based materials and composites
- Surface modifications of natural clinoptilolite-dominated zeolite for phenolic pollutant mitigation
- Flame retardant property of nanopowder aerosols toward methane
- Trace analysis of lead by anodic stripping voltammetry with collection at interdigitated microelectrodes in small-volume samples
- Investigation of the solid samples evaporation from the auxiliary DC arc discharge in the atomic emission spectroscopy
- Determination of bioavailable iron in noncontaminated Slovak soils by flame atomic absorption spectrometry
- Determination of technetium-99 in soils and radioactive wastes using ICP-MS
- Synthesis and characterization of the rare-earth complexes with salicylic acid
- Spectrophotometric determination of nickel(II) in different samples by complexation with some triazolylazo dyes
- Complexes of biologically important ligands. I. Ternary complexes of nickel(II) comprising 1,10-o-phenanthrolineazosulfonamide derivatives and alkyldithiophosphates
- Effects of Cd(II) and Zn(II) complexes with bioactive ligands on some photosynthesizing organisms
- Efficiency of a fixed-bed and a gas-lift three-column reactor for continuous production of ethanol by pectate-and alginate-immobilized Saccharomyces cerevisiae cells
- Reactions and applications of trans-1,2-epoxy-(Z,E)-cyclododeca-5,9-diene
- Dictionary of Carbohydrates. Edited by P. M. Collins. Second Edition
- In memoriam Associate Professor Ing. Vladimír Daněk, DrSc
Articles in the same Issue
- Chemistry for the design and better understanding of cement-based materials and composites
- Surface modifications of natural clinoptilolite-dominated zeolite for phenolic pollutant mitigation
- Flame retardant property of nanopowder aerosols toward methane
- Trace analysis of lead by anodic stripping voltammetry with collection at interdigitated microelectrodes in small-volume samples
- Investigation of the solid samples evaporation from the auxiliary DC arc discharge in the atomic emission spectroscopy
- Determination of bioavailable iron in noncontaminated Slovak soils by flame atomic absorption spectrometry
- Determination of technetium-99 in soils and radioactive wastes using ICP-MS
- Synthesis and characterization of the rare-earth complexes with salicylic acid
- Spectrophotometric determination of nickel(II) in different samples by complexation with some triazolylazo dyes
- Complexes of biologically important ligands. I. Ternary complexes of nickel(II) comprising 1,10-o-phenanthrolineazosulfonamide derivatives and alkyldithiophosphates
- Effects of Cd(II) and Zn(II) complexes with bioactive ligands on some photosynthesizing organisms
- Efficiency of a fixed-bed and a gas-lift three-column reactor for continuous production of ethanol by pectate-and alginate-immobilized Saccharomyces cerevisiae cells
- Reactions and applications of trans-1,2-epoxy-(Z,E)-cyclododeca-5,9-diene
- Dictionary of Carbohydrates. Edited by P. M. Collins. Second Edition
- In memoriam Associate Professor Ing. Vladimír Daněk, DrSc
