Article
Licensed
Unlicensed
Requires Authentication
The atomic structure of deuterated boyleite ZnSO4·4D2O, ilesite MnSO4·4D2O, and bianchite ZnSO4·6D2O
-
Jennifer L. Anderson
and
Ian Swainson
Published/Copyright:
April 2, 2015
Abstract
Deuterated boyleite ZnSO4⋅4D2O, was synthesized and the atomic structure, including D positions, was successfully refined in a combined histogram neutron diffraction refinement. The cell dimensions for boyleite are a = 5.9144(2), b = 13.5665(4), c = 7.8924(2) Å, and β = 90.668(2)° with space group P21/n and Z = 4. The atomic structure including D positions of the isostructural mineral ilesite, MnSO4⋅4D2O, was refined and the cell dimensions are a = 5.9753(1), b = 13.8186(3), c = 8.0461(1) Å, and β = 90.826(2)°. Deuterated bianchite ZnSO4⋅6D2O was synthesized and the atomic structure, including D positions, was successfully refined with a unit cell of a = 9.969(1), b = 7. 2441(7), c = 24.249(3) Å, and β = 98.488(5)° in space group C2/c and Z = 8. A comparison of the hydrogen bonding in M2+SO4⋅4D2O with that in M2+SO4⋅6D2O shows that bifurcated hydrogen bonds are common in the tetrahydrate sulfates but nonexistent in the hexahydrate structures. This is a result of the packing constraints of the rings of the sulfate and metal-containing octahedra in the tetrahydrates. In the hexahydrate sulfates there is no direct linkage between the sulfate and metal-containing octahedra and hydrogen bonds are optimized without packing constraints, and no bifurcated hydrogen bonds are observed.
Keywords : Bianchite; boyleite; ilesite; hexahydrite; moorhouseite; Ni-hexahydrite; rozenite; crystal-structure refinement; neutron diffraction; hydrogen bonding
Received: 2012-2-1
Accepted: 2012-7-3
Published Online: 2015-4-2
Published in Print: 2012-11-1
© 2015 by Walter de Gruyter Berlin/Boston
You are currently not able to access this content.
You are currently not able to access this content.
Articles in the same Issue
- Cation ordering over short-range and long-range scales in the MgAl2O4-CuAl2O4 series
- Blue spinel crystals in the MgAl2O4-CoAl2O4 series: Part I. Flux growth and chemical characterization
- Blue spinel crystals in the MgAl2O4-CoAl2O4 series: Part II. Cation ordering over short-range and long-range scales
- CO2 solubility in primitive martian basalts similar to Yamato 980459, the effect of composition on CO2 solubility of basalts, and the evolution of the martian atmosphere
- New structural features of the high-pressure synthetic sheet-disilicate Phase-X, K(2–x)Mg2Si2O7Hx
- Crystal structure refinements of borate dimorphs inderite and kurnakovite using 11B and 25Mg nuclear magnetic resonance and DFT calculations
- Hydrogen-bond system and dehydration behavior of the natural zeolite parthéite
- In situ dehydration behavior of zeolite-like cavansite: A single-crystal X-ray study
- LREE-redistribution among fluorapatite, monazite, and allanite at high pressures and temperatures
- A single-crystal neutron diffraction study of hambergite, Be2BO3(OH,F)
- Analyzing water contents in unexposed glass inclusions in quartz crystals
- The atomic structure of deuterated boyleite ZnSO4·4D2O, ilesite MnSO4·4D2O, and bianchite ZnSO4·6D2O
- Synthesis and crystal chemistry of Fe3+-bearing (Mg,Fe3+)(Si,Fe3+)O3 perovskite
- Mixed-layered structure formation during trans-vacant Al-rich illite partial dehydroxylation
- Structural regularities in 2M1 dioctahedral micas: The structure modeling approach
- Incorporation of Fe and Al in MgSiO3 perovskite: An investigation by 27Al and 29Si NMR spectroscopy
- In situ high-temperature Raman and FTIR spectroscopy of the phase transformation of lizardite
- Packing systematics and structural relationships of the new copper molybdate markascherite and related minerals
- On the origin of sellaite (MgF2)-rich deposits in Mg-poor environments
- Edgrewite Ca9(SiO4)4F2-hydroxyledgrewite Ca9(SiO4)4(OH)2, a new series of calcium humite-group minerals from altered xenoliths in the ignimbrite of Upper Chegem caldera, Northern Caucasus, Kabardino-Balkaria, Russia
- Whelanite, Cu2Ca6[Si6O17(OH)](CO3)(OH)3(H2O)2, an (old) new mineral from the Bawana mine, Milford, Utah
- 2M1-phlogopite from Black Hills (South Australia): The first case of configurational polytype in micas
- Oxy-chromium-dravite, NaCr3(Cr4Mg2)(Si6O18)(BO3)3(OH)3O, a new mineral species of the tourmaline supergroup
- First-principles study of self-diffusion and viscous flow in diopside (CaMgSi2O6) liquid
- Browneite, MnS, a new sphalerite-group mineral from the Zakłodzie meteorite
- Mineralogical variation of silica induced by Al and Na in hydrothermal solutions
Keywords for this article
Bianchite;
boyleite;
ilesite;
hexahydrite;
moorhouseite;
Ni-hexahydrite;
rozenite;
crystal-structure refinement;
neutron diffraction;
hydrogen bonding
Articles in the same Issue
- Cation ordering over short-range and long-range scales in the MgAl2O4-CuAl2O4 series
- Blue spinel crystals in the MgAl2O4-CoAl2O4 series: Part I. Flux growth and chemical characterization
- Blue spinel crystals in the MgAl2O4-CoAl2O4 series: Part II. Cation ordering over short-range and long-range scales
- CO2 solubility in primitive martian basalts similar to Yamato 980459, the effect of composition on CO2 solubility of basalts, and the evolution of the martian atmosphere
- New structural features of the high-pressure synthetic sheet-disilicate Phase-X, K(2–x)Mg2Si2O7Hx
- Crystal structure refinements of borate dimorphs inderite and kurnakovite using 11B and 25Mg nuclear magnetic resonance and DFT calculations
- Hydrogen-bond system and dehydration behavior of the natural zeolite parthéite
- In situ dehydration behavior of zeolite-like cavansite: A single-crystal X-ray study
- LREE-redistribution among fluorapatite, monazite, and allanite at high pressures and temperatures
- A single-crystal neutron diffraction study of hambergite, Be2BO3(OH,F)
- Analyzing water contents in unexposed glass inclusions in quartz crystals
- The atomic structure of deuterated boyleite ZnSO4·4D2O, ilesite MnSO4·4D2O, and bianchite ZnSO4·6D2O
- Synthesis and crystal chemistry of Fe3+-bearing (Mg,Fe3+)(Si,Fe3+)O3 perovskite
- Mixed-layered structure formation during trans-vacant Al-rich illite partial dehydroxylation
- Structural regularities in 2M1 dioctahedral micas: The structure modeling approach
- Incorporation of Fe and Al in MgSiO3 perovskite: An investigation by 27Al and 29Si NMR spectroscopy
- In situ high-temperature Raman and FTIR spectroscopy of the phase transformation of lizardite
- Packing systematics and structural relationships of the new copper molybdate markascherite and related minerals
- On the origin of sellaite (MgF2)-rich deposits in Mg-poor environments
- Edgrewite Ca9(SiO4)4F2-hydroxyledgrewite Ca9(SiO4)4(OH)2, a new series of calcium humite-group minerals from altered xenoliths in the ignimbrite of Upper Chegem caldera, Northern Caucasus, Kabardino-Balkaria, Russia
- Whelanite, Cu2Ca6[Si6O17(OH)](CO3)(OH)3(H2O)2, an (old) new mineral from the Bawana mine, Milford, Utah
- 2M1-phlogopite from Black Hills (South Australia): The first case of configurational polytype in micas
- Oxy-chromium-dravite, NaCr3(Cr4Mg2)(Si6O18)(BO3)3(OH)3O, a new mineral species of the tourmaline supergroup
- First-principles study of self-diffusion and viscous flow in diopside (CaMgSi2O6) liquid
- Browneite, MnS, a new sphalerite-group mineral from the Zakłodzie meteorite
- Mineralogical variation of silica induced by Al and Na in hydrothermal solutions
