Abstract
The crystal structures of herderite, CaBePO4[F0.75(OH)0.25], a = 9.7446(4), b = 7.6769(3), c = 4.7633(2) Å, β = 90.667(1)°, V = 356.31(4) Å3, P21/a, and Z = 4, from the Mogok Stone Tract, Myanmar, and hydroxyl-herderite, CaBePO4[(OH)0.52F0.48], a = 9.7615(4), b = 7.6680(3), c = 4.7853(2) Å, β = 90.184(1)°, V = 358.18(4) Å3, P21/a, and Z = 4, from the Sauberg mine, Morgenröther Zug, Ehrenfriedersdorf, Germany, have been refined to R1 indices of 1.7%, in both cases, using MoKα single-crystal X-ray diffraction data. Herderite from Mogok is associated with complex rare-element beryl-type granite pegmatite. Most herderite-series minerals are the product of late-stage processes in granite pegmatite evolution, typically of an exsolved fluid upon crystallization, and significant F-enrichment in these fluids appears to result in the domination of herderite over hydroxyl-herderite. Herderite is now documented from Mogok, Myanmar; Yichung, China; Brazil; and probably Erongo, Namibia. The pegmatites at Ehrenfriedersdorf, Germany have produced samples at the boundary between herderite and hydroxyl-herderite, if not possibly herderite as well.
© 2015 by Walter de Gruyter Berlin/Boston
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- Amorphous Materials: Properties, structure, and durability: Oxidation state of iron in hydrous phono-tephritic melts
- Amorphous materials: Properties, structure, and durability: Quantitative Raman spectroscopy: Speciation of Na-silicate glasses and melts
- Dissolution-reprecipitation of zircon at low-temperature, high-pressure conditions (Lanzo Massif, Italy)
- High-pressure behavior of gypsum: A single-crystal X-ray study
- Presence and zoning of hydrous components in leucite from the Alban Hills volcano, Rome, Italy
- Herderite from Mogok, Myanmar, and comparison with hydroxyl-herderite from Ehrenfriedersdorf, Germany
- Application of Raman spectroscopy to quantify trace water concentrations in glasses and garnets
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- A simple predictive model for the thermal expansion of AlSi3 feldspars
- New data on PGE alloy minerals from a very old collection (probably 1890s), California
- High-pressure study on lead fluorapatite
- High-pressure Al-rich hexagonal phases—What are their kin?
- Leucite at high pressure: Elastic behavior, phase stability, and petrological implications
- Thermodynamic mixing properties of Rb-K feldspars
- Demicheleite, BiSBr, a new mineral from La Fossa crater, Vulcano, Aeolian Islands, Italy
- A lattice dynamical study of the aragonite and post-aragonite phases of calcium carbonate rock
- Water in natural olivine—determined by proton-proton scattering analysis
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- Disordering of Fe2+ over octahedrally coordinated sites of tourmaline
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- The thermal behavior of richterite
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