Abstract
The mineral proportions of rocks or rock fragments in thin section can be retrieved from electron microprobe element X-ray maps using multispectral image classification software. However, different image classification algorithms can yield different inferred mineral proportions and thus deviate from the true modal mineralogy. Several image classification algorithms (implemented in the programs Erdas Imagine and Multispec) were evaluated on a very simple rock-a fragment of noritic anorthositic granulite in a thin section of lunar meteorite ALHA81005. This fragment contains only plagioclase, orthopyroxene, olivine, clinopyroxene, and chromite; each has a constant composition across the fragment. The true (reference) mineral proportions of the fragment were measured manually from the X-ray maps. Results of classification algorithms varied widely in accuracy-from ~1% to more than 15% misclassified pixels compared to the reference. The best match for this fragment comes from an unsupervised classification using the ISODATA algorithm (most minerals were placed into multiple classes, which had to be manually recombined), and the second closest match was a supervised classification using a Euclidean distance classifier. The results of supervised classifications depend strongly on the user’s selection of training areas, and small errors in defined training areas (e.g., a training area for one phase contains an inclusion of another) can produce large errors. The most common source of misclassification is “mixed pixels”-those that contain signatures from multiple phases. In this example, pixels including both plagioclase and olivine tend to be classified as clinopyroxene. Thus, mineral proportions calculated from classification of X-ray maps must be considered critically, even for simple rocks. In more complex samples, like those with more phases or with chemically zoned phases, mineral classification of X-ray maps are likely to require care and may be difficult to validate.
© 2015 by Walter de Gruyter Berlin/Boston
Articles in the same Issue
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- Direct EXAFS evidence for incorporation of As5+ in the tetrahedral site of natural andraditic garnet
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- Partitioning of trace elements among coexisting crystals, melt, and supercritical fluid during isobaric crystallization and melting
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- Hydrogen analysis in minerals by continuous-flow mass spectrometry
- Re-examination of berlinite (AlPO4) from the Cioclovina Cave, Romania
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Articles in the same Issue
- Evaluation of image classification routines for determining modal mineralogy of rocks from X-ray maps
- Atomic structure and formation mechanism of (301) rutile twins from Diamantina (Brazil)
- Significance of the depth-related transition montmorillonite-beidellite in the Bouillante geothermal field (Guadeloupe, Lesser Antilles)
- High-pressure infrared spectra of talc and lawsonite
- Proton dynamics in letovicite: Part I. Static 1H and 15N NMR MAS experiments and lineshape simulations
- Proton dynamics in letovicite: Part II. Static 2H NMR experiments and lineshape simulations
- Chemical and structural variations at augite (100) deformation twin boundaries
- Comparative compressibility and structural behavior of spinel MgAl2O4 at high pressures: The independency on the degree of cation order
- Multiple breakdown and chemical equilibrium of silicic clinopyroxene under extreme metamorphic conditions in the Kontum Massif, central Vietnam
- Direct EXAFS evidence for incorporation of As5+ in the tetrahedral site of natural andraditic garnet
- Deformation-controlled cation diffusion in tourmaline: A microanalytical study on trace elements and boron isotopes
- Scandium-45 NMR of pyrope-grossular garnets: Resolution of multiple scandium sites and comparison with X-ray diffraction and X-ray absorption spectroscopy
- Partitioning of trace elements among coexisting crystals, melt, and supercritical fluid during isobaric crystallization and melting
- Thermal diffusivity of aluminous spinels and magnetite at elevated temperature with implications for heat transport in Earth’s transition zone
- High-pressure structure and bonding in CaIrO3: The structure model of MgSiO3 post-perovskite investigated with time-of-flight neutron powder diffraction
- Application of major- and trace-element geochemistry to refine U-Pb zircon, and Sm/Nd or Lu/Hf sampling targets for geochronology of HP and UHP eclogites, Western Gneiss Region, Norway
- Measurement of U-Pb ages of uraninite and davidite by laser ablation-HR-ICP-MS
- A modeling approach to understanding the role of microstructure development on crystalsize distributions and on recovering crystal-size distributions from thin slices
- Neptunium substitution in synthetic uranophane and soddyite
- Coexistence of twisted and untwisted crystals: An impurity/structural order model with implications for agate patterns
- Intracrystalline boron isotope partitioning in illite-smectite: Testing the geothermometer
- Mineralogy of the hardpan formation processes in the interface between sulfide-rich sludge and fly ash: Applications for acid mine drainage mitigation
- Dissolution of radiation-damaged zircon in lateritic soils
- Hydrogen analysis in minerals by continuous-flow mass spectrometry
- Re-examination of berlinite (AlPO4) from the Cioclovina Cave, Romania
- Letter. Valence state partitioning of Cr between pyroxene-melt: Effects of pyroxene and melt composition and direct determination of Cr valence states by XANES. Application to Martian basalt QUE 94201 composition