Abstract
The underestimated rhenium (Re) concentration of continental crust is crucial for resolving the “missing Re puzzle” in the silicate Earth. Previous studies attributed the unknown Re reservoir in the continental crust to sulfide cumulates in the lower crust. However, the impact of aqueous fluids on Re abundance in the continental crust has been largely overlooked due to a lack of partition coefficients between fluids and silicate melts
Acknowledgments and Funding
This work is supported by the Guangdong S&T Program (2024B0303390002), the National Natural Science Foundation of China (No. 42003045) by S.X., and the Strategic Priority Research Program of the Chinese Academy of Sciences (XDB42000000).
References Cited
Ahmad, I., Richards, J.P., Pearson, D.G., Liu, J., Barnes, S-J., Jugo, P.J., Shah, M.T., Leybourne, M., and Jagoutzs, O. (2021) Fractionation of sulfide phases controls the chalcophile metal budget of arc magmas: Evidence from the Chilas complex, Kohistan arc, Pakistan. In A. Sholeh and R. Wang, Eds., Special Publications of the Society of Economic Geologists: Tectonomagmatic Influences on Metallogeny and Hydrothermal Ore Deposits: A Tribute to Jeremy P. Richards (Volume II), p. 297–310. Society of Economic Geologists.Search in Google Scholar
Bai, T. and Koster van Groos, A. (1999) The distribution of Na, K, Rb, Sr, Al, Ge, Cu, W, Mo, La, and Ce between granitic melts and coexisting aqueous fluids. Geochimica et Cosmochimica Acta, 63, 1117–1131, https://doi.org/10.1016/S0016-7037(98)00284-1.Search in Google Scholar
Barnes, J.D., Manning, C.E., Scambelluri, M., and Selverstone, J. (2018) The behavior of halogens during subduction-zone processes, The role of halogens in terrestrial and extraterrestrial geochemical processes, 545–590. Springer.Search in Google Scholar
Barth, M.G., McDonough, W.F., and Rudnick, R.L. (2000) Tracking the budget of Nb and Ta in the continental crust. Chemical Geology, 165, 197–213, https://doi.org/10.1016/S0009-2541(99)00173-4.Search in Google Scholar
Brenan, J.M. (2008) Re-Os fractionation by sulfide melt-silicate melt partitioning: A new spin. Chemical Geology, 248, 140–165, https://doi.org/10.1016/j.chemgeo.2007.09.003.Search in Google Scholar
Brumsack, H.-J. (2006) The trace metal content of recent organic carbon-rich sediments: Implications for Cretaceous black shale formation. Palaeogeography, Palaeoclimatology, Palaeoecology, 232, 344–361, https://doi.org/10.1016/j.palaeo.2005.05.011.Search in Google Scholar
Candela, P.A. and Holland, H.D. (1984) The partitioning of copper and molybdenum between silicate melts and aqueous fluids. Geochimica et Cosmochimica Acta, 48, 373–380, https://doi.org/10.1016/0016-7037(84)90257-6.Search in Google Scholar
Colin, A., Schmidt, C., Pokrovski, G.S., Wilke, M., Borisova, A.Y., and Toplis, M.J. (2020) In situ determination of sulfur speciation and partitioning in aqueous fluid-silicate melt systems. Geochemical Perspectives Letters, 14, 31–35, https://doi.org/10.7185/geochemlet.2020.Search in Google Scholar
Colodner, D. (1991) The marine geochemistry of rhenium, iridium and platinum, 273 p. Ph.D. thesis, Massachusetts Institute of Technology.Search in Google Scholar
Dadze, T.P., Kashirtseva, G.A., Novikov, M.P., and Plyasunov, A.V. (2018) Solubility of MoO3 in aqueous acid chloride-bearing solutions at 573 K. Journal of Chemical & Engineering Data, 63, 1827–1832, https://doi.org/10.1021/acs.jced.8b00151.Search in Google Scholar
Duan, X. (2014) A general model for predicting the solubility behavior of H2O-CO2 fluids in silicate melts over a wide range of pressure, temperature and compositions. Geochimica et Cosmochimica Acta, 125, 582–609, https://doi.org/10.1016/j.gca.2013.10.018.Search in Google Scholar
Duncan, M.S. and Dasgupta, R. (2014) CO2 solubility and speciation in rhyolitic sediment partial melts at 1.5–3.0 GPa – Implications for carbon flux in subduction zones. Geochimica et Cosmochimica Acta, 124, 328–347, https://doi.org/10.1016/j.gca.2013.09.026.Search in Google Scholar
Ertel, W., O’Neill, H.St.C., Sylvester, P.J., Dingwell, D., and Spettel, B. (2001) The solubility of rhenium in silicate melts: Implications for the geochemical properties of rhenium at high temperatures. Geochimica et Cosmochimica Acta, 65, 2161–2170, https://doi.org/10.1016/S0016-7037(01)00582-8.Search in Google Scholar
Esser, B.K. and Turekian, K.K. (1993) The osmium isotopic composition of the continental crust. Geochimica et Cosmochimica Acta, 57, 3093–3104, https://doi.org/10.1016/0016-7037(93)90296-9.Search in Google Scholar
Feng, L. and Li, Y. (2019) Comparative partitioning of Re and Mo between sulfide phases and silicate melt and implications for the behavior of Re during magmatic processes. Earth and Planetary Science Letters, 517, 14–25, https://doi.org/10.1016/j.epsl.2019.04.010.Search in Google Scholar
Gadd, M.G., Peter, J.M., Jackson, S.E., Yang, Z., and Petts, D. (2019) Platinum, Pd, Mo, Au and Re deportment in hyper-enriched black shale Ni-Zn-Mo-PGE mineralization, Peel River, Yukon, Canada. Ore Geology Reviews, 107, 600–614, https://doi.org/10.1016/j.oregeorev.2019.02.030.Search in Google Scholar
Gualda, G.A., Ghiorso, M.S., Lemons, R.V., and Carley, T.L. (2012) Rhyolite-MELTS: A modified calibration of MELTS optimized for silica-rich, fluid-bearing magmatic systems. Journal of Petrology, 53, 875–890, https://doi.org/10.1093/petrology/egr080.Search in Google Scholar
Guo, H. and Audétat, A. (2017) Transfer of volatiles and metals from mafic to felsic magmas in composite magma chambers: An experimental study. Geochimica et Cosmochimica Acta, 198, 360–378, https://doi.org/10.1016/j.gca.2016.11.029.Search in Google Scholar
Hauri, E.H. and Hart, S.R. (1997) Rhenium abundances and systematics in oceanic basalts. Chemical Geology, 139, 185–205, https://doi.org/10.1016/S0009-2541(97)00035-1.Search in Google Scholar
Holzheid, A., Borisov, A., and Palme, H. (1994) The effect of oxygen fugacity and temperature on solubilities of nickel, cobalt, and molybdenum in silicate melts. Geochimica et Cosmochimica Acta, 58, 1975–1981, https://doi.org/10.1016/0016-7037(94)90429-4.Search in Google Scholar
Iveson, A.A., Webster, J.D., Rowe, M.C., and Neill, O.K. (2019) Fluid-melt trace-element partitioning behaviour between evolved melts and aqueous fluids: Experimental constraints on the magmatic-hydrothermal transport of metals. Chemical Geology, 516, 18–41, https://doi.org/10.1016/j.chemgeo.2019.03.029.Search in Google Scholar
Jégo, S. and Dasgupta, R. (2014) The fate of sulfur during fluid-present melting of subducting basaltic crust at variable oxygen fugacity. Journal of Petrology, 55, 1019–1050, https://doi.org/10.1093/petrology/egu016.Search in Google Scholar
Jenner, F.E. (2017) Cumulate causes for the low contents of sulfide-loving elements in the continental crust. Nature Geoscience, 10, 524–529, https://doi.org/10.1038/ngeo2965.Search in Google Scholar
Jenner, F.E., O’Neill, H.S.C., Arculus, R.J., and Mavrogenes, J.A. (2010) The magnetite crisis in the evolution of arc-related magmas and the initial concentration of Au, Ag and Cu. Journal of Petrology, 51, 2445–2464, https://doi.org/10.1093/petrology/egq063.Search in Google Scholar
Jiang, Z., Shang, L., Guo, H., Wang, X., Chen, C., and Zhou, Y. (2021) An experimental investigation into the partition of Mo between aqueous fluids and felsic melts: Implications for the genesis of porphyry Mo ore deposits. Ore Geology Reviews, 134, 104144, https://doi.org/10.1016/j.oregeorev.2021.104144.Search in Google Scholar
Kelemen, P.B. and Manning, C.E. (2015) Reevaluating carbon fluxes in subduction zones, what goes down, mostly comes up. Proceedings of the National Academy of Sciences of the United States of America, 112, E3997–E4006, https://doi.org/10.1073/pnas.1507889112.Search in Google Scholar
Keppler, H. and Wyllie, P.J. (1991) Partitioning of Cu, Sn, Mo, W, U, and Th between melt and aqueous fluid in the systems haplogranite-H2O-HCl and haplogranite-H2O-HF. Contributions to Mineralogy and Petrology, 109, 139–150, https://doi.org/10.1007/BF00306474.Search in Google Scholar
Lee, C.-T.A., Luffi, P., Chin, E.J., Bouchet, R., Dasgupta, R., Morton, D.M., Le Roux, V., Yin, Q.Z., and Jin, D. (2012) Copper systematics in arc magmas and implications for crust-mantle differentiation. Science, 336, 64–68, https://doi.org/10.1126/science.1217313.Search in Google Scholar
Li, Y. (2014) Comparative geochemistry of rhenium in oxidized arc magmas and MORB and rhenium partitioning during magmatic differentiation. Chemical Geology, 386, 101–114, https://doi.org/10.1016/j.chemgeo.2014.08.013.Search in Google Scholar
Lin, Y., van Westrenen, W., and Mao, H.-K. (2021) Oxygen controls on magmatism in rocky exoplanets. Proceedings of the National Academy of Sciences of the United States of America, 118, e2110427118, https://doi.org/10.1073/pnas.2110427118.Search in Google Scholar
MacKenzie, J.M. and Canil, D. (2011) Fluid/melt partitioning of Re, Mo, W, Tl and Pb in the system haplobasalt-H2O-Cl and the volcanic degassing of trace metals. Journal of Volcanology and Geothermal Research, 204, 57–65, https://doi.org/10.1016/j.jvolgeores.2011.04.011.Search in Google Scholar
McDonough, W.F. and Sun, S.-S. (1995) The composition of the Earth. Chemical Geology, 120, 223–253, https://doi.org/10.1016/0009-2541(94)00140-4.Search in Google Scholar
Moore, G., Vennemann, T., and Carmichael, I. (1998) An empirical model for the solubility of H2O in magmas to 3 kilobars. American Mineralogist, 83, 36–42.Search in Google Scholar
Norman, M.D., Garcia, M.O., and Bennett, V.C. (2004) Rhenium and chalcophile elements in basaltic glasses from Ko’olau and Moloka’i volcanoes: Magmatic outgassing and composition of the Hawaiian plume. Geochimica et Cosmochimica Acta, 68, 3761–3777, https://doi.org/10.1016/j.gca.2004.02.025.Search in Google Scholar
Park, J.-W., Campbell, I.H., Ickert, R.B., and Allen, C.M. (2013) Chalcophile element geochemistry of the Boggy Plain zoned pluton, southeastern Australia: A S-saturated barren compositionally diverse magmatic system. Contributions to Mineralogy and Petrology, 165, 217–236, https://doi.org/10.1007/s00410-012-0806-9.Search in Google Scholar
Pašava, J., Chrastný, V., Loukola-Ruskeeniemi, K., and Šebek, O. (2019) Nickel isotopic variation in black shales from Bohemia, China, Canada, and Finland: A reconnaissance study. Mineralium Deposita, 54, 719–742, https://doi.org/10.1007/s00126-018-0839-8.Search in Google Scholar
Peucker-Ehrenbrink, B. and Jahn, B. (2001) Rhenium-osmium isotope systematics and platinum group element concentrations: Loess and the upper continental crust. Geochemistry, Geophysics, Geosystems, 2, 2001GC000172, https://doi.org/10.1029/2001GC000172.Search in Google Scholar
Rempel, K.U., Migdisov, A., and Williams-Jones, A. (2006) The solubility and speciation of molybdenum in water vapour at elevated temperatures and pressures: Implications for ore genesis. Geochimica et Cosmochimica Acta, 70, 687–696, https://doi.org/10.1016/j.gca.2005.09.013.Search in Google Scholar
Rempel, K., Williams-Jones, A., and Migdisov, A. (2008) The solubility of molybdenum dioxide and trioxide in HCl-bearing water vapour at 350 °C and pressures up to 160 bars. Geochimica et Cosmochimica Acta, 72, 3074–3083, https://doi.org/10.1016/j.gca.2008.04.015.Search in Google Scholar
Righter, K., Chesley, J., Caiazza, C., Gibson, E. Jr., and Ruiz, J. (2008) Re and Os concentrations in arc basalts: The roles of volatility and source region
Rosenthal, Y., Lam, P., Boyle, E.A., and Thomson, J. (1995) Authigenic cadmium enrichments in suboxic sediments: Precipitation and postdepositional mobility. Earth and Planetary Science Letters, 132, 99–111, https://doi.org/10.1016/0012-821X(95)00056-I.Search in Google Scholar
Rudnick, R.L. and Fountain, D.M. (1995) Nature and composition of the continental crust: A lower crustal perspective. Reviews of Geophysics, 33, 267–309, https://doi.org/10.1029/95RG01302.Search in Google Scholar
Rudnick, R. and Gao, S. (2014) Composition of the continental crust. In H. Holland and K. Turekian, Eds., Treatise on Geochemistry, Volume 3, p. 1–64. Elsevier.Search in Google Scholar
Saal, A., Rudnick, R., Ravizza, G., and Hart, S. (1998) Re–Os isotope evidence for the composition, formation and age of the lower continental crust. Nature, 393, 58–61, https://doi.org/10.1038/29966.Search in Google Scholar
Seedorff, E., Dilles, J.H., Proffett, J.M. Jr., Einaudi, M.T., Zurcher, L., Stavast, W.J.A., Johnson, D.A., and Barton, M.D. (2005) Porphyry deposits: Characteristics and origin of hypogene features. In J.W. Hedenquist, J.F.H. Thompson, R.J. Goldfarb, and J.P. Richards, Eds., One Hundredth Anniversary Volume, Chapter. Society of Economic Geologists.Search in Google Scholar
Shang, L., Williams-Jones, A.E., Wang, X., Timofeev, A., Hu, R., and Bi, X. (2020) An experimental study of the solubility and speciation of MoO3(s) in hydrothermal fluids at temperatures up to 350 °C. Economic Geology and the Bulletin of the Society of Economic Geologists, 115, 661–669, https://doi.org/10.5382/econgeo.4715.Search in Google Scholar
Smythe, D.J., Wood, B.J., and Kiseeva, E.S. (2017) The S content of silicate melts at sulfide saturation: New experiments and a model incorporating the effects of sulfide composition. American Mineralogist, 102, 795–803, https://doi.org/10.2138/am-2017-5800CCBY.Search in Google Scholar
Sun, W.D., Arculus, R.J., Bennett, V.C., Eggins, S.M., and Binns, R.A. (2003a) Evidence for rhenium enrichment in the mantle wedge from submarine arc–like volcanic glasses (Papua New Guinea). Geology, 31, 845–848, https://doi.org/10.1130/G19832.1.Search in Google Scholar
Sun, W.D., Bennett, V.C., Eggins, S.M., Arculus, R.J., and Perfit, M.R. (2003b) Rhenium systematics in submarine MORB and back-arc basin glasses: Laser ablation ICP-MS results. Chemical Geology, 196, 259–281, https://doi.org/10.1016/S0009-2541(02)00416-3.Search in Google Scholar
Sun, W., Bennett, V.C., Eggins, S.M., Kamenetsky, V.S., and Arculus, R.J. (2003c) Enhanced mantle-to-crust rhenium transfer in undegassed arc magmas. Nature, 422, 294–297, https://doi.org/10.1038/nature01482.Search in Google Scholar
Sun, W., Arculus, R.J., Kamenetsky, V.S., and Binns, R.A. (2004) Release of gold-bearing fluids in convergent margin magmas prompted by magnetite crystallization. Nature, 431, 975–978, https://doi.org/10.1038/nature02972.Search in Google Scholar
Sun, W., Audétat, A., and Dolejš, D. (2014) Solubility of molybdenite in hydrous granitic melts at 800 °C, 100–200 MPa. Geochimica et Cosmochimica Acta, 131, 393–401, https://doi.org/10.1016/j.gca.2013.12.028.Search in Google Scholar
Sundby, B., Martinez, P., and Gobeil, C. (2004) Comparative geochemistry of cadmium, rhenium, uranium, and molybdenum in continental margin sediments. Geochimica et Cosmochimica Acta, 68, 2485–2493, https://doi.org/10.1016/j.gca.2003.08.011.Search in Google Scholar
Tattitch, B.C. and Blundy, J.D. (2017) Cu-Mo partitioning between felsic melts and saline-aqueous fluids as a function of
Ulrich, T. and Mavrogenes, J. (2008) An experimental study of the solubility of molybdenum in H2O and KCl-H2O solutions from 500 C to 800 °C, and 150 to 300 MPa. Geochimica et Cosmochimica Acta, 72, 2316–2330, https://doi.org/10.1016/j.gca.2008.02.014.Search in Google Scholar
Urann, B.M., Le Roux, V., Jagoutz, O., Müntener, O., Behn, M.D., and Chin, E.J. (2022) High water content of arc magmas recorded in cumulates from subduction zone lower crust. Nature Geoscience, 15, 501–508, https://doi.org/10.1038/s41561-022-00947-w.Search in Google Scholar
Wang, J., Zhang, L., Ren, Z., Xiong, X. (2016) Oxygen fugacity control in gas-mixing furnaces. Geochimica, 45, 475–485 (Chinese with abstract in English).Search in Google Scholar
Wanty, R.B. and Goldhaber, M.B. (1992) Thermodynamics and kinetics of reactions involving vanadium in natural systems: Accumulation of vanadium in sedimentary rocks. Geochimica et Cosmochimica Acta, 56, 1471–1483, https://doi.org/10.1016/0016-7037(92)90217-7.Search in Google Scholar
Webster, J.D. (1997) Exsolution of magmatic volatile phases from Cl-enriched mineralizing granitic magmas and implications for ore metal transport. Geochimica et Cosmochimica Acta, 61, 1017–1029, https://doi.org/10.1016/S0016-7037(96)00395-X.Search in Google Scholar
Xue, S. and Li, Y. (2022) Pyrrhotite–silicate melt partitioning of rhenium and the deep rhenium cycle in subduction zones. Geology, 50, 232–237, https://doi.org/10.1130/G49374.1.Search in Google Scholar
Yokoi, K., Matsubayashi, N., Miyanaga, T., Watanabe, I., and Ikeda, S. (1993) Studies on the structure of molybdenum (VI) in acidic solution by XANES and EXAFS. Polyhedron, 12, 911–914, https://doi.org/10.1016/S0277-5387(00)81545-4.Search in Google Scholar
Zajacz, Z., Halter, W.E., Pettke, T., and Guillong, M. (2008) Determination of fluid/melt partition coefficients by LA-ICPMS analysis of co-existing fluid and silicate melt inclusions: Controls on element partitioning. Geochimica et Cosmochimica Acta, 72, 2169–2197, https://doi.org/10.1016/j.gca.2008.01.034.Search in Google Scholar
Zajacz, Z., Candela, P.A., Piccoli, P.M., and Sanchez-Valle, C. (2012) The partitioning of sulfur and chlorine between andesite melts and magmatic volatiles and the exchange coefficients of major cations. Geochimica et Cosmochimica Acta, 89, 81–101, https://doi.org/10.1016/j.gca.2012.04.039.Search in Google Scholar
Zhang, L., Audétat, A., and Dolejš, D. (2012) Solubility of molybdenite (MoS2) in aqueous fluids at 600–800 °C, 200 MPa: A synthetic fluid inclusion study. Geochimica et Cosmochimica Acta, 77, 175–185, https://doi.org/10.1016/j.gca.2011.11.015.Search in Google Scholar
Zhao, P., Zajacz, Z., Tsay, A., Chu, X., Cheng, Q., and Yuan, S. (2022) The partitioning behavior of Mo during magmatic fluid exsolution and its implications for Mo mineralization. Geochimica et Cosmochimica Acta, 339, 115–126, https://doi.org/10.1016/j.gca.2022.10.020.Search in Google Scholar
Zheng, Y., Anderson, R.F., Van Geen, A., and Kuwabara, J. (2000) Authigenic molybdenum formation in marine sediments: A link to pore water sulfide in the Santa Barbara Basin. Geochimica et Cosmochimica Acta, 64, 4165–4178, https://doi.org/10.1016/S0016-7037(00)00495-6.Search in Google Scholar
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Articles in the same Issue
- Ertlite, NaAl3Al6(Si4B2O18)(BO3)3(OH)3O, a new mineral species of the tourmaline supergroup
- Synthesis of zircon-hafnon to determine oxygen isotope matrix effects in secondary ionization mass spectrometry
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- Pre-eruptive characteristics of “suspect” silicic magmas in Carlin-type Au-forming systems
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- Apatite geochemistry records crustal anatexis: A case study of metapelites and granitic gneisses from the Cona area in the eastern Himalaya
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- The effect of H2O on the crystallization of orthopyroxene in a high-Mg andesitic melt
- Bradleyite, Na3Mg(PO4)(CO3), inclusion in diamond: Structure and significance
- Revision of Y3+ ionic radii in common minerals based on trace element partitioning
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