Petrogenetic insights from chromite in ultramafic cumulates of the Xiarihamu intrusion, northern Tibet Plateau, China
-
Xie-Yan Song
, Kai-Yuan Wang
Abstract
Chromite is one of the earliest crystallized minerals from mafic melts and has been used as an important “petrogenetic indicator.” Its composition may be modified by interaction with intercumulate melt and adjacent minerals. Thus, chromite in mafic-ultramafic rocks contains clues to the geochemical affinity, evolution, and mantle source of its parent magmas. The Devonian Xiarihamu intrusion, located in the East Kunlun Orogenic Belt in the northern Tibet Plateau, China, hosts a very large disseminated Ni-Co sulfide deposit. This study focuses on geochemistry of the chromite enclosed in olivine of ultramafic rocks of the intrusion. Enrichments in Mg and Al in the rim of the chromite indicate only minor effects of alteration on the compositions of the chromite. The chromites enclosed in the olivines with forsterite percentage (Fo) lower than 87 are characterized by large variations in major and trace elements, such as large ranges of Cr·100/(Cr+Al) (Cr# = 15–47), Mg·100/(Mg+Fe2+) (Mg# = 41–65), and Al2O3 (= 26–53 wt%) as well as 380–3100 ppm V, 70–380 ppm Ga, and 1100–16300 ppm Zn. The chromites display positive correlations between Cr/(Cr+Al) and Ti, Mn, V, Ga, and Sc, inconsistent with fractional crystallization but indicative of an interaction between the chromites, intercumulate melts and hosting minerals. In contrast, chromites hosted in olivine with Fo > 87 in harzburgite have small variations in Cr# (ranging from 37 to 41), Mg# (48 to 51), and Al2O3 (30 to 35 wt%) as well as restricted variation in trace elements, indicating relatively weak interaction with trapped liquid and adjacent phases; these compositions are close to those of the most primitive, earliest crystallized chromites. The most primitive chromite has similarities with chromite in mid-ocean ridge basalt (MORB) in TiO2 and Al2O3 contents (0.19–0.32 and 27.9–36.3 wt%, respectively) and depletion of Sc and enrichment of Ga and Zn relative to MORB chromite. The geochemistry of the chromite indicates a partial melting of the asthenospheric mantle that was modified by melts derived from the subduction slab at garnet-stable pressures.
Acknowledgments and Funding
We thank Wen-Qin Zheng for her important contributions on mineralogy study in this work. We are grateful to Michael Lesher, J.M. González-Jiménez, and Heather Handley for constructive comments and suggestions. We thank Xiang Li and Zhi-Hui Dai for high-quality EPMA and LA-ICPMS analytical data. This study is supported by NSFC (41630316), National Key Research and Development Program of China (2018YFA0702605 and 2016YFC0600503) and NSFC (41473050 and 41772067) to X.-Y. Song.
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Articles in the same Issue
- Buoyant rise of anorthosite from a layered basic complex triggered by Rayleigh-Taylor instability: Insights from a numerical modeling study
- Chemically oscillating reactions in the formation of botryoidal malachite
- Micro- and nano-size hydrogarnet clusters and proton ordering in calcium silicate garnet: Part I. The quest to understand the nature of “water” in garnet continues
- Micro- and nano-size hydrogarnet clusters in calcium silicate garnet: Part II. Mineralogical, petrological, and geochemical aspects
- Petrogenetic insights from chromite in ultramafic cumulates of the Xiarihamu intrusion, northern Tibet Plateau, China
- Enigmatic diamonds from the Tolbachik volcano, Kamchatka
- Volcanic SiO2-cristobalite: A natural product of chemical vapor deposition
- Mg diffusion in forsterite from 1250–1600 °C
- Alteration of magmatic monazite in granitoids from the Ryoke belt (SW Japan): Processes and consequences
- Smamite, Ca2Sb(OH)4[H(AsO4)2]·6H2O, a new mineral and a possible sink for Sb during weathering of fahlore
- The new K, Pb-bearing uranyl-oxide mineral kroupaite: Crystal-chemical implications for the structures of uranyl-oxide hydroxy-hydrates
- Changes in the cell parameters of antigorite close to its dehydration reaction at subduction zone conditions
- Memorial of Edward J. Olsen 1927–2020
Articles in the same Issue
- Buoyant rise of anorthosite from a layered basic complex triggered by Rayleigh-Taylor instability: Insights from a numerical modeling study
- Chemically oscillating reactions in the formation of botryoidal malachite
- Micro- and nano-size hydrogarnet clusters and proton ordering in calcium silicate garnet: Part I. The quest to understand the nature of “water” in garnet continues
- Micro- and nano-size hydrogarnet clusters in calcium silicate garnet: Part II. Mineralogical, petrological, and geochemical aspects
- Petrogenetic insights from chromite in ultramafic cumulates of the Xiarihamu intrusion, northern Tibet Plateau, China
- Enigmatic diamonds from the Tolbachik volcano, Kamchatka
- Volcanic SiO2-cristobalite: A natural product of chemical vapor deposition
- Mg diffusion in forsterite from 1250–1600 °C
- Alteration of magmatic monazite in granitoids from the Ryoke belt (SW Japan): Processes and consequences
- Smamite, Ca2Sb(OH)4[H(AsO4)2]·6H2O, a new mineral and a possible sink for Sb during weathering of fahlore
- The new K, Pb-bearing uranyl-oxide mineral kroupaite: Crystal-chemical implications for the structures of uranyl-oxide hydroxy-hydrates
- Changes in the cell parameters of antigorite close to its dehydration reaction at subduction zone conditions
- Memorial of Edward J. Olsen 1927–2020