Abstract
It is now widely accepted that Earth’s transition zone, located at depth between 410 and 670 km, is most likely hydrated. However, a definite conclusion has yet to be reached regarding the nature of the hydrous phase or phases that have the capacity to efficiently transport water down to such depths. In the April issue of American Mineralogist, Nishihara and Matsukage (2016) show that (FeH)1–xTixO2 can be stable in wet basalts and sediments at high pressures and temperatures. These phases allow subducting lithosphere to transport far more water to the mantle transition zone than previously thought possible.
References cited
Bell, D.R., and Rossman, G.R. (1992) Water in Earth’s mantle: The role of nominally anhydrous minerals. Science, 255, 1391–1396.10.1126/science.255.5050.1391Search in Google Scholar
Bercovici, D., and Karato, S.-i. (2003) Whole-mantle convection and the transition-zone water filter. Nature, 425, 39–44.10.1038/nature01918Search in Google Scholar
Doucet, L.S., Peslier, A.H., Ionov, D.A., Brandon, A.D., Golovin, A.V., Goncharov, A.G., and Ashchepkov, I.V. (2014) High water contents in the Siberian cratonic mantle linked to metasomatism: An FTIR study of Udachnaya peridotite xenoliths. Geochimica et Cosmochimica Acta, 137, 159–187.10.1016/j.gca.2014.04.011Search in Google Scholar
Hirschmann, M.M., Aubaud, C., and Withers, A.C. (2005) Storage capacity of H2O in nominally anhydrous minerals in the upper mantle. Earth and Planetary Science Letters, 236(1–2), 167–181.10.1016/j.epsl.2005.04.022Search in Google Scholar
Inoue, T., Yurimoto, H., and Kudoh, Y. (1995) Hydrous modified spinel, Mg1.75SiH0.5O4: a new water reservoir in the mantle transition region. Geophysical Research Letter, 22, 117–120.10.1029/94GL02965Search in Google Scholar
Kawamoto, T. (2006) Hydrous phases and water transport in the subducting slab. In H. Keppler, and J.R. Smyth, Eds., Water in Nominally Anhydrous Minerals, 62, p. 273–289. Reviews in Mineralogy and Geochemistry, Mineralogical Society of America, Chantilly, Virginia.10.1515/9781501509476-016Search in Google Scholar
Kawamoto, T., and Holloway, J.R. (1997) Melting temperature and partial melt chemistry of H2O-saturated mantle peridotite to 11 gigapascal. Science, 276, 240–243.10.1126/science.276.5310.240Search in Google Scholar
Kawamoto, T., Hervig, R.L., and Holloway, J.R. (1996) Experimental evidence for a hydrous transition zone of the early Earth’s mantle. Earth and Planetary Science Letters, 142, 587–592.10.1016/0012-821X(96)00113-6Search in Google Scholar
Kohlstedt, D.L., Keppler, H., and Rubie, D.C. (1996) Solubility of water in α, β, and γ phases of (Mg,Fe)2SiO4. Contributions to Mineralogy and Petrology, 123, 345–357.10.1007/s004100050161Search in Google Scholar
Mibe, K., Kanzaki, M., Kawamoto, T., Matsukage, K.N., Fei, Y., and Ono, S. (2007) Second critical endpoint in peridotite-H2O system. Journal of Geophysical Research, 112, B03201.10.1029/2005JB004125Search in Google Scholar
Nishihara, Y., and Matsukage, N.K. (2016) Iron-titanium oxyhydroxides as water carriers in the Earth’s deep mantle. American Mineralogist, 101, 919–927.10.2138/am-2016-5517Search in Google Scholar
Okamoto, K., and Maruyama, S. (2004) The eclogite–garnetite transformation in the MORB + H2O system. Physics of the Earth and Planetary Interiors, 146(1–2), 283–296.10.1016/j.pepi.2003.07.029Search in Google Scholar
Ono, S. (1998) Stability limits of hydrous minerals in sediment and mid-ocean ridge basalt compositions: Implications for water transport in subduction zones. Journal of Geophysical Research, 103, 18,253–18,267.10.1029/98JB01351Search in Google Scholar
Pearson, D.G., Brenker, F.E., Nestola, F., McNeill, J., Nasdala, L., Hutchison, M.T., Matveev, S., Mather, K., Silversmit, G., Schmitz, S., Vekemans, B., and Vincze, L. (2014) Hydrous mantle transition zone indicated by ringwoodite included within diamond. Nature, 507, 221–224.10.1038/nature13080Search in Google Scholar PubMed
Peslier, A.H., Woodland, A.B., Bell, D.R., Lazarov, M., and Lapen, T.J. (2012) Metasomatic control of water contents in the Kaapvaal cratonic mantle. Geochimica et Cosmochimica Acta, 97, 213–246.10.1016/j.gca.2012.08.028Search in Google Scholar
Poli, S., and Schmidt, M.W. (1995) H2O transport and release in subductionzones: experimental constraints on basaltic and andesitic systems. Journal of Geophysical Research, 100, 22299.10.1029/95JB01570Search in Google Scholar
Smyth, J.R. (1987) β-Mg2SiO4: A potential host for water in the mantle? American Mineralogist, 72, 1051–1055.Search in Google Scholar
Sudo, A., and Tatsumi, Y. (1990) Phlogopite and K-amphibole in the upper mantle: implications for magma genesis in subduction zones. Geophysical Research Letter, 17, 29.10.1029/GL017i001p00029Search in Google Scholar
Tatsumi, Y. (1989) Migration of fluid phases and genesis of basalt magmas in subduction zones. Journal of Geophysical Research, 94, 4697–4707.10.1029/JB094iB04p04697Search in Google Scholar
Ulmer, P., and Trommsdorff, V. (1995) Serpentine stability to mantle depthsand subduction-related magmatism. Science, 268, 858–861.10.1126/science.268.5212.858Search in Google Scholar PubMed
Young, T., Green, H. II, Hofmeister, A., and Walker, D. (1993) Infrared spectroscopic investigation of hydroxyl in β-(Mg,Fe)2SiO and coexisting olivine: Implications for mantle evolution and dynamics. Physics and Chemistry of Minerals, 19(6), 409–422.10.1007/BF00202978Search in Google Scholar
© 2016 by Walter de Gruyter Berlin/Boston
Articles in the same Issue
- Highlights and Breakthroughs
- (FeH)1–xTixO2: A new water carrier to the mantle transition zone
- Highlights and Breakthroughs
- Dissecting a volcano
- Highlights and Breakthroughs
- W-WO joins the deep Earth electrochemical series
- Presidential Address
- Time’s arrow in the trees of life and minerals
- Research Article
- A century of mineral structures: How well do we know them?
- Special collection: Building planets: The dynamics and Geochemistry of core formation
- Equation of state of pyrite to 80 GPa and 2400 K
- Special collection: Perspectives on origins and evolution of crustal magmas
- Understanding magmatic processes at Telica volcano, Nicaragua: Crystal size distribution and textural analysis
- Special Collection: Apatite: A Common Mineral, Uncommonly Versatile
- Non-hydrothermal origin of apatite in SEDEX mineralization and host rocks of the Howard’s Pass district, Yukon, Canada
- Research Article
- Petrographic investigation of smithing slag of the Hellenistic to Byzantine city of Sagalassos (SW-Turkey)
- Research Article
- Equation of state and spin crossover of (Mg,Fe)O at high pressure, with implications for explaining topographic relief at the core-mantle boundary
- Research Article
- “Satellite monazites” in polymetamorphic basement rocks of the Alps: Their origin and petrological significance
- Research Article
- Solution-chemistry control of Mg2+-calcite interaction mechanisms: Implication for biomineralization
- Research Article
- Probing carbon-bearing species and CO2 inclusions in amorphous carbon-MgSiO3 enstatite reaction products at 1.5 GPa: Insights from 13C high-resolution solid-state NMR
- Research Article
- Thermochemistry of rare earth perovskites Na3xRE0.67–xTiO3 (RE = La, Ce)
- Research Article
- Thermodynamics of bastnaesite: A major rare earth ore mineral
- Research Article
- A single-crystal X-ray and Raman spectroscopic study of hydrothermally synthesized arsenates and vanadates with the descloizite and adelite structure types
- Research Article
- Compressional and shear wave velocities for polycrystalline bcc-Fe up to 6.3 GPa and 800 K
- Research Article
- Majindeite, Mg2Mo3O8, a new mineral from the Allende meteorite and a witness to post-crystallization oxidation of a Ca-Al-rich refractory inclusion
- Research Article
- Use of multivariate analysis for synchrotron micro-XANES analysis of iron valence state in amphiboles
- Research Article
- Elasticity and phase transformation at high pressure in coesite from experiments and first-principles calculations
- Research Article
- Thermodynamics of mixing in an isostructural solid solution: Simulation methodologies and application to the rutile-cassiterite system
- Research Article
- Compressibility of 2M1 muscovite-paragonite series minerals: A computational study to 6 GPa
- Research Article
- Joegoldsteinite: A new sulfide mineral (MnCr2S4) from the Social Circle IVA iron meteorite
- Research Article
- Oxygen isotope thermometry reveals high magmatic temperatures and short residence times in Yellowstone and other hot-dry rhyolites compared to cold-wet systems
- Letter
- The elastic tensor of monoclinic alkali feldspars
- Letter
- Ca neighbors from XANES spectroscopy: A tool to investigate structure, redox, and nucleation processes in silicate glasses, melts, and crystals
- Letter
- Coupled substitution of Fe3+ and H+ for Si in wadsleyite: A study by polarized infrared and Mössbauer spectroscopies and single-crystal X-ray diffraction
- Research Article
- New Mineral Names
Articles in the same Issue
- Highlights and Breakthroughs
- (FeH)1–xTixO2: A new water carrier to the mantle transition zone
- Highlights and Breakthroughs
- Dissecting a volcano
- Highlights and Breakthroughs
- W-WO joins the deep Earth electrochemical series
- Presidential Address
- Time’s arrow in the trees of life and minerals
- Research Article
- A century of mineral structures: How well do we know them?
- Special collection: Building planets: The dynamics and Geochemistry of core formation
- Equation of state of pyrite to 80 GPa and 2400 K
- Special collection: Perspectives on origins and evolution of crustal magmas
- Understanding magmatic processes at Telica volcano, Nicaragua: Crystal size distribution and textural analysis
- Special Collection: Apatite: A Common Mineral, Uncommonly Versatile
- Non-hydrothermal origin of apatite in SEDEX mineralization and host rocks of the Howard’s Pass district, Yukon, Canada
- Research Article
- Petrographic investigation of smithing slag of the Hellenistic to Byzantine city of Sagalassos (SW-Turkey)
- Research Article
- Equation of state and spin crossover of (Mg,Fe)O at high pressure, with implications for explaining topographic relief at the core-mantle boundary
- Research Article
- “Satellite monazites” in polymetamorphic basement rocks of the Alps: Their origin and petrological significance
- Research Article
- Solution-chemistry control of Mg2+-calcite interaction mechanisms: Implication for biomineralization
- Research Article
- Probing carbon-bearing species and CO2 inclusions in amorphous carbon-MgSiO3 enstatite reaction products at 1.5 GPa: Insights from 13C high-resolution solid-state NMR
- Research Article
- Thermochemistry of rare earth perovskites Na3xRE0.67–xTiO3 (RE = La, Ce)
- Research Article
- Thermodynamics of bastnaesite: A major rare earth ore mineral
- Research Article
- A single-crystal X-ray and Raman spectroscopic study of hydrothermally synthesized arsenates and vanadates with the descloizite and adelite structure types
- Research Article
- Compressional and shear wave velocities for polycrystalline bcc-Fe up to 6.3 GPa and 800 K
- Research Article
- Majindeite, Mg2Mo3O8, a new mineral from the Allende meteorite and a witness to post-crystallization oxidation of a Ca-Al-rich refractory inclusion
- Research Article
- Use of multivariate analysis for synchrotron micro-XANES analysis of iron valence state in amphiboles
- Research Article
- Elasticity and phase transformation at high pressure in coesite from experiments and first-principles calculations
- Research Article
- Thermodynamics of mixing in an isostructural solid solution: Simulation methodologies and application to the rutile-cassiterite system
- Research Article
- Compressibility of 2M1 muscovite-paragonite series minerals: A computational study to 6 GPa
- Research Article
- Joegoldsteinite: A new sulfide mineral (MnCr2S4) from the Social Circle IVA iron meteorite
- Research Article
- Oxygen isotope thermometry reveals high magmatic temperatures and short residence times in Yellowstone and other hot-dry rhyolites compared to cold-wet systems
- Letter
- The elastic tensor of monoclinic alkali feldspars
- Letter
- Ca neighbors from XANES spectroscopy: A tool to investigate structure, redox, and nucleation processes in silicate glasses, melts, and crystals
- Letter
- Coupled substitution of Fe3+ and H+ for Si in wadsleyite: A study by polarized infrared and Mössbauer spectroscopies and single-crystal X-ray diffraction
- Research Article
- New Mineral Names