Home Letters. Chloride ion sites in silicate and aluminosilicate glasses: A preliminary study by 35Cl solid-state NMR
Article
Licensed
Unlicensed Requires Authentication

Letters. Chloride ion sites in silicate and aluminosilicate glasses: A preliminary study by 35Cl solid-state NMR

  • Jonathan F. Stebbins EMAIL logo and Lin-Shu Du
Published/Copyright: March 28, 2015
Become an author with De Gruyter Brill
Author Information
American Mineralogist
From the journal American Mineralogist Volume 87 Issue 2-3

Abstract

Despite the importance of the chloride ion in magmas and the fluids that separate from them, very little is known about atomic-scale structural environments for Cl- in silicate glasses. We present here the first solid-state 35Cl NMR data for Cl in silicate and aluminosilicate glasses, made possible by the availability of very high (14.1 to 18.8 Tesla) magnetic fields. We find that 35Cl has a wide range in chemical shifts that correlate well with cation-Cl distance and thus contain considerable structural information. In general, Cl is coordinated primarily by network-modifying alkali or alkaline earth cations, and we see no evidence for Al-Cl bonding.

Received: 2001-10-23
Accepted: 2001-11-7
Published Online: 2015-3-28
Published in Print: 2002-2-1

© 2015 by Walter de Gruyter Berlin/Boston

Articles in the same Issue

  1. Presidential Address. Scales of disequilibrium and rates of equilibration during metamorphism
  2. Characterization of coexisting NH4- and K-micas in very low-grade metapelites
  3. Effect of sonic and ultrasonic frequencies on the crystallization of basalt
  4. Sulfur saturation limits in silicate melts and their implications for core formation scenarios for terrestrial planets
  5. Molecular water in beryl, VIAl2 [Be3Si6O18]·nH2O, as a function of pressure and temperature: An experimental study
  6. Fluid-induced nucleation of (Y + REE)-phosphate minerals within apatite: Nature and experiment. Part I. Chlorapatite
  7. X-ray spectroscopic investigations of fluids in the hydrothermal diamond anvil cell: The hydration structure of aqueous La3+ up to 300 °C and 1600 bars
  8. Fibrous nanoinclusions in massive rose quartz: HRTEM and AEM investigations
  9. Polysomatism in högbomite: The crystal structures of 10T, 12H, 14T, and 24R polysomes
  10. Ordering of hydroxyl defects in hydrous wadsleyite (β-Mg2SiO4)
  11. The crystal structure and cation ordering of Phase-X-(K1–x–n)2(Mg1–n[Al,Cr]n)2Si2O7H2x: A potential K- and H-bearing phase in the mantle
  12. Feasibility of determining the quantitative OH content of garnets with Raman spectroscopy
  13. Raman spectroscopic study of garnet inclusions in diamonds from the mantle transition zone
  14. Raman spectroscopy of Fe2O3 to 62 GPa
  15. Study of the (010) olivine surface by Rutherford backscattering spectrometry in channeling geometry
  16. Equation of state of dense hydrous magnesium silicate phase A, Mg7Si2O8(OH)6
  17. Si-F bonding in aluminosilicate glasses: Inferences from ab initio NMR calculations
  18. Monoclinic nearly stoichiometric wüstite at low temperatures
  19. On the nature of tincalconite
  20. Letters. Chloride ion sites in silicate and aluminosilicate glasses: A preliminary study by 35Cl solid-state NMR
  21. Nuclear magnetic resonance and infrared spectroscopic study of excess-boron olenite from Koralpe, Styria, Austria
https://doi.org/10.2138/am-2002-2-320

Articles in the same Issue

  1. Presidential Address. Scales of disequilibrium and rates of equilibration during metamorphism
  2. Characterization of coexisting NH4- and K-micas in very low-grade metapelites
  3. Effect of sonic and ultrasonic frequencies on the crystallization of basalt
  4. Sulfur saturation limits in silicate melts and their implications for core formation scenarios for terrestrial planets
  5. Molecular water in beryl, VIAl2 [Be3Si6O18]·nH2O, as a function of pressure and temperature: An experimental study
  6. Fluid-induced nucleation of (Y + REE)-phosphate minerals within apatite: Nature and experiment. Part I. Chlorapatite
  7. X-ray spectroscopic investigations of fluids in the hydrothermal diamond anvil cell: The hydration structure of aqueous La3+ up to 300 °C and 1600 bars
  8. Fibrous nanoinclusions in massive rose quartz: HRTEM and AEM investigations
  9. Polysomatism in högbomite: The crystal structures of 10T, 12H, 14T, and 24R polysomes
  10. Ordering of hydroxyl defects in hydrous wadsleyite (β-Mg2SiO4)
  11. The crystal structure and cation ordering of Phase-X-(K1–x–n)2(Mg1–n[Al,Cr]n)2Si2O7H2x: A potential K- and H-bearing phase in the mantle
  12. Feasibility of determining the quantitative OH content of garnets with Raman spectroscopy
  13. Raman spectroscopic study of garnet inclusions in diamonds from the mantle transition zone
  14. Raman spectroscopy of Fe2O3 to 62 GPa
  15. Study of the (010) olivine surface by Rutherford backscattering spectrometry in channeling geometry
  16. Equation of state of dense hydrous magnesium silicate phase A, Mg7Si2O8(OH)6
  17. Si-F bonding in aluminosilicate glasses: Inferences from ab initio NMR calculations
  18. Monoclinic nearly stoichiometric wüstite at low temperatures
  19. On the nature of tincalconite
  20. Letters. Chloride ion sites in silicate and aluminosilicate glasses: A preliminary study by 35Cl solid-state NMR
  21. Nuclear magnetic resonance and infrared spectroscopic study of excess-boron olenite from Koralpe, Styria, Austria
Sign up now to receive a 20% welcome discount
Institutional Access
How does access work?
Have an idea on how to improve our website?
Please write us.
© 2025 De Gruyter Brill
Downloaded on 9.9.2025 from https://www.degruyterbrill.com/document/doi/10.2138/am-2002-2-320/html
Scroll to top button