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Individual Extraction Constants of Some Univalent Organic Cations in the Two-Phase Water–Phenyltrifluoromethyl Sulfone System
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Emanuel Makrlík
Published/Copyright:
June 9, 2011
Abstract
From extraction experiments and γ-activity measurements, the extraction constants corresponding to the general equilibrium C+(aq) + I−(aq) ⇔ C+(org) + I−(org) taking place in the two-phase water–phenyltrifluoromethyl sulfone (abbrev. FS 13) system (C+ = organic cation; aq = aqueous phase, org = FS 13 phase) were evaluated. Furthermore, the individual extraction constants of 8 univalent organic cations in the mentioned two-phase system were calculated.
Keywords: Univalent Organic Cations; Water-Phenyltrifluoromethyl Sulfone System; Individual Extraction Constants.
Published Online: 2011-6-9
Published in Print: 2011-8-1
© by Oldenbourg Wissenschaftsverlag, Pilsen, Germany
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Keywords for this article
Univalent Organic Cations;
Water-Phenyltrifluoromethyl Sulfone System;
Individual Extraction Constants.
Articles in the same Issue
- Modulating Hydrogen Tunnelling in Ascorbate Proton-Coupled Electron Transfers
- Small Molecule Tunnelling Systems: Variation of Isotope Effects
- Photochemical Properties and Reactions with Biomolecules of 4'-N-Acetyl Derivative of Norfloxacin
- Spectroscopic and Molecular Modeling Studies of the Inclusion Complex of TNBAB with β-cyclodextrin in Aqueous Solution
- Individual Extraction Constants of Some Univalent Organic Cations in the Two-Phase Water–Phenyltrifluoromethyl Sulfone System
- Modified Combustion Synthesis of γ-Alumina Nano Powders
