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Structural and Magnetic Properties of [Mn3(C2H3O2)6(H2O)4]· 2(C2H5NO2)· 2(H2O)
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Manuela Ramos Silva
Published/Copyright:
September 25, 2009
Abstract
Hexa-acetate-tetra-aqua-trimanganese diglycine dihydrated retains the two-dimensional character of commercial manganese diacetate tetrahydrate. The manganese atoms assemble in short centrosymetric chains that are further bridged through the carboxylic group of the acetate ions agglomerating the chains into a two-dimensional pattern. The layers are bonded through H-bonds involving the zwitterionic glycine and the solvate water molecules. Susceptibility measurements show a ferrimagnetic behaviour of the sample.
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Published Online: 2009-09-25
Published in Print: 2006-07-01
© by Oldenbourg Wissenschaftsverlag, München
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Articles in the same Issue
- Preface: Wolf Weyrich – a biography
- Comparison of the Proton Transfer Path in Hydrogen Bonds from Theoretical Potential Energy Surfaces and the Concept of Conservation of Bond Order
- Theoretical Study of Structure and Energetics of Gold Clusters with the EAM Method
- Crystal Spectrometers for Compton Scattering Studies
- Compton Profiles of Hydrated Na+ and F- Ions
- Wigner Functions and Bond Orders
- Structural and Magnetic Properties of [Mn3(C2H3O2)6(H2O)4]· 2(C2H5NO2)· 2(H2O)
- Ab Initio Study of the Vibrational Spectrum and Related Properties of Crystalline Compounds; the Case of CaCO3 Calcite
- On the Prospective Use of the One-Electron Density Matrix as a Test of the Quality of Post-Hartree–Fock Schemes for Crystals
- Generalized Hybrid Orbitals in the FA-ADMA Method
- Density-Matrix Study of the Hydrogen-Antihydrogen Molecule
- The Role of the Lone Pairs in Hydrogen Bonding
- Nuclear Inelastic Scattering on Ferrocene-Based Rotator Phases: Theory vs. Experiment
