Ultrasonic Speeds and Volumetric Properties of Dipropylene Glycol Monomethyl Ether–n-Alkylamine Mixtures at 298.15 K
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A. Pal
The excess molar volume and ultrasonic speed have been measured in dipropylene glycol monomethyl ether + butylamine, dibutylamine, and tributylamine across the entire composition range, at the temperature 298.15 K and atmospheric pressure. The ultrasonic speed values have been combined with those of the excess molar volumes converted to densities to give estimates of the product KS,m of the molar volumes and isentropic compressibility κS and the excess quantity KS,mE. The excess volumes are negative over the entire range of composition for all mixtures with the exception of tributylamine. The KS,mE values are negative for all mixtures. The deviation of the speeds of sound uD from their ideal values uid in an ideal mixture were also calculated for all measured mole fractions. Graphs of VmE, u, uD, and KS,mE against composition are presented as a basis for a qualitative discussion of the results.
Articles in the same Issue
- Ultrasonic Speeds and Volumetric Properties of Dipropylene Glycol Monomethyl Ether–n-Alkylamine Mixtures at 298.15 K
- Thermodynamic and UV Studies of Association Reaction between Phenols and Benzil Mono Benzylidene Aniline
- The Hydrothermal Formation of Hydronium Alunite from Aqueous Al2(SO4)3 Solution and the Characterization of the Solid
- Effect of β-Cyclodextrin on the Micellar Behavior of Cetylpydinium Chloride in Aqueous Solution
- Solvent Effects on the Gibbs Energy of Adsorption of Neutral Organic Compounds
- Photodarkening of Amorphous Selenium under High Pressure
- A Jäntti Approach for Quick Calculations of Sorption Equilibria
- Book Reviews
Articles in the same Issue
- Ultrasonic Speeds and Volumetric Properties of Dipropylene Glycol Monomethyl Ether–n-Alkylamine Mixtures at 298.15 K
- Thermodynamic and UV Studies of Association Reaction between Phenols and Benzil Mono Benzylidene Aniline
- The Hydrothermal Formation of Hydronium Alunite from Aqueous Al2(SO4)3 Solution and the Characterization of the Solid
- Effect of β-Cyclodextrin on the Micellar Behavior of Cetylpydinium Chloride in Aqueous Solution
- Solvent Effects on the Gibbs Energy of Adsorption of Neutral Organic Compounds
- Photodarkening of Amorphous Selenium under High Pressure
- A Jäntti Approach for Quick Calculations of Sorption Equilibria
- Book Reviews
