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On the possibility of the Observation of Intramolecular Reaction Dynamics in Liquids by Time-resolved X-ray Scattering
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S. Techert
Published/Copyright:
September 25, 2009
The feasibility of time-resolved structural studies using pulsed X-ray radiation from a 3rd generation synchrotron is discussed and compared with scattering experiments which might be possible with a future free electron laser (X-FEL). As an example, it is shown that the structural changes during the isomerisation process of trans-stilbene into cis-stilbene can be observed using time-resolved X-ray diffraction in the gas-phase as well as in solution.
Published Online: 2009-09-25
Published in Print: 2002-05
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Articles in the same Issue
- Fluorescence Excitation Spectrum, Lifetimes and Photoisomerization of Jet-Cooled Conformers of 1,1´-bi(benzocyclobutylidene)
- On the possibility of the Observation of Intramolecular Reaction Dynamics in Liquids by Time-resolved X-ray Scattering
- Femtosecond Fluorescence Anisotropy Kinetics as a Signature of Ultrafast Electronic Energy Transfer in Bichromophoric Molecules
- On the sudden Limit in the Capture of Particles for Long-Range Anisotropic Interactions
- Particle Entropies and Entropy Quanta. III. The van der Waals Gas
- Formation of Carbon Nanoparticle in Carbon Suboxide Pyrolysis behind Shock Waves
- Quantum Cluster Equilibrium Theory of Liquids: Isotopically substituted QCE/3-21G Model Water
- Kinematical Description of Meandering Spiral Waves in Active Media
- Chemo-Mechanical Coupling and Pattern Formation in a Complex Reaction System
- Relative Electrical Resistance of Pd Saturated by Gaseous Deuterium in a Wide Pressure Range at 298 K
- Book Reviews
