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[Cu(imidazole)2(CO3)]⋅H2O: an intermediate in the formation of the copper bis-imidazolate polymer (blue phase)
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N. Masciocchi
Published/Copyright:
September 25, 2009
Abstract
The crystal structure of [Cu(Him)2(CO3)]·H2O, determined from conventional X-ray powder diffraction methods, allowed to clarify, on the basis of a structural interpretation of the chemical transformation, the role of the title compound in the formation of the blue phase of Cu(im)2 [Cu(Him)2(CO3)]·H2O is triclinic, P1̅; a = 8.8565(7), b = 8.9579(5), c = 8.3705(6) Å, α = 105.728(4)°, β = 105.318(3)°, γ = 114.369(4)°; final Rwp, Rp and RF agreement factors, for 4700 data collected in the 11–105° range, are 0.053, 0.036 and 0.078, respectively.
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Published Online: 2009-9-25
Published in Print: 2002-3-1
© 2002 Oldenbourg Wissenschaftsverlag GmbH
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- [Cu(imidazole)2(CO3)]⋅H2O: an intermediate in the formation of the copper bis-imidazolate polymer (blue phase)
Articles in the same Issue
- Search for structure-forming components in molecular crystals of binary compounds: a topological approach
- Least-squares refinements of crystal structures: leverage analysis and the effects of truncating data
- Monte Carlo Study of the quasicrystal-to-crystal transformation using an approach based on the Gummelt covering
- Crystal structure analysis, pseudosymmetry and spectroscopic data of K4[Fe(CN)5NO2]⋅KNO2⋅H2O
- Stacking disorder in 2H-NbS2 and its intercalation compounds Kx(H2O)yNbS2 I. Description and model calculations of stacking faults in the host lattice NbS2
- [Cu(imidazole)2(CO3)]⋅H2O: an intermediate in the formation of the copper bis-imidazolate polymer (blue phase)
