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The structure of the palladium-rich boride Pd5B (Pd16B3)
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M. Ellner
Published/Copyright:
September 25, 2009
Abstract
The low-temperature boride Pd5B (Pd16B3) formscongruently from the corresponding interstitial solid solu-tion Pd(B) (Pearson-Parthé symbol cF(8-x), space group Fm3̅m) at 658 K. The structure of Pd5B has been investigated by X-ray powder diffraction yielding the following structural data: I4/mmm, tI2.38; unit cell parameters a = 0.28490(4) nm, c = 0.40038(9) nm, c/a = 1.405 < √2, with the occupation 2Pd (a) and 0.19 x 2B (b). The crystal chemical data of Pd5B and some other homeotypic interstitial compounds of transition metals have been compared.
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Published Online: 2009-9-25
Published in Print: 2001-11-1
© 2001 Oldenbourg Wissenschaftsverlag GmbH
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Articles in the same Issue
- Structure solution with PATSEE
- The quasicrystal-to-crystal transformation. II. Landau theory
- Superstructure of strontium chromate aluminate sodalite at low temperatures
- The structure of the palladium-rich boride Pd5B (Pd16B3)
- Crystal structure and twinning of Bi4O5Br2
- Synthesis and properties of 6-fluoro-7-chloro-4-oxo-4H-chromene 3-carboxylic acid. X-ray structure of achiral heterotopic 3-diethoxymethyl-6-fluoro-7-chloro-4-oxo-4H-chromene
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