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Structure and properties of a rare-topology [MnII4]-core complex with terminal bromido ligands
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Published/Copyright:
July 16, 2012
Abstract
A rare-topology [MnII4]-core complex [Mn4Br4(ppko)4(CH3OH)4] (1; ppkoH = phenyl 2-pyridyl ketoxime) was synthesized via a solvothermal route and characterized by X-ray diffraction, IR, EPR, ESI-MS and magnetic properties measurements. In 1 Mn2+ ions are bridged with phenyl 2-pyridyl ketoxime ligands. Bromine atoms and methanol molecules are terminal ligands. A comparison is made to the reported analogues with different terminal ligands pattern.
Published Online: 2012-07-16
Published in Print: 2012-09
© by Oldenbourg Wissenschaftsverlag, München, Germany
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Articles in the same Issue
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- Investigations of new barium dicarboxylates
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