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The phase transition to the low-temperature form of (D5O2)[SbCl6] and determination of the deuterium positions
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Henning Henke
Published/Copyright:
August 4, 2010
Abstract
The crystal structure of the low-temperature form of (D5O2)[SbCl6] has been investigated using X-ray and neutron diffraction on powder samples and compared with the high-temperature phase. At 40 K in space group C2/c the lattice parameters are a = 11.938(1), b = 6.8968(4), c = 12.996(1) Å, β = 115.165(6)° in agreement with Z = 4. Although the phase transition corresponds to a 1st order process the similarity between high- and low-temperature form is remarkable.
Keywords: Phase transition; Hexachloridoantimonic acid; Deuterium bonds; Powder diffraction structure analysis; X-ray diffraction
Published Online: 2010-08-04
Published in Print: 2010-09
© by Oldenbourg Wissenschaftsverlag, Karlsruhe, Germany
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Keywords for this article
Phase transition;
Hexachloridoantimonic acid;
Deuterium bonds;
Powder diffraction structure analysis;
X-ray diffraction
Articles in the same Issue
- Indium-doped gallophosphate NH4[NiGa1.84In0.16(PO4)3(H2O)2]: synthesis, X-ray crystal structure and IR spectroscopy
- The phase transition to the low-temperature form of (D5O2)[SbCl6] and determination of the deuterium positions
- Half antiperovskites: V. Systematics in ordering and group-subgroup-relations for Pb2Pd3Se2, Bi2Pd3Se2, and Bi2Pd3S2
- X-ray powder diffraction, solid-state NMR and dispersion-corrected DFT calculations to investigate the solid state structure of 2-ammonio-5-chloro-4-methylbenzenesulfonate
- Mixed salts of amino acids: Syntheses, crystal structure and vibrational spectra of L-histidinium(2+) · NO3 · ClO4 and L-histidinium(2+) · NO3 · BF4
- Synthesis, X-ray analysis and DFT study of 2-amino-3-(N-oxipiridin-4-ilsulfanil)-propionic acid dihydrate
- Discussion of unusual hydrogen atom display in solid acids
