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Synthesis, crystal structure and magnetic behaviourof a mononuclear Fe(III) — Schiff base metal complex
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Hasan Nazir
Published/Copyright:
September 25, 2009
Abstract
A complex from Fe(II) and a hexa-dentate linear ligand containing O2N4 donor atoms were prepared and the structure enlightened with X-ray diffraction. The Fe(II) ion in the complex was seen to be oxidized to form a Fe(III) complex, [C20H24Cl3N4O2]Fe and the three chloride ions were situated at a distance of Fe…Cl(1) 3.976(5), Fe…Cl(2) 4.479(3) and Fe…Cl(3) 7.509(4) Å outside the coordination sphere. The Fe(III) ion has an octahedral coordination sphere and as expected the two oxygen donor atoms are coordinated in a -cis position. The Fe—O, Fe—Nimin and Fe—Namine distances are 1.880(3) Å, 1.931(4) Å and 2.004(4) Å, respectively.
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Published Online: 2009-9-25
Published in Print: 2006-4-1
© by Oldenbourg Wissenschaftsverlag, München
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Keywords for this article
Fe(III) metal complex;
Schiff bases;
X-ray diffraction;
Crystal structure analysis
Articles in the same Issue
- Enumeration of closest-packings by the space group: a simple approach
- Crystal chemistry study of the solid solutions in the system La2BaZnO5—Eu2BaZnO5
- Uranyl oxalate hydrates: structures and IR spectra
- The crystal structure of ZSM-10, a powder X-ray and electron diffraction study
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- Crystal structure of silver salicylate C7H5AgO3 solved by reverse Monte-Carlo method from X-ray powder diffraction data and confirmed on single crystal
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