Annealing effects, anomalous dielectric properties and conductivity of As-diluted lead phosphate Pb3(P1–xAsxO4)2
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Anatolii I. Baranov
Abstract
The influence of annealing (thermal treatment) in different atmospheres on the conductivity and dielectric properties of As-diluted lead phosphate Pb3(P1–xAsxO4)2was studied. The anomalous low frequency dielectric behavior of these crystals was found to be related to their conductive properties. A model invoking the dissociation of polar impurity complexes is proposed in order to explain the observed giant dielectric maxima and their strong frequency dispersion. It was found that extrinsic proton conductivity dominates the dielectric properties in the temperature range 350–900 K in Pb3(P1–xAsxO4)2 and that annealing in wet atmosphere increases the protonic conductivity by more than one order of magnitude.
© by Oldenbourg Wissenschaftsverlag, München
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- Crystal structure of new lanthanide diphosphates KLnP2O7 · 2 H2O (Ln = Gd, Tb, Yb)
- Annealing effects, anomalous dielectric properties and conductivity of As-diluted lead phosphate Pb3(P1–xAsxO4)2
- Effect of hydrostatic pressure on the crystal structure of sodium oxalate: X-ray diffraction study and ab initio simulations
- The transformation mechanism of the sodalite- to the melilite-topology: Thermal expansion and decomposition of bicchulite-type to melilite-type compounds
- Ab initio crystal structure determination of Bi6Rh12O29 from powder diffraction data
- The crystal structure of natural 33R moissanite from Tibet
- Structure, phase transitions and dielectric properties of a new inclusion compound of bis-thiourea pyridinium nitrate salt
- Self-association and stereochemistry study of (5R)-4-methyl-5-phenyl-1,3,4-oxadiazinan-2-one
- The crystal and molecular structures of sodium and barium complexes of dibenzo-24-crown-8 ether
- Books Received
Articles in the same Issue
- Crystal structure of new lanthanide diphosphates KLnP2O7 · 2 H2O (Ln = Gd, Tb, Yb)
- Annealing effects, anomalous dielectric properties and conductivity of As-diluted lead phosphate Pb3(P1–xAsxO4)2
- Effect of hydrostatic pressure on the crystal structure of sodium oxalate: X-ray diffraction study and ab initio simulations
- The transformation mechanism of the sodalite- to the melilite-topology: Thermal expansion and decomposition of bicchulite-type to melilite-type compounds
- Ab initio crystal structure determination of Bi6Rh12O29 from powder diffraction data
- The crystal structure of natural 33R moissanite from Tibet
- Structure, phase transitions and dielectric properties of a new inclusion compound of bis-thiourea pyridinium nitrate salt
- Self-association and stereochemistry study of (5R)-4-methyl-5-phenyl-1,3,4-oxadiazinan-2-one
- The crystal and molecular structures of sodium and barium complexes of dibenzo-24-crown-8 ether
- Books Received
