Crystal structures of the [18]-crown-6 ammoniate C12H24O6 · 2 NH3 and the cryptand [2.2.2] ammoniate C18H36O6N2 · 2 NH3
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Christof Suchentrunk
Summary
The crystal structures of the new polyether ligand-ammoniates C12H24O6 · 2 NH3 (1) and C18H36O6N2 · 2 NH3 (2) have been elucidated at 123 K by single crystal X-ray structure analysis. Compound 1 crystallizes as yellow plate-like crystals in the monoclinic space group P21/c (no. 14) with unit cell parameters a = 7.572(4) Å, b = 7.724(4) and c = 14.448(7) Å with an angle β = 91.79(6)°. It consists of a molecule of [18]-crown-6 to which two ammonia molecules of crystallisation are bound by three hydrogen bonds each. The ammonia molecules reside below and above the plane of the crown ether oxygen atoms. Compound 2 crystallizes as colourless isometric crystals in the space group P6322 (no. 182) with unit cell parameters a = 8.2568(5) Å and c = 18.992(2) Å. It consists of molecules of cryptand [2.2.2] which are connected by hydrogen bonds via ammonia molecules of crystallisation, resulting in two-dimensional layers parallel to the ab-plane.
© by Oldenbourg Wissenschaftsverlag, München
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Articles in the same Issue
- Coincidences of hypercubic lattices in 4 dimensions
- Two isostructural manganese (III) diphosphates, acid α-MnHP2O7 and double MnLiP2O7: crystal structure determination from X-ray powder diffraction data
- The crystal structure of Cu1.78Bi4.73Se8, an N = 3 pavonite homologue with a Cu-for-Bi substitution
- Variable temperature (100—295 K) single-crystal X-ray diffraction study of the α-polymorph of glycylglycine and a glycylglycine hydrate
- The structure of O-phospho-DL-threonine in potassium, sodium and ammonium environments
- A comparative study of the anisotropy of lattice strain induced in the crystals of DL-serine by cooling down to 100 K, or by increasing pressure up to 8.6 GPa. A comparison with L-serine
- Crystal structures of the [18]-crown-6 ammoniate C12H24O6 · 2 NH3 and the cryptand [2.2.2] ammoniate C18H36O6N2 · 2 NH3
- Synthesis, crystal structure and theoretical studies of aryltellurenyl tetramethylthiourea(tmtu) iodine complexes: Ph-Te(tmtu)I (1) and β-naphtyl-Te(tmtu)I (2)
