Article
Licensed
Unlicensed
Requires Authentication
Crystal structures of α and β modifications of trichlorophosphazo-N-sulfurylchloride Cl3PNSO2Cl
Published/Copyright:
July 28, 2010
Abstract
The X-ray structures of a high temperature α-phase (monoclinic, P21/c, Z = 24) and a low temperature β-phase (orthorhombic, Pbca, Z = 8) of trichlorophosphazo-N-sulfurylchloride Cl3PNSO2Cl were determined at 173 K and 150 K, respectively. Both modifications are composed of isolated molecules arranged in layers with no strong intermolecular interactions with numerous Cl … O intermolecular interactions. The molecules in both modifications are fairly eclipsed along the P … S direction, the largest deviation from an ideal position being −17.4(2)° and 22.7(3)°. The bond lengths and angles of all molecules are equal within 4σ limits with an exception of P–Cl bonds.
Published Online: 2010-7-28
Published in Print: 1997-12-1
© 2015 Oldenbourg Wissenschaftsverlag GmbH, Rosenheimer Str. 145, 81671 München
You are currently not able to access this content.
You are currently not able to access this content.
Articles in the same Issue
- Improved analysis of surface X-ray data
- Combination of α-NbOPO4 type layers with enantiomorphic α′-type layers: the “racemic structure” of α-α′-Nb0.787W0.213OPO4
- Synthese und Kristallstruktur von Mo7Sn12Zn40 – einer kubischen Verbindung mit Ikosaedern aus Ikosaedern
- The structural study of Sr4Fe6O13 using a Weissenberg technique and synchrotron radiation – unusual ionic radii of five-coordinated Fe3+ ions
- Crystal structures of α and β modifications of trichlorophosphazo-N-sulfurylchloride Cl3PNSO2Cl
- Verschiedene Aspekte der Kristallstrukturen von YbV4O8.1 III. Domänenstruktur aus parallel verwachsenen Bereichen der α-und β-Phasen und gruppentheoretische Betrachtung ihrer Symmetrie
- Clinotobermorite, Ca5[Si3O8(OH)]2 · 4 H2O \p=n-\ Ca5[Si6O17] · 5 H2O, a natural C\p=n-\S\p=n-\H(I) type cement mineral: determination of the substructure
- The structure of [C12H14N2]3[BiCl6]2 · 2H2O at room temperature
- Structure of (2S)-1-[(2R)-2,4-diphenyl-4-oxobutylideneamino]-2-(methoxymethyl) pyrrolidine
- Crystal and molecular structure of l-hypaphorine hydroiodide
- The crystal structures of two aluminium chloro-propoxides
- Structural analysis of some benzoxazoles containing strong electron donor-acceptor groups
- Anomalous elastic properties and phase transitions of (NH4)2PF7
- Elements of Inorganic Structural Chemistry. Selected Efforts to predict Structural Features
- Micro/Nanotribology and Its Applications
- Crystal structures. I. Patterns and symmetry
- Liquid Crystals in the Nineties and Beyond
- Books Received
Articles in the same Issue
- Improved analysis of surface X-ray data
- Combination of α-NbOPO4 type layers with enantiomorphic α′-type layers: the “racemic structure” of α-α′-Nb0.787W0.213OPO4
- Synthese und Kristallstruktur von Mo7Sn12Zn40 – einer kubischen Verbindung mit Ikosaedern aus Ikosaedern
- The structural study of Sr4Fe6O13 using a Weissenberg technique and synchrotron radiation – unusual ionic radii of five-coordinated Fe3+ ions
- Crystal structures of α and β modifications of trichlorophosphazo-N-sulfurylchloride Cl3PNSO2Cl
- Verschiedene Aspekte der Kristallstrukturen von YbV4O8.1 III. Domänenstruktur aus parallel verwachsenen Bereichen der α-und β-Phasen und gruppentheoretische Betrachtung ihrer Symmetrie
- Clinotobermorite, Ca5[Si3O8(OH)]2 · 4 H2O \p=n-\ Ca5[Si6O17] · 5 H2O, a natural C\p=n-\S\p=n-\H(I) type cement mineral: determination of the substructure
- The structure of [C12H14N2]3[BiCl6]2 · 2H2O at room temperature
- Structure of (2S)-1-[(2R)-2,4-diphenyl-4-oxobutylideneamino]-2-(methoxymethyl) pyrrolidine
- Crystal and molecular structure of l-hypaphorine hydroiodide
- The crystal structures of two aluminium chloro-propoxides
- Structural analysis of some benzoxazoles containing strong electron donor-acceptor groups
- Anomalous elastic properties and phase transitions of (NH4)2PF7
- Elements of Inorganic Structural Chemistry. Selected Efforts to predict Structural Features
- Micro/Nanotribology and Its Applications
- Crystal structures. I. Patterns and symmetry
- Liquid Crystals in the Nineties and Beyond
- Books Received
