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Revised crystal structure of molybdenum hydroxymonophosphate, MoO2 · H2O · P(O3OH)
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July 28, 2010
Abstract
The structure of the Kierkegaard hydroxymonophosphate has been revised. The chain-like structure of this compound is confirmed. The valence-strength based on valence length calculations, allows a new distribution of hydrogen atoms to be proposed. The structure consists of P(O3OH) tetrahedra and MoO5(H2O) octahedra, leading to the formulation MoO2 · H2O · P(O3OH) instead of Mo(OH)3PO4. The cohesion of the structure is effectuated by strong hydrogen bonds between the different chains.
Published Online: 2010-7-28
Published in Print: 1997-11-1
© 2015 Oldenbourg Wissenschaftsverlag GmbH, Rosenheimer Str. 145, 81671 München
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Articles in the same Issue
- Generalized Fibonacci numbers and coordination sequences for decorated Bethe lattices
- An improved method for analysing single crystal diffuse scattering using the Reverse Monte Carlo technique
- Enumeration of periodic tetrahedral frameworks
- Revised crystal structure of molybdenum hydroxymonophosphate, MoO2 · H2O · P(O3OH)
- The crystal structure of lithiumpentamolybdate Li4Mo5O17
- Rietveld refinement of the as synthesized and partially calcined forms of the molecular sieve GaPO4-ZON
- The crystal structure of dibenzoylmethane, C15H12O2 (enol form)
- The crystal and molecular structures of [Te(S2COR)2], R = nPr and CH2CH2CMe3
- Crystal structure of bis(diphenylglyoximato)nickel(II), Ni(pdg)2
- Unusual conformations adopted by standard amino acids in Aib-containing oligopeptides
- Physical properties and phase transitions of bis(guanidinium)zirconium bis(nitrilotriacetate)hydrate, [C(NH2)3]2Zr[N(CH2COO)3]2 · H2O
- Books Received
