Home Elastic properties and piezoelectric coupling coefficients of nitrilotriacetic acid, (N(CH2COOH)3 = NTA = H3NTA′), Li3NTA′ · 2 H2O, Na2HNTA′, K2Zr(NTA′)2 · 2 H2O, Rb2Zr(NTA′)2 · 2 H2O, Cs2Zr(NTA′)2 · H2O and (NH4)2Zr(NTA′)2
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Elastic properties and piezoelectric coupling coefficients of nitrilotriacetic acid, (N(CH2COOH)3 = NTA = H3NTA′), Li3NTA′ · 2 H2O, Na2HNTA′, K2Zr(NTA′)2 · 2 H2O, Rb2Zr(NTA′)2 · 2 H2O, Cs2Zr(NTA′)2 · H2O and (NH4)2Zr(NTA′)2

Published/Copyright: July 28, 2010
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Zeitschrift für Kristallographie - Crystalline Materials
From the journal Zeitschrift für Kristallographie - Crystalline Materials Volume 211 Issue 2

Abstract

Elastic and thermoelastic constants of nitrilotriacetic acid, N(CH2COOH)3, Li3N(CH2COO)3 · 2 H2O, Na2HN(CH2COO)3, X2Zr(N(CH2COO)3)2 · y H2O (X = K, Rb, Cs; y = 1,2) and (NH4)2Zr(N(CH2COO)3)2 were determined from ultrasonic resonance frequencies of thick plates and their shift upon variation of temperature, respectively. In addition, the piezoelectric-elastic coupling was studied by different methods.

The packing density of these species and the chemical bonding are quite similar due to the dominance of the large anions. Elastic and thermoelastic properties behave as expected for chemically related compounds. Large piezoelectric coupling coefficients >0.25 are observed on crystals of N(CH2COO)3 and X2Zr(N(CH2COO)3)2 · y H2O, whereas the other species exhibit considerably smaller coupling effects.

Published Online: 2010-7-28
Published in Print: 1996-2-1

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Articles in the same Issue

  1. The asymptotic behavior of coordination sequences for the 4-connected nets of zeolites and related structures
  2. Crystal structure, thermal expansion and elastic properties of triclinic betaine hydrogen ammonium sulfate, ((CH3)3NCH2COOH)NH4SO4
  3. Clathrate hydrates as layer structures: comparison between the structures of Type II and hypothetical Type V
  4. Darstellung und Kristallstrukturen von β-Rb2Te2 und Cs2Te2 sowie die Verfeinerung der Strukturen von Ca2P2 und Sr2As2
  5. Amorphization of quartz-type structures and a new high-pressure phase of AlAsO4
  6. Elastic properties and piezoelectric coupling coefficients of nitrilotriacetic acid, (N(CH2COOH)3 = NTA = H3NTA′), Li3NTA′ · 2 H2O, Na2HNTA′, K2Zr(NTA′)2 · 2 H2O, Rb2Zr(NTA′)2 · 2 H2O, Cs2Zr(NTA′)2 · H2O and (NH4)2Zr(NTA′)2
  7. Crystal and magnetic structure of TbCo0.5Ni0.5C2
  8. Crystal and molecular structures of bis(O-n-propyldithiocarbonato)-nickel(II) and bis(O-i-propyldithiocarbonato)nickel(II)
  9. The crystal structure of N-(3-hydroxypropyl)-hexadecanoic acid amide
  10. Crystal structure of scandium cobalt digermanide, ScCoGe2
  11. Crystal structure of ytterbium gold gallium, YbAu3Ga7 in the ScRh3Si7-type
  12. Crystal structure of tetrazirconium tetrairon heptasilicide, Zr4Fe4Si7
  13. Crystal structure of tetrakis(acetonitrile)palladium(II) bis(pentachloro-acetonitrilestannate(IV)), [Pd(CH3CN)4][SnCl5(CH3CN)]2
  14. Crystal structure of 2-ethylimidazolium toluene-p-sulfonate, (C3H4N2C2H5)(CH3C6H4SO3)
  15. Crystal structure of 1-benzylimidazolium toluene-p-sulfonate, (C3H4N2CH2C6H5)(CH3C6H4SO3)
  16. Crystal structure of 2-methylimidazolium toluene-p-sulfonate, (C3H4N2CH3)(CH3C6H4SO3)
  17. Crystal structure of 1-methylimidazolium toluene-p-sulfonate, (C3H4N2CH3)(CH3C6H4SO3)
  18. Crystal structure of tetramethylammonium 1-methyl-1,4-dicarboxybutanic acid, (N(CH3)4)(O2C(CH2)2CO2CH3)
  19. Crystal structure of 1-n-butyliodo-1-azonia-3,5-diaza-7-phosphaadamantane iodide, (C6H12PN3(CH2)4I)I
  20. Crystal structure of 1-methyl-1-azonia-3,5-diaza-7-phosphaadamantane-7-oxide tetraphenylborate, (C6H12PON3CH3) B(C6H5)4
  21. Crystal structure of 2,2-difluoro-6-methyl-4-(2,3,6,7-tetrahydro-1H,5H-benzo[i,j]quinolizin-9-yl)-1,3,2-2H-dioxaborine, C16H18BF2NO2
  22. Crystal structure of 3,5-disila-3,3,5,5-tetramethyl-3,5-dihydrodinaphtho-[2,1-c:1′,2′-e]oxepin, C24H24OSi2
  23. Crystal structure of 10E,-1,3,4,5,6,7,8,9-octahydro-11-formyl-4-methylene-3-oxo-cyclodeca[c]furan, C14H16O3
  24. Crystal structure of dimethyl-(1Z)-1,2,14-tribromo[8]paracyclophane-1-ene-10,11-dicarboxylate, C18H19Br3O4
  25. Crystal structure of 14-acetoxymethyl-10-bromo[8]metacyclophane-2-one, C17H21BrO3
  26. Crystal structure of dimethyl-9-bromo-12,12′-dichloro-10-methoxytricyclo[6.4.2.01,11]tetradeca-8,13-diene-13,14-dicarboxylate, C19H23BrCl2O5
  27. Crystal structure of dimethyl-13-chloro-1-methoxy-bicyclo[6.3.2]-trideca-8,10,12-triene-9,10-dicarboxylate, C18H23ClO5
https://doi.org/10.1524/zkri.1996.211.2.101

Articles in the same Issue

  1. The asymptotic behavior of coordination sequences for the 4-connected nets of zeolites and related structures
  2. Crystal structure, thermal expansion and elastic properties of triclinic betaine hydrogen ammonium sulfate, ((CH3)3NCH2COOH)NH4SO4
  3. Clathrate hydrates as layer structures: comparison between the structures of Type II and hypothetical Type V
  4. Darstellung und Kristallstrukturen von β-Rb2Te2 und Cs2Te2 sowie die Verfeinerung der Strukturen von Ca2P2 und Sr2As2
  5. Amorphization of quartz-type structures and a new high-pressure phase of AlAsO4
  6. Elastic properties and piezoelectric coupling coefficients of nitrilotriacetic acid, (N(CH2COOH)3 = NTA = H3NTA′), Li3NTA′ · 2 H2O, Na2HNTA′, K2Zr(NTA′)2 · 2 H2O, Rb2Zr(NTA′)2 · 2 H2O, Cs2Zr(NTA′)2 · H2O and (NH4)2Zr(NTA′)2
  7. Crystal and magnetic structure of TbCo0.5Ni0.5C2
  8. Crystal and molecular structures of bis(O-n-propyldithiocarbonato)-nickel(II) and bis(O-i-propyldithiocarbonato)nickel(II)
  9. The crystal structure of N-(3-hydroxypropyl)-hexadecanoic acid amide
  10. Crystal structure of scandium cobalt digermanide, ScCoGe2
  11. Crystal structure of ytterbium gold gallium, YbAu3Ga7 in the ScRh3Si7-type
  12. Crystal structure of tetrazirconium tetrairon heptasilicide, Zr4Fe4Si7
  13. Crystal structure of tetrakis(acetonitrile)palladium(II) bis(pentachloro-acetonitrilestannate(IV)), [Pd(CH3CN)4][SnCl5(CH3CN)]2
  14. Crystal structure of 2-ethylimidazolium toluene-p-sulfonate, (C3H4N2C2H5)(CH3C6H4SO3)
  15. Crystal structure of 1-benzylimidazolium toluene-p-sulfonate, (C3H4N2CH2C6H5)(CH3C6H4SO3)
  16. Crystal structure of 2-methylimidazolium toluene-p-sulfonate, (C3H4N2CH3)(CH3C6H4SO3)
  17. Crystal structure of 1-methylimidazolium toluene-p-sulfonate, (C3H4N2CH3)(CH3C6H4SO3)
  18. Crystal structure of tetramethylammonium 1-methyl-1,4-dicarboxybutanic acid, (N(CH3)4)(O2C(CH2)2CO2CH3)
  19. Crystal structure of 1-n-butyliodo-1-azonia-3,5-diaza-7-phosphaadamantane iodide, (C6H12PN3(CH2)4I)I
  20. Crystal structure of 1-methyl-1-azonia-3,5-diaza-7-phosphaadamantane-7-oxide tetraphenylborate, (C6H12PON3CH3) B(C6H5)4
  21. Crystal structure of 2,2-difluoro-6-methyl-4-(2,3,6,7-tetrahydro-1H,5H-benzo[i,j]quinolizin-9-yl)-1,3,2-2H-dioxaborine, C16H18BF2NO2
  22. Crystal structure of 3,5-disila-3,3,5,5-tetramethyl-3,5-dihydrodinaphtho-[2,1-c:1′,2′-e]oxepin, C24H24OSi2
  23. Crystal structure of 10E,-1,3,4,5,6,7,8,9-octahydro-11-formyl-4-methylene-3-oxo-cyclodeca[c]furan, C14H16O3
  24. Crystal structure of dimethyl-(1Z)-1,2,14-tribromo[8]paracyclophane-1-ene-10,11-dicarboxylate, C18H19Br3O4
  25. Crystal structure of 14-acetoxymethyl-10-bromo[8]metacyclophane-2-one, C17H21BrO3
  26. Crystal structure of dimethyl-9-bromo-12,12′-dichloro-10-methoxytricyclo[6.4.2.01,11]tetradeca-8,13-diene-13,14-dicarboxylate, C19H23BrCl2O5
  27. Crystal structure of dimethyl-13-chloro-1-methoxy-bicyclo[6.3.2]-trideca-8,10,12-triene-9,10-dicarboxylate, C18H23ClO5
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