Home Darstellung und Kristallstrukturen von β-Rb2Te2 und Cs2Te2 sowie die Verfeinerung der Strukturen von Ca2P2 und Sr2As2
Article
Licensed
Unlicensed Requires Authentication

Darstellung und Kristallstrukturen von β-Rb2Te2 und Cs2Te2 sowie die Verfeinerung der Strukturen von Ca2P2 und Sr2As2

Published/Copyright: July 28, 2010
Become an author with De Gruyter Brill
Submit Manuscript Author Information
Zeitschrift für Kristallographie - Crystalline Materials
From the journal Zeitschrift für Kristallographie - Crystalline Materials Volume 211 Issue 2

Abstract

Two alkali metal tellurides, which crystallize with a new type of structure, are described: Cs2Te2 type, space group Pbam, Rietveld refinement of powder data (Cs2Te2: a = 11.629(2) Å, b = 6.128(1) Å, c = 4.960(1) Å; β-Rb2Te2: a = 11.151(1) Å, b = 5.854(1) Å, c = 4.821(1) Å). This structure type may be described as a lower symmetric, distorted variant of the CsCl type. Furthermore we report the single crystal refinements of the structures of two alkaline earth pnicogenides M′2Y2(Ca2P2,Sr2As2) in order to get exact information about the bond lengths of the Y24−-dumbbells. Due to the Na2O2 type of both structures, two crystallographic independent sites exist for the pnicogen atoms. Interestingly, in both compounds two different bond lengths of the two independent dumbells Y24− are found (Ca2P2: P–P: 2.268(8) Å and 2.320(4) Å; Sr2As2: As–As: 2.521(9) Å and 2.574(5) Å).

Published Online: 2010-7-28
Published in Print: 1996-2-1

© 2015 Oldenbourg Wissenschaftsverlag GmbH, Rosenheimer Str. 145, 81671 München

Articles in the same Issue

  1. The asymptotic behavior of coordination sequences for the 4-connected nets of zeolites and related structures
  2. Crystal structure, thermal expansion and elastic properties of triclinic betaine hydrogen ammonium sulfate, ((CH3)3NCH2COOH)NH4SO4
  3. Clathrate hydrates as layer structures: comparison between the structures of Type II and hypothetical Type V
  4. Darstellung und Kristallstrukturen von β-Rb2Te2 und Cs2Te2 sowie die Verfeinerung der Strukturen von Ca2P2 und Sr2As2
  5. Amorphization of quartz-type structures and a new high-pressure phase of AlAsO4
  6. Elastic properties and piezoelectric coupling coefficients of nitrilotriacetic acid, (N(CH2COOH)3 = NTA = H3NTA′), Li3NTA′ · 2 H2O, Na2HNTA′, K2Zr(NTA′)2 · 2 H2O, Rb2Zr(NTA′)2 · 2 H2O, Cs2Zr(NTA′)2 · H2O and (NH4)2Zr(NTA′)2
  7. Crystal and magnetic structure of TbCo0.5Ni0.5C2
  8. Crystal and molecular structures of bis(O-n-propyldithiocarbonato)-nickel(II) and bis(O-i-propyldithiocarbonato)nickel(II)
  9. The crystal structure of N-(3-hydroxypropyl)-hexadecanoic acid amide
  10. Crystal structure of scandium cobalt digermanide, ScCoGe2
  11. Crystal structure of ytterbium gold gallium, YbAu3Ga7 in the ScRh3Si7-type
  12. Crystal structure of tetrazirconium tetrairon heptasilicide, Zr4Fe4Si7
  13. Crystal structure of tetrakis(acetonitrile)palladium(II) bis(pentachloro-acetonitrilestannate(IV)), [Pd(CH3CN)4][SnCl5(CH3CN)]2
  14. Crystal structure of 2-ethylimidazolium toluene-p-sulfonate, (C3H4N2C2H5)(CH3C6H4SO3)
  15. Crystal structure of 1-benzylimidazolium toluene-p-sulfonate, (C3H4N2CH2C6H5)(CH3C6H4SO3)
  16. Crystal structure of 2-methylimidazolium toluene-p-sulfonate, (C3H4N2CH3)(CH3C6H4SO3)
  17. Crystal structure of 1-methylimidazolium toluene-p-sulfonate, (C3H4N2CH3)(CH3C6H4SO3)
  18. Crystal structure of tetramethylammonium 1-methyl-1,4-dicarboxybutanic acid, (N(CH3)4)(O2C(CH2)2CO2CH3)
  19. Crystal structure of 1-n-butyliodo-1-azonia-3,5-diaza-7-phosphaadamantane iodide, (C6H12PN3(CH2)4I)I
  20. Crystal structure of 1-methyl-1-azonia-3,5-diaza-7-phosphaadamantane-7-oxide tetraphenylborate, (C6H12PON3CH3) B(C6H5)4
  21. Crystal structure of 2,2-difluoro-6-methyl-4-(2,3,6,7-tetrahydro-1H,5H-benzo[i,j]quinolizin-9-yl)-1,3,2-2H-dioxaborine, C16H18BF2NO2
  22. Crystal structure of 3,5-disila-3,3,5,5-tetramethyl-3,5-dihydrodinaphtho-[2,1-c:1′,2′-e]oxepin, C24H24OSi2
  23. Crystal structure of 10E,-1,3,4,5,6,7,8,9-octahydro-11-formyl-4-methylene-3-oxo-cyclodeca[c]furan, C14H16O3
  24. Crystal structure of dimethyl-(1Z)-1,2,14-tribromo[8]paracyclophane-1-ene-10,11-dicarboxylate, C18H19Br3O4
  25. Crystal structure of 14-acetoxymethyl-10-bromo[8]metacyclophane-2-one, C17H21BrO3
  26. Crystal structure of dimethyl-9-bromo-12,12′-dichloro-10-methoxytricyclo[6.4.2.01,11]tetradeca-8,13-diene-13,14-dicarboxylate, C19H23BrCl2O5
  27. Crystal structure of dimethyl-13-chloro-1-methoxy-bicyclo[6.3.2]-trideca-8,10,12-triene-9,10-dicarboxylate, C18H23ClO5
https://doi.org/10.1524/zkri.1996.211.2.90

Articles in the same Issue

  1. The asymptotic behavior of coordination sequences for the 4-connected nets of zeolites and related structures
  2. Crystal structure, thermal expansion and elastic properties of triclinic betaine hydrogen ammonium sulfate, ((CH3)3NCH2COOH)NH4SO4
  3. Clathrate hydrates as layer structures: comparison between the structures of Type II and hypothetical Type V
  4. Darstellung und Kristallstrukturen von β-Rb2Te2 und Cs2Te2 sowie die Verfeinerung der Strukturen von Ca2P2 und Sr2As2
  5. Amorphization of quartz-type structures and a new high-pressure phase of AlAsO4
  6. Elastic properties and piezoelectric coupling coefficients of nitrilotriacetic acid, (N(CH2COOH)3 = NTA = H3NTA′), Li3NTA′ · 2 H2O, Na2HNTA′, K2Zr(NTA′)2 · 2 H2O, Rb2Zr(NTA′)2 · 2 H2O, Cs2Zr(NTA′)2 · H2O and (NH4)2Zr(NTA′)2
  7. Crystal and magnetic structure of TbCo0.5Ni0.5C2
  8. Crystal and molecular structures of bis(O-n-propyldithiocarbonato)-nickel(II) and bis(O-i-propyldithiocarbonato)nickel(II)
  9. The crystal structure of N-(3-hydroxypropyl)-hexadecanoic acid amide
  10. Crystal structure of scandium cobalt digermanide, ScCoGe2
  11. Crystal structure of ytterbium gold gallium, YbAu3Ga7 in the ScRh3Si7-type
  12. Crystal structure of tetrazirconium tetrairon heptasilicide, Zr4Fe4Si7
  13. Crystal structure of tetrakis(acetonitrile)palladium(II) bis(pentachloro-acetonitrilestannate(IV)), [Pd(CH3CN)4][SnCl5(CH3CN)]2
  14. Crystal structure of 2-ethylimidazolium toluene-p-sulfonate, (C3H4N2C2H5)(CH3C6H4SO3)
  15. Crystal structure of 1-benzylimidazolium toluene-p-sulfonate, (C3H4N2CH2C6H5)(CH3C6H4SO3)
  16. Crystal structure of 2-methylimidazolium toluene-p-sulfonate, (C3H4N2CH3)(CH3C6H4SO3)
  17. Crystal structure of 1-methylimidazolium toluene-p-sulfonate, (C3H4N2CH3)(CH3C6H4SO3)
  18. Crystal structure of tetramethylammonium 1-methyl-1,4-dicarboxybutanic acid, (N(CH3)4)(O2C(CH2)2CO2CH3)
  19. Crystal structure of 1-n-butyliodo-1-azonia-3,5-diaza-7-phosphaadamantane iodide, (C6H12PN3(CH2)4I)I
  20. Crystal structure of 1-methyl-1-azonia-3,5-diaza-7-phosphaadamantane-7-oxide tetraphenylborate, (C6H12PON3CH3) B(C6H5)4
  21. Crystal structure of 2,2-difluoro-6-methyl-4-(2,3,6,7-tetrahydro-1H,5H-benzo[i,j]quinolizin-9-yl)-1,3,2-2H-dioxaborine, C16H18BF2NO2
  22. Crystal structure of 3,5-disila-3,3,5,5-tetramethyl-3,5-dihydrodinaphtho-[2,1-c:1′,2′-e]oxepin, C24H24OSi2
  23. Crystal structure of 10E,-1,3,4,5,6,7,8,9-octahydro-11-formyl-4-methylene-3-oxo-cyclodeca[c]furan, C14H16O3
  24. Crystal structure of dimethyl-(1Z)-1,2,14-tribromo[8]paracyclophane-1-ene-10,11-dicarboxylate, C18H19Br3O4
  25. Crystal structure of 14-acetoxymethyl-10-bromo[8]metacyclophane-2-one, C17H21BrO3
  26. Crystal structure of dimethyl-9-bromo-12,12′-dichloro-10-methoxytricyclo[6.4.2.01,11]tetradeca-8,13-diene-13,14-dicarboxylate, C19H23BrCl2O5
  27. Crystal structure of dimethyl-13-chloro-1-methoxy-bicyclo[6.3.2]-trideca-8,10,12-triene-9,10-dicarboxylate, C18H23ClO5
Sign up now to receive a 20% welcome discount
Institutional Access
How does access work?
Have an idea on how to improve our website?
Please write us.
© 2025 De Gruyter Brill
Downloaded on 15.9.2025 from https://www.degruyterbrill.com/document/doi/10.1524/zkri.1996.211.2.90/html
Scroll to top button