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Crystal structure of diaquadichlorodimethyltin · 15-crown-5

Published/Copyright: July 28, 2010
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Zeitschrift für Kristallographie - Crystalline Materials
From the journal Zeitschrift für Kristallographie - Crystalline Materials Volume 209 Issue 7

Abstract

Dimethyltin dichloride crystallizes with 15-crown-5 from methanol as the diaqua complex, (CH3)2SnCl2 · 2H2O · 15-crown-5, C12H30Cl2O7Sn, which is monoclinic in the C2/c space group (a = 9.313(2) Å, b = 17.266(3) Å, c = 13.525(3) Å, β = 107.37(2)°; Z = 4). The tin atom occupies a distorted (trans-CH3, cis-Cl, cis-H2O octahedral site (C–Sn–C = 157.5(3)°, Sn—Cl = 2.474(1), Sn—O = 2.460(4) Å). The oxygen atoms of the polyether point away from the center of the ring and the Owater[unk]Ocrown ether distances all exceed 3.5 Å.

Published Online: 2010-7-28
Published in Print: 1994-7-1

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Articles in the same Issue

  1. An introduction to magnetic photon scattering. Studies of condensed matter
  2. Edgeworth series probability distribution of intensity for spacegroup P21/c
  3. The phase equations of crystal structure analysis
  4. Helical [unk](P1−) chains in the structures of Hg2P3Br and Hg2P3Cl
  5. The crystal structure of BaCuO2 at 193 K
  6. Structure of URuAl by single-crystal neutron diffraction at 120 K
  7. The crystal structure of Z-Leu-Aib-Pro-Leuol, the synthetic, protected C-terminal tetrapeptide of trichovirin
  8. Structure of 1,1′-dinapthoxymethanephenyloxyphosphinesulphide1
  9. Crystal structure and spectra of the mixed-ligands complex 1-(2-thenoyl)-2-[1′(2″-pyridyl)-ethylidene]hydrazino-acetato lead(II)
  10. Crystal structure of 2,2-di-tert-butyl-3-cyclohexyl-4,5-diphenyl-1-oxa-2-sila-3-aza-4-cyclopentene1
  11. Crystal structure of diaquadichlorodimethyltin · 15-crown-5
  12. Crystal structure of lithium copper molybdate, Li2Cu2(MoO4)3
  13. Crystal structure of aluminum sodium pyrophosphate, NaAlP2O7
  14. Crystal structure of lithium magnesium dinitridoborate, LiMgBN2
  15. Crystal structure of lithium tetraeuropium tris(dinitridoborate), LiEu4(BN2)3
  16. Crystal structure of hexaaquacobalt(II) hexafluorostannate(IV), (Co(H2O)6)(SnF6)
  17. Crystal structure of bis(triphenylphosphine)nitrogen tetraphenylborate, ((C6H5)3P)2N(C6H5)4B
  18. Crystal structure of bis[chloro-1kCl-μ-hydroxo-μ-oxo-(tetraphenyl-1K2C,2K2C)ditin], [Cl(C6H5)2Sn(OH)OSn(C6H5)2]2
  19. Crystal structure of μ-oxalato-bis[di-(2-aminoethyl)amine-copper(II)] diperchlorate monohydrate, (C4H13N3Cu)2(C2O4)(ClO4)2 · H2O
  20. Crystal structure of methylcyclopentadienylnitrosyl-2-aminophenyl-diphenylphosphinemanganese(I)hexafluorophosphate chloroform solvate (1/1), C25H24Cl3F6MnN2OP2
  21. Crystal structure of 2,2′-dioxapropyl-bis[5(2-methylpropyl)phenyl]ethyne, C25H30O2
  22. Crystal structure of 1-methoxycarbonylethyl-2,8,9-trioxa-5-azal-germa-tricyclo3,3,3,01,5]-undecane, N(C2H4O)3GeC2H4COOCH3
  23. Crystal structure of 1-methoxycarbonyl-1′-methylethyl-2,8,9-trioxa-5-aza-1-germa-tricyclot[3,3,3,01,5]-undecane, N(C2H4O)3GeC3H6COOCH3
  24. Crystal structure of tetrachlorobis(triphenylarsine oxide)titanium(IV), ((C6H5)3AsO)2TiCl4 · 2CH2Cl2
https://doi.org/10.1524/zkri.1994.209.7.613

Articles in the same Issue

  1. An introduction to magnetic photon scattering. Studies of condensed matter
  2. Edgeworth series probability distribution of intensity for spacegroup P21/c
  3. The phase equations of crystal structure analysis
  4. Helical [unk](P1−) chains in the structures of Hg2P3Br and Hg2P3Cl
  5. The crystal structure of BaCuO2 at 193 K
  6. Structure of URuAl by single-crystal neutron diffraction at 120 K
  7. The crystal structure of Z-Leu-Aib-Pro-Leuol, the synthetic, protected C-terminal tetrapeptide of trichovirin
  8. Structure of 1,1′-dinapthoxymethanephenyloxyphosphinesulphide1
  9. Crystal structure and spectra of the mixed-ligands complex 1-(2-thenoyl)-2-[1′(2″-pyridyl)-ethylidene]hydrazino-acetato lead(II)
  10. Crystal structure of 2,2-di-tert-butyl-3-cyclohexyl-4,5-diphenyl-1-oxa-2-sila-3-aza-4-cyclopentene1
  11. Crystal structure of diaquadichlorodimethyltin · 15-crown-5
  12. Crystal structure of lithium copper molybdate, Li2Cu2(MoO4)3
  13. Crystal structure of aluminum sodium pyrophosphate, NaAlP2O7
  14. Crystal structure of lithium magnesium dinitridoborate, LiMgBN2
  15. Crystal structure of lithium tetraeuropium tris(dinitridoborate), LiEu4(BN2)3
  16. Crystal structure of hexaaquacobalt(II) hexafluorostannate(IV), (Co(H2O)6)(SnF6)
  17. Crystal structure of bis(triphenylphosphine)nitrogen tetraphenylborate, ((C6H5)3P)2N(C6H5)4B
  18. Crystal structure of bis[chloro-1kCl-μ-hydroxo-μ-oxo-(tetraphenyl-1K2C,2K2C)ditin], [Cl(C6H5)2Sn(OH)OSn(C6H5)2]2
  19. Crystal structure of μ-oxalato-bis[di-(2-aminoethyl)amine-copper(II)] diperchlorate monohydrate, (C4H13N3Cu)2(C2O4)(ClO4)2 · H2O
  20. Crystal structure of methylcyclopentadienylnitrosyl-2-aminophenyl-diphenylphosphinemanganese(I)hexafluorophosphate chloroform solvate (1/1), C25H24Cl3F6MnN2OP2
  21. Crystal structure of 2,2′-dioxapropyl-bis[5(2-methylpropyl)phenyl]ethyne, C25H30O2
  22. Crystal structure of 1-methoxycarbonylethyl-2,8,9-trioxa-5-azal-germa-tricyclo3,3,3,01,5]-undecane, N(C2H4O)3GeC2H4COOCH3
  23. Crystal structure of 1-methoxycarbonyl-1′-methylethyl-2,8,9-trioxa-5-aza-1-germa-tricyclot[3,3,3,01,5]-undecane, N(C2H4O)3GeC3H6COOCH3
  24. Crystal structure of tetrachlorobis(triphenylarsine oxide)titanium(IV), ((C6H5)3AsO)2TiCl4 · 2CH2Cl2
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