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The crystal structure of tetraethylammonium tetrafluoroborate, (C2H5)4NBF4

Published/Copyright: July 28, 2010
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Zeitschrift für Kristallographie - Crystalline Materials
From the journal Zeitschrift für Kristallographie - Crystalline Materials Volume 209 Issue 6

Abstract

Mr = 217.06, monoclinic, Cc, a = 12.471(8) Å, b = 7.381(6) Å, c = 14.191(5) Å, β = 115.58(5)°, V = 1178(1) Å3, Z = 4, Dm = 1.232(5) g cm−3, Dx = 1.224g cm−3, λ(MoKα) = 0.7107 Å, μ = 1.12cm−1, F(000) = 464, R = 0.055 for 464 unique reflections with / > 3σ(I). The interaction compound is formed by the tetraethylammonium cation and the tetrafluoroborate anion. The remarkable features of this crystal at 298 K are: i) the non centrosymmetric structure; ii) the ordered distribution of the fluoroborate tetrahedra associated with the substituted ammonium ions, also confirmed by NMR measurements, which is very different from the disordered configuration of the BF4 group in (CH3)4NBF4.

Published Online: 2010-7-28
Published in Print: 1994-6-1

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Articles in the same Issue

  1. Refinement of the crystal structure of hutchinsonite, TlPbAs5S9
  2. Refinement of the Fe4Al13 structure and its relationship to the quasihomological homeotypical structures
  3. Structure of solid trichlorofluoromethane, CFCl3, by powder neutron diffraction
  4. Refinements of the crystal structures and UV-absorption properties of KBrO3, RbBrO3 and CsBrO3
  5. Structure cristalline et moléculaire de la 3-acétoacétyl-7-méthyl-2H,5Hpyrano-(4,3b)pyran-2,5-dione: C13H906
  6. The crystal structure of 5-bromo-7-nitroindoline
  7. Crystal structure and spectra of a complex resulting from copper (II) nitrate with the bis Schiff base of thiophene-2-aldehyde and diethylene triamine
  8. Structure of 1-carbamoyl-3-phenyl-(1,2-dideoxy-α-D-glucofurano) [1,2-d]imidazolidin-2-one
  9. The crystal structure of tetraethylammonium tetrafluoroborate, (C2H5)4NBF4
  10. Molecular structure of an O-blocked form of ACRL Toxin I
  11. The “tube” structure of 1,7-bis(dimethylamino)-heptamethinium tetrafluoroborate, a streptocyanine dye
  12. Compression mechanism in trioxane silica sodalite, [Si12O24] · 2 C3H6O3
  13. Crystal structure of (S)-1-cyano-2-(1′-phenylethyl)-isoindole1
  14. Crystal structure of S′,5′-dimethylphenyl 3-bromo-4,6,7-trimethoxy-2-naphthoate1
  15. Crystal structure of biphenylenyliodonium[bis(phenylsulphonyl)] methylsulphonylmethylide, C28H21IO6S3
  16. Crystal structure of the 4-methylthio-4′-[3-sulfonatopropyl]-stilbazolium monohydrate orthorhombic phase: a very efficient nonlinear optical crystalline material
  17. Crystal structures of silver (I) nicotinate and silver (I) isonicotinate tetrahydrate
  18. A curved vacuum deposited thin film sample holder for Seemann-Bohlin diffractometer
  19. Crystal structure of potassium indium germanium, K8In6Ge40
  20. Crystal structure of sodium copper cadmium gallium, Na34Cu7Cd6Ga92
  21. Crystal structure of sodium tetraiodoaluminate (III), NaAlI4
  22. Crystal structure of 11-(E)-benzylidene-4-pheriyl-2,4,6-triazatricyclo[5.4.2.02,6]-trideca-8,12-diene-3,5-dione, C23H19N3O2
  23. Crystal structure of diphenylphosphinic acid (redetermination at 173 K), C12H11O2P
  24. Crystal structure of bis[tris(pyrazol-1-yl)methane]cobalt(II) nitrate (redetermination at 173 K), C20H20CoN14O6
  25. Crystal structure of l,l,2,2-tetrakis(2-methoxy-5-methyl-3-tbutyl phenyl) ethane, C50H70O4
  26. Crystal structure of bis(bis(triphenylphosphane)-μ-N,Ocyanoacetato)copper(I)tetrahydrofuran, C86H80CU2N2O6P4
  27. Crystal structure of bis((l,4,7,11-tetraazacyclotetradecane)chlorozinc(II)) tetrachlorozincate(II), (ZnCl(C10H20N4))2(ZnCl4)
  28. Crystal structure of 2,3-hexanedione-dioxime, H3CC(NOH)C(NOH)CH2CH2CH3
  29. Crystal structure of phenyl(2-benzoylaminostyryl)thioketone, C22H17NOS
  30. Crystal structure of 3,9-diphenoxy-2,4,8,10-tetraoxa-3,9diphosphaspiro[5.5] undecane-3,9-dioxide, C17H18O8P2
  31. Crystal structure of 2,5,8-trithia[9]-o-benzenophane, C12H16S3
  32. Crystal-Quasicrystal Transitions.
  33. Symmetrie und Struktur in der Chemie.
  34. Kristallographie. Eine Einführung für Naturwissenschaftler.
  35. Applied Group Theory. For Physicists and Chemists.
  36. Inorganic Structural Chemistry.
https://doi.org/10.1524/zkri.1994.209.6.509

Articles in the same Issue

  1. Refinement of the crystal structure of hutchinsonite, TlPbAs5S9
  2. Refinement of the Fe4Al13 structure and its relationship to the quasihomological homeotypical structures
  3. Structure of solid trichlorofluoromethane, CFCl3, by powder neutron diffraction
  4. Refinements of the crystal structures and UV-absorption properties of KBrO3, RbBrO3 and CsBrO3
  5. Structure cristalline et moléculaire de la 3-acétoacétyl-7-méthyl-2H,5Hpyrano-(4,3b)pyran-2,5-dione: C13H906
  6. The crystal structure of 5-bromo-7-nitroindoline
  7. Crystal structure and spectra of a complex resulting from copper (II) nitrate with the bis Schiff base of thiophene-2-aldehyde and diethylene triamine
  8. Structure of 1-carbamoyl-3-phenyl-(1,2-dideoxy-α-D-glucofurano) [1,2-d]imidazolidin-2-one
  9. The crystal structure of tetraethylammonium tetrafluoroborate, (C2H5)4NBF4
  10. Molecular structure of an O-blocked form of ACRL Toxin I
  11. The “tube” structure of 1,7-bis(dimethylamino)-heptamethinium tetrafluoroborate, a streptocyanine dye
  12. Compression mechanism in trioxane silica sodalite, [Si12O24] · 2 C3H6O3
  13. Crystal structure of (S)-1-cyano-2-(1′-phenylethyl)-isoindole1
  14. Crystal structure of S′,5′-dimethylphenyl 3-bromo-4,6,7-trimethoxy-2-naphthoate1
  15. Crystal structure of biphenylenyliodonium[bis(phenylsulphonyl)] methylsulphonylmethylide, C28H21IO6S3
  16. Crystal structure of the 4-methylthio-4′-[3-sulfonatopropyl]-stilbazolium monohydrate orthorhombic phase: a very efficient nonlinear optical crystalline material
  17. Crystal structures of silver (I) nicotinate and silver (I) isonicotinate tetrahydrate
  18. A curved vacuum deposited thin film sample holder for Seemann-Bohlin diffractometer
  19. Crystal structure of potassium indium germanium, K8In6Ge40
  20. Crystal structure of sodium copper cadmium gallium, Na34Cu7Cd6Ga92
  21. Crystal structure of sodium tetraiodoaluminate (III), NaAlI4
  22. Crystal structure of 11-(E)-benzylidene-4-pheriyl-2,4,6-triazatricyclo[5.4.2.02,6]-trideca-8,12-diene-3,5-dione, C23H19N3O2
  23. Crystal structure of diphenylphosphinic acid (redetermination at 173 K), C12H11O2P
  24. Crystal structure of bis[tris(pyrazol-1-yl)methane]cobalt(II) nitrate (redetermination at 173 K), C20H20CoN14O6
  25. Crystal structure of l,l,2,2-tetrakis(2-methoxy-5-methyl-3-tbutyl phenyl) ethane, C50H70O4
  26. Crystal structure of bis(bis(triphenylphosphane)-μ-N,Ocyanoacetato)copper(I)tetrahydrofuran, C86H80CU2N2O6P4
  27. Crystal structure of bis((l,4,7,11-tetraazacyclotetradecane)chlorozinc(II)) tetrachlorozincate(II), (ZnCl(C10H20N4))2(ZnCl4)
  28. Crystal structure of 2,3-hexanedione-dioxime, H3CC(NOH)C(NOH)CH2CH2CH3
  29. Crystal structure of phenyl(2-benzoylaminostyryl)thioketone, C22H17NOS
  30. Crystal structure of 3,9-diphenoxy-2,4,8,10-tetraoxa-3,9diphosphaspiro[5.5] undecane-3,9-dioxide, C17H18O8P2
  31. Crystal structure of 2,5,8-trithia[9]-o-benzenophane, C12H16S3
  32. Crystal-Quasicrystal Transitions.
  33. Symmetrie und Struktur in der Chemie.
  34. Kristallographie. Eine Einführung für Naturwissenschaftler.
  35. Applied Group Theory. For Physicists and Chemists.
  36. Inorganic Structural Chemistry.
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