Home Solid state polymerization of diacetylenes
Article
Licensed
Unlicensed Requires Authentication

Solid state polymerization of diacetylenes

5*. Crystal and molecular structure of 1,6-bis(1-oxyl-2,2,6,6-tetramethyl-4-hydroxypiperidine-4-yl)-hexa-2,4-diyne
Published/Copyright: August 25, 2010
Become an author with De Gruyter Brill
Submit Manuscript Author Information
Zeitschrift für Kristallographie
From the journal Zeitschrift für Kristallographie Volume 191 Issue 1-2

Abstract

An X-ray structural study (R = 0.043 for 2704 reflections) of C24H30N2O4 was carried out. The molecule has a skewed conformation, the piperidine cycles are in a chair conformation. The N atoms of paramagnetic groups exhibit different degrees of pyramidalization, due to crystal packing effects, their displacements from the planes of three bonded atoms being 0.111 and 0.042(2) Å. The H-bonds of the O – H … O type link the molecules into layers parallel to the ac-plane. The molecules do not form characteristic stacking necessary for the topochemical solid state polymerization. This fact is in good agreement with the observed inertness of the crystals with respect to the solid state polymerization.

Published Online: 2010-08-25
Published in Print: 1990

Articles in the same Issue

  1. Solid state polymerization of diacetylenes
  2. Solid state polymerization of diacetylenes 4*
  3. Solid state polymerization of diacetylenes
  4. Search tree method for the determination of similarity operators between arbitrary lattices
  5. Bond valence VS bond length and Pauling's bond strength: The Ca – O bond
  6. Geometrische Größen und einfache Modellrechnungen für BO4-Gruppen
  7. The crystal structure of 1-methyltriphenylene
  8. Structure cristalline de la (1R,5R)-(+)-dibenzyl-3,3 nopinone. Dichroïsme circulaire des dérivés dialkylés de la nopinone
  9. Neutron powder investigation of CuI*
  10. Single crystal structure refinement of high-pressure ZnGeO3 ilmenite
  11. Structural investigation of an antimony-rich pinakiolite, Mg1.90Mn0.91Sb0.19O2BO3, from Långban, Sweden
  12. The crystal structure of δ-yttrium pyrosilicate, δ-Y2Si2O7
  13. Crystal structure of mimetite, Pb5(AsO4)3Cl
  14. Advanced Techniques for Microstructural Characterization
  15. New Crystal Structures
  16. Crystal structure of silver pentabromodiplumbate, AgPb2Br5
  17. Crystal structure refinement of rubidium vanadium diphosphate, RbVP2O7
  18. Crystal structure of niobium pentachloride, NbCl5
  19. Crystal structure of copper(I) tetrachlorogallate, CuGaCl4
  20. Crystal structure of η5-cyclopentadienyl-di-η2-(tert.butylamine-diallyl)cobalt(II), (C5H5)CoC6H10NC(CH3)3
  21. Crystal structure of 8-(α-phenylethyl)-aminochinolin-palladium(II) chloride, (C9H6N)PdCl2(NH(CH3)(CH)(C6H5))
  22. Crystal structure refinement of decacarbonylbis(triphenylphosphine)tetrairidium, (CO)10(P(C6H5)3)2Ir4
  23. Crystal structure of nonacarbonyl-trimethylphosphine-dimanganese, ((CH3)3P)(CO)4Mn2(CO)5
  24. Crystal structure of diaqua-bis(diaminoethane)-copper bis(1-oxo-1,2-diphenyl-3,3,5-tricarbbutoxy-1,2-diphosphacyclopentanonate) bis(methanol), (H2O)2Cu(C2H8N2)2(C30H37O8P2)2(CH3OH)2
https://doi.org/10.1524/zkri.1990.191.1-2.15

Articles in the same Issue

  1. Solid state polymerization of diacetylenes
  2. Solid state polymerization of diacetylenes 4*
  3. Solid state polymerization of diacetylenes
  4. Search tree method for the determination of similarity operators between arbitrary lattices
  5. Bond valence VS bond length and Pauling's bond strength: The Ca – O bond
  6. Geometrische Größen und einfache Modellrechnungen für BO4-Gruppen
  7. The crystal structure of 1-methyltriphenylene
  8. Structure cristalline de la (1R,5R)-(+)-dibenzyl-3,3 nopinone. Dichroïsme circulaire des dérivés dialkylés de la nopinone
  9. Neutron powder investigation of CuI*
  10. Single crystal structure refinement of high-pressure ZnGeO3 ilmenite
  11. Structural investigation of an antimony-rich pinakiolite, Mg1.90Mn0.91Sb0.19O2BO3, from Långban, Sweden
  12. The crystal structure of δ-yttrium pyrosilicate, δ-Y2Si2O7
  13. Crystal structure of mimetite, Pb5(AsO4)3Cl
  14. Advanced Techniques for Microstructural Characterization
  15. New Crystal Structures
  16. Crystal structure of silver pentabromodiplumbate, AgPb2Br5
  17. Crystal structure refinement of rubidium vanadium diphosphate, RbVP2O7
  18. Crystal structure of niobium pentachloride, NbCl5
  19. Crystal structure of copper(I) tetrachlorogallate, CuGaCl4
  20. Crystal structure of η5-cyclopentadienyl-di-η2-(tert.butylamine-diallyl)cobalt(II), (C5H5)CoC6H10NC(CH3)3
  21. Crystal structure of 8-(α-phenylethyl)-aminochinolin-palladium(II) chloride, (C9H6N)PdCl2(NH(CH3)(CH)(C6H5))
  22. Crystal structure refinement of decacarbonylbis(triphenylphosphine)tetrairidium, (CO)10(P(C6H5)3)2Ir4
  23. Crystal structure of nonacarbonyl-trimethylphosphine-dimanganese, ((CH3)3P)(CO)4Mn2(CO)5
  24. Crystal structure of diaqua-bis(diaminoethane)-copper bis(1-oxo-1,2-diphenyl-3,3,5-tricarbbutoxy-1,2-diphosphacyclopentanonate) bis(methanol), (H2O)2Cu(C2H8N2)2(C30H37O8P2)2(CH3OH)2
Sign up now to receive a 20% welcome discount
Institutional Access
How does access work?
Have an idea on how to improve our website?
Please write us.
© 2025 De Gruyter Brill
Downloaded on 26.9.2025 from https://www.degruyterbrill.com/document/doi/10.1524/zkri.1990.191.1-2.15/html
Scroll to top button