Article
Licensed
Unlicensed
Requires Authentication
Solid state polymerization of diacetylenes
3.* Crystal and molecular structure of 1,4-bis(1-oxyl-2,2,6,6-tetramethyl-4-hydroxy-piperidine-4-yl)butadiyne
Published/Copyright:
August 25, 2010
Abstract
An X-ray structural study (R = 0.040 for 1871 reflections) of the title compound has been carried out. Molecules in crystal are pseudocentrosymmetric, the piperidine cycle is in a chair conformation. The N atoms of both paramagnetic centers exhibit, in fact, the same degree of pyramidalization, their displacements from the planes of their bonded atoms being 0.111 and 0.119(2) Å. In crystal the molecules form two sets of infinite ribbons (along the [112] and [[unk]12] directions), which are linked with each other via the O – H … O hydrogen bonds along the [001] direction. Although the packing of diacetylene rod-like groups does not correspond to the conditions of topochemical polymerization of diacetylenes, compound I polymerizes in crystal.
Published Online: 2010-08-25
Published in Print: 1990
You are currently not able to access this content.
You are currently not able to access this content.
Articles in the same Issue
- Solid state polymerization of diacetylenes
- Solid state polymerization of diacetylenes 4*
- Solid state polymerization of diacetylenes
- Search tree method for the determination of similarity operators between arbitrary lattices
- Bond valence VS bond length and Pauling's bond strength: The Ca – O bond
- Geometrische Größen und einfache Modellrechnungen für BO4-Gruppen
- The crystal structure of 1-methyltriphenylene
- Structure cristalline de la (1R,5R)-(+)-dibenzyl-3,3 nopinone. Dichroïsme circulaire des dérivés dialkylés de la nopinone
- Neutron powder investigation of CuI*
- Single crystal structure refinement of high-pressure ZnGeO3 ilmenite
- Structural investigation of an antimony-rich pinakiolite, Mg1.90Mn0.91Sb0.19O2BO3, from Långban, Sweden
- The crystal structure of δ-yttrium pyrosilicate, δ-Y2Si2O7
- Crystal structure of mimetite, Pb5(AsO4)3Cl
- Advanced Techniques for Microstructural Characterization
- New Crystal Structures
- Crystal structure of silver pentabromodiplumbate, AgPb2Br5
- Crystal structure refinement of rubidium vanadium diphosphate, RbVP2O7
- Crystal structure of niobium pentachloride, NbCl5
- Crystal structure of copper(I) tetrachlorogallate, CuGaCl4
- Crystal structure of η5-cyclopentadienyl-di-η2-(tert.butylamine-diallyl)cobalt(II), (C5H5)CoC6H10NC(CH3)3
- Crystal structure of 8-(α-phenylethyl)-aminochinolin-palladium(II) chloride, (C9H6N)PdCl2(NH(CH3)(CH)(C6H5))
- Crystal structure refinement of decacarbonylbis(triphenylphosphine)tetrairidium, (CO)10(P(C6H5)3)2Ir4
- Crystal structure of nonacarbonyl-trimethylphosphine-dimanganese, ((CH3)3P)(CO)4Mn2(CO)5
- Crystal structure of diaqua-bis(diaminoethane)-copper bis(1-oxo-1,2-diphenyl-3,3,5-tricarbbutoxy-1,2-diphosphacyclopentanonate) bis(methanol), (H2O)2Cu(C2H8N2)2(C30H37O8P2)2(CH3OH)2
Articles in the same Issue
- Solid state polymerization of diacetylenes
- Solid state polymerization of diacetylenes 4*
- Solid state polymerization of diacetylenes
- Search tree method for the determination of similarity operators between arbitrary lattices
- Bond valence VS bond length and Pauling's bond strength: The Ca – O bond
- Geometrische Größen und einfache Modellrechnungen für BO4-Gruppen
- The crystal structure of 1-methyltriphenylene
- Structure cristalline de la (1R,5R)-(+)-dibenzyl-3,3 nopinone. Dichroïsme circulaire des dérivés dialkylés de la nopinone
- Neutron powder investigation of CuI*
- Single crystal structure refinement of high-pressure ZnGeO3 ilmenite
- Structural investigation of an antimony-rich pinakiolite, Mg1.90Mn0.91Sb0.19O2BO3, from Långban, Sweden
- The crystal structure of δ-yttrium pyrosilicate, δ-Y2Si2O7
- Crystal structure of mimetite, Pb5(AsO4)3Cl
- Advanced Techniques for Microstructural Characterization
- New Crystal Structures
- Crystal structure of silver pentabromodiplumbate, AgPb2Br5
- Crystal structure refinement of rubidium vanadium diphosphate, RbVP2O7
- Crystal structure of niobium pentachloride, NbCl5
- Crystal structure of copper(I) tetrachlorogallate, CuGaCl4
- Crystal structure of η5-cyclopentadienyl-di-η2-(tert.butylamine-diallyl)cobalt(II), (C5H5)CoC6H10NC(CH3)3
- Crystal structure of 8-(α-phenylethyl)-aminochinolin-palladium(II) chloride, (C9H6N)PdCl2(NH(CH3)(CH)(C6H5))
- Crystal structure refinement of decacarbonylbis(triphenylphosphine)tetrairidium, (CO)10(P(C6H5)3)2Ir4
- Crystal structure of nonacarbonyl-trimethylphosphine-dimanganese, ((CH3)3P)(CO)4Mn2(CO)5
- Crystal structure of diaqua-bis(diaminoethane)-copper bis(1-oxo-1,2-diphenyl-3,3,5-tricarbbutoxy-1,2-diphosphacyclopentanonate) bis(methanol), (H2O)2Cu(C2H8N2)2(C30H37O8P2)2(CH3OH)2
