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A comparative study of the crystal structures of Ba(ClO3)2, Ba(BrO3)2 II, Pb(ClO3)2, and Sr(ClO3)2
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August 25, 2010
Abstract
The crystal structures of the isotypic orthorhombic alkaline earth and lead halates Ba(ClO3)2, Ba(BrO3)2 II, and Pb(ClO3)2 [Sr(ClO3)2-type, oF72, Fdd2, Z = 8] were determined by single crystal X-ray diffraction data.
The final R values (number of observed unique reflections) are 0.033(854), 0.067(853), and 0.051(720). The data obtained are compared with those of Sr(ClO3)2 and discussed in terms of metal oxygen coordination and distortion of the halate ions, respectively. A stereochemical effect of the lone-pair of the lead ion is not observed.
Published Online: 2010-08-25
Published in Print: 1989
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- A redetermination of the crystal structure of cupric chloride dihydrate
- Crystal data and crystal structure for silver cyclohexaphosphate monohydrate: Ag6P6O18 · H2O
- On the microstructure of a rapidly quenched Mn4Si alloy
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