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NaxMoP2O7, a mixed valence molybdenum diphosphate with a tunnel structure
Published/Copyright:
August 25, 2010
Abstract
The crystal structure of Na0.3MoP2O7 has been solved by three-dimensional single crystal X-ray analysis. The refinement in the cell of symmetry P[unk] with a = 4.8813(6) Å, b = 7.0110(5) Å, c = 8.2563(4) Å, α = 91.400(5) Å, β = 92.466(8)°, γ = 106.551(9)°, Z = 2 has led to R = 0.030 and Rw = 0.031 for 3327 reflections with I ≥ 3σ(I). The framework of the structure, built up from corner-sharing MoO6 octahedra and diphosphate groups, delimits large octogonal tunnels where the Na+ ions are located. This structure is closely related to that of NaMoP2O7 which differs only by the stacking of similar layers.
Published Online: 2010-08-25
Published in Print: 1988
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Articles in the same Issue
- The crystal and molecular structure of aceto-acetanilide hydrazone pigment N-phenyl-2-(4-chloro-phenylhydrazono)-3-oxo-butyramide
- The crystal and molecular structure of azo disperse dye 3-(4-diethylamino-phenyl-azo)phthalimide
- Crystal structure and bonding of tris(3-methylpyridinium)(3-ethylpyridinium) β-octamolybdate
- Structure cristalline d'un chloro-silico-chromate de plomb, Pb5(CrO4,SiO4)3Cl
- The single chain arsenites Pb(AsO2)Cl and Pb2(AsO2)3Cl. Preparation and structure investigation
- Crystal state conformation of a β,β′-disubstituted dehydroaminoacid derivative
- Room temperature X-ray crystal structure analysis of a twinned crystal of high-Tc superconducting YBa2Cu3O7−x(0 ≤ x ≤ 0.10)
- Crystal structure and optical properties of potassium pentafluorohafnate monohydrate, KHfF5 · H2O
- The structures of crystalline hydrogen bromide
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- The oxygen packings of low-quartz and ReO3 under high pressure
- Indigo: Crystal structure refinement based on synchrotron data
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- Crystal structure of iodanilic acid
- Can X-ray crystal structure analysis decide between twinning by pseudo-merohedry and statistical distribution in YBa2Cu3O7?
