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Crystal structure of molybdenum hexacarbonyl

Published/Copyright: August 25, 2010
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Zeitschrift für Kristallographie - Crystalline Materials
From the journal Zeitschrift für Kristallographie - Crystalline Materials Volume 166 Issue 3-4

Abstract

Crystals of molybdenum hexacarbonyl are orthorhombic, with a = 12.019(2), b = 11.415(2), c = 6.488(1) Å, space group Pnma, and Z = 4. The structure has been refined to RF = 0.025 for 1316 observed MoKα. data. The Mo(CO)6 octahedron conforms closely to idealized m3m symmetry, and the averages of chemically equivalent bond lengths are: Mo – C = 2.059(3) Å and C – O = 1.125(5) Å.

Published Online: 2010-8-25
Published in Print: 1984-2-1

© 2015 Oldenbourg Wissenschaftsverlag GmbH, Rosenheimer Str. 145, 81671 München

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  1. Crystallographic studies of olivine-related sarcopside-type solid solutions
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  3. Crystal structure of anhydrous zinc bromide
  4. P.B.C.-vector analysis by Fourier transform of morphology. On crystal growth of monoclinic potassium feldspars*
  5. Die Kristall- und Molekülstruktur des Tris(ethylendiamin)cadmium(II)-dibenzohydroxamathydrates, CdC20H38O5N8
  6. Die Kristall- und Molekülstruktur von 4-Dimethylaminopyridin C7H10N2
  7. Structure refinement of scolecite by neutron diffraction
  8. The crystal and molecular structure of [4]peristylanedione, C12H12O2
  9. Experimental difference densities of hexacyanobenzene at 120 K. Refinement of electron density distributions with charge-cloud models
  10. Die Kristallstruktur von Na4CaSi3O9 und dessen strukturelle Beziehungen zu K4SrGe3O9 und Ca3Al2O6
  11. Die Kristallstruktur von Ba2Ni(N3)6 · 3H2O
  12. X-ray studies on protoenstatite
  13. Crystal structure of molybdenum hexacarbonyl
  14. Ungewöhnliche lineare, oligomere Anionen [GanSe2n + 2](n + 4) − (n = 2,4,6) in festen Selenogallaten des Cäsiums
  15. Seltenerdaluminate SEAl11O18, SEMgAl11O19 und SELi0,5Al11,519
  16. The crystal structure of Cs0.35Al0.35Si2.65O6, a cesium-aluminosilicate with the bikitaite framework
  17. Crystal structure of 2-oxo-5-(exo)-6-(endo)-bis(phenylsulfonyl)-7,8-benzobicyclo [2.2.2] oct-7-ene
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https://doi.org/10.1524/zkri.1984.166.3-4.277

Articles in the same Issue

  1. Crystallographic studies of olivine-related sarcopside-type solid solutions
  2. The crystal structure of aceto-acetanilide azo-pigments III C.I. Pigment Yellow 1, α-(1-hydroxyethylidene) acetanilide-α-azo-(4′-methyl-2′-nitrobenzene)
  3. Crystal structure of anhydrous zinc bromide
  4. P.B.C.-vector analysis by Fourier transform of morphology. On crystal growth of monoclinic potassium feldspars*
  5. Die Kristall- und Molekülstruktur des Tris(ethylendiamin)cadmium(II)-dibenzohydroxamathydrates, CdC20H38O5N8
  6. Die Kristall- und Molekülstruktur von 4-Dimethylaminopyridin C7H10N2
  7. Structure refinement of scolecite by neutron diffraction
  8. The crystal and molecular structure of [4]peristylanedione, C12H12O2
  9. Experimental difference densities of hexacyanobenzene at 120 K. Refinement of electron density distributions with charge-cloud models
  10. Die Kristallstruktur von Na4CaSi3O9 und dessen strukturelle Beziehungen zu K4SrGe3O9 und Ca3Al2O6
  11. Die Kristallstruktur von Ba2Ni(N3)6 · 3H2O
  12. X-ray studies on protoenstatite
  13. Crystal structure of molybdenum hexacarbonyl
  14. Ungewöhnliche lineare, oligomere Anionen [GanSe2n + 2](n + 4) − (n = 2,4,6) in festen Selenogallaten des Cäsiums
  15. Seltenerdaluminate SEAl11O18, SEMgAl11O19 und SELi0,5Al11,519
  16. The crystal structure of Cs0.35Al0.35Si2.65O6, a cesium-aluminosilicate with the bikitaite framework
  17. Crystal structure of 2-oxo-5-(exo)-6-(endo)-bis(phenylsulfonyl)-7,8-benzobicyclo [2.2.2] oct-7-ene
  18. Crystal structure of a fourteen-layered cadmium iodide polytype
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