Home Morphology and space group of hexaantipyrine perchlorate complexes of Mg++, Ca++ and Zn++, and pentaantipyrine perchlorate of Cu++
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Morphology and space group of hexaantipyrine perchlorate complexes of Mg++, Ca++ and Zn++, and pentaantipyrine perchlorate of Cu++

Published/Copyright: July 28, 2010
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Abstract

Morphology and x-ray study of hexaantipyrine perchlorate complexes of Mg++, Ca++ and Zn++ show that they are isomorphous, crystallizing in the space group P[unk] with one molecule in the unit cell. A similar study shows that copper pentaantipyrine perchlorate crystallizes with a tetramolecular unit cell, space group P21/a. The cell dimensions are:

Mg(C11H12ON2)6(ClO4)2: a = 14.06, c = 9.76 Å

Ca(C11H12ON2)6(ClO4)2: a = 14.33, c = 9.78 Å

Zn(C11H12ON2)6(ClO4)2: a = 14.14, c = 9.61 Å

Cu(C11H12ON2)5(ClO4)2: a = 19.52, b = 16.27, c = 18.99 Å, β = 102°36′

Published Online: 2010-07-28
Published in Print: 1965-10
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