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Synthesis and characterization of uranium(VI) and thorium(IV) complexes with o-hydroxy N,N´-dimethylbenzylamine and o-carboxy N,N´-dimethylbenzylamine
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Samina Khan
Published/Copyright:
September 25, 2009
Summary
Complexes of uranium(VI) and thorium(IV) with o-hydroxy N,N´-dimethylbenzylamine and o-carboxy N,N´-dimethylbenzylamine have been synthesized and characterized by elemental analysis, IR and 1H-NMR techniques. The coordination of metal ions with the ligand and their structures were established. The chemical and spectral properties revealed that uranium(VI) complexes have square bipyramidal structure for coordination number 6, and hexagonal bipyramidal structure for coordination number 8, whereas thorium(IV) shows bicapped square antiprism structure for coordination number 10.
Published Online: 2009-9-25
Published in Print: 2004-8-1
© 2004 Oldenbourg Wissenschaftsverlag GmbH
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Articles in the same Issue
- Experimental studies and nuclear model calculations on (p, xn) and (p, pxn) reactions on 85Rb from their thresholds up to 100 MeV
- Theoretical treatment of the complexation of element 106, Sg, in HF solutions
- Extraction and separation of Am(III) and Sr(II) by N,N,N´,N´-tetraoctyl-3-oxapentanediamide (TODGA)
- Method for determining plutonium in air filters in detection of nuclear activities
- Advanced aqueous reprocessing in P&T strategies: Process demonstrations on genuine fuels and targets
- Uranium association with halophilic and non-halophilic bacteria and archaea
- Complex formation of uranium(VI) in periodate solutions
- Fluorescence and IR studies on the hydration state of lanthanides(III) and curium(III) in the complexes extracted with purified Cyanex301, Cyanex302 and Cyanex272
- Synthesis and characterization of uranium(VI) and thorium(IV) complexes with o-hydroxy N,N´-dimethylbenzylamine and o-carboxy N,N´-dimethylbenzylamine
- Ion exchange and chromatographic separation of cesium, strontium and europium from acidic streams using uranium antimonate
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