Determination of In and Ga in plutonium oxide matrix by ICP-AES after chemical separation
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Abstract
An analytical method was developed for the determination of indium and gallium in plutonium samples. A solvent extraction technique was employed by using 30% TBP in CCl4 for the quantitative separation of plutonium from the sample solution and subsequent determination by radial inductively coupled plasma atomic emission spectrometry (ICP-AES). The quantitative recovery of In and Ga in the separated samples was confirmed from radiometric/tracer studies. Recording of spectral profile at 303.396 nm for In and 403.298 nm for Ga has clearly indicated that the determination of Ga and In at lower concentrations will be affected by the presence of significant amounts of residual Pu in the aqueous phase due to spectral interference. These elements can be determined from ppm to % HNO3 and appropriate (100 mg and 1 g) sample size. The analytical range obtained for Ga and In was 0.1–1000 μg/mL and 0.05–500 μg/mL respectively by ICP-AES. Synthetic samples of plutonium containing indium and gallium in the range of 50–20000 ppm were analyzed.
© by Oldenbourg Wissenschaftsverlag, Trombay, Mumbai 400 085, Germany
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- Incorporation of iodate into uranyl borates and its implication for the immobilization of 129I in nuclear waste repositories
- Determination of In and Ga in plutonium oxide matrix by ICP-AES after chemical separation
- Sequential determination of free acidity and hydrazine in presence of hydrolysable ions
- Adsorption interaction of astatine species with quartz and gold surfaces
- Application of instrumental neutron activation analysis for the examination of oil pigments
Articles in the same Issue
- Investigation on the production and isolation of 149,150,151Tb from 12C irradiated natural praseodymium target
- Luminescence properties of uranium(VI) citrate and uranium(VI) oxalate species and their application in the determination of complex formation constants
- Bioaccumulation of U(VI) by Sulfolobus acidocaldarius under moderate acidic conditions
- Electrochemical studies of U(VI)/U(V) in saturated Na2CO3 solution at gold nanoparticles embedded CTA-modified electrode
- Spectroscopic monitoring of spent nuclear fuel reprocessing streams: an evaluation of spent fuel solutions via Raman, visible, and near-infrared spectroscopy
- Incorporation of iodate into uranyl borates and its implication for the immobilization of 129I in nuclear waste repositories
- Determination of In and Ga in plutonium oxide matrix by ICP-AES after chemical separation
- Sequential determination of free acidity and hydrazine in presence of hydrolysable ions
- Adsorption interaction of astatine species with quartz and gold surfaces
- Application of instrumental neutron activation analysis for the examination of oil pigments
