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Effect of humic acid on cesium sorption on silica colloids
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Sumit Kumar
Published/Copyright:
September 25, 2009
Summary
Effect of humic acid (HA) on the sorption behaviour of 137Cs on silica colloids has been studied by batch procedure over a pH range of 3-10 and at ionic strength of 0.05 M (NaClO4). The sorption of 137Cs on bare silica colloids was found to be negligible up to pH 7 above which it was found to increase sharply with pH. In the presence of HA significant enhancement in the sorption of 137Cs on silica colloids was observed at lower pH values with no effect at pH > 7. Zeta potential of the colloidal suspension of HA, silica and their binary mixture were also measured. Binary interaction between 137Cs and HA, and that between HA and silica were investigated in order to explain the observations in terms of linear additive model. The data obtained in the present work confirmed the role of non-additive factors in the ternary sorption system.
Received: 2005-9-5
Accepted: 2006-3-29
Published Online: 2009-9-25
Published in Print: 2006-6-1
© by Oldenbourg Wissenschaftsverlag, München
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Keywords for this article
137Cs;
Silica colloids;
Humic acid;
Zeta-potential;
Sorption;
Linear additive model
Articles in the same Issue
- Preface - Special Issue: NUCAR 2005
- Incomplete fusion mechanism in 16O + 93Nb reaction at 6 MeV/nucleon: Recoil range measurements
- Extraction of actinides using N, N, N′, N′-tetraoctyl diglycolamide (TODGA): a thermodynamic study
- Extraction of neptunium(IV) by a mixture of 3-phenyl-4-acetyl-5-isoxazolone and tri-n-octyl phosphine oxide
- Third phase formation in the extraction of Th(NO3)4 by tri-2-methyl butyl phosphate from nitric acid media
- Solvent extraction behaviour of some fission product elements with N,N-dihexyl octanamide and tri-n-butyl phosphate under simulated PUREX process conditions
- Transport of uranium from nitric acid solution by non-dispersive solvent extraction using a hollow fibre contactor
- Fixation of some major fission products in NaZr2P3O12 ceramic employing microwave heating
- Synthesis, characterization and structural refinement of polycrystalline uranium substituted zirconolite CaZr0.9U0.1Ti2O7
- Effect of glass composition on diffusion of cesium in borosilicate glass
- Studies on diffusional mobility and selectivity of I− ion in plasticized anion-exchange membrane using radiotracer
- BEHSA grafted polymer for selective extraction of U(VI), Th(IV) and La(III) from acidic matrices and environmental samples – a green process
- Studies on the dissolution behaviour of ThO2 and (U,Th)O2 by a solid state reaction method
- Studies on some divalent metal α-isosaccharinic acid complexes
- Effect of humic acid on cesium sorption on silica colloids
- Preparation and preliminary biological evaluation of a 177Lu labeled nitroimidazole derivative for possible use in targeted tumor therapy
