Article
Licensed
Unlicensed
Requires Authentication
The ionic radii of Rf4+, Db5+ and Sg6+
-
A. Bilewicz
Published/Copyright:
September 25, 2009
Commonly used calculations of ionic radii (IR) based on the correlation between IR and the maximum radial charge density (Rmax,np) give overestimated values for the heaviest elements. That is because the method does not take into account the significant splitting of outermost p orbitals into p1/2 and p3/2. Using 2j+1 weighted expectation orbital radii, (rnp), instead of Rmax,np, new values of IR for Rf4+, Db5+ and Sg6+ have been calculated. These IR values for coordination number 6 are equal to 74 (instead of 79) pm for Rf4+, 66 (instead of 74) pm for Db5+ and 63 (instead of 65) pm for Sg6+.
Published Online: 2009-9-25
Published in Print: 2000-12-1
© 2015 Oldenbourg Wissenschaftsverlag GmbH, Rosenheimer Str. 145, 81671 München
You are currently not able to access this content.
You are currently not able to access this content.
Articles in the same Issue
- Cross sections for the formation of long-lived radionuclides 10Be, 26Al and 36Cl in 14.6 MeV neutron induced reactions determined via accelerator mass spectrometry (AMS)
- The ionic radii of Rf4+, Db5+ and Sg6+
- On-line gas chromatographic studies of Rf, Zr, and Hf bromides
- Effects of pH and uranium concentration on the removal of uranium from drinking water by ion exchange
- Complexation of thorium(IV) with desmethyldesferrithiocin
- Partitioning of minor actinides from HLLW using the DIAMEX process. Part 1 - Demonstration of extraction performances and hydraulic behaviour of the solvent in a continuous process
- Partitioning of minor actinides from HLLW using the DIAMEX process. Part 2 - ´´Hot´´ continuous counter-current experiment
- On-line gas-phase separation of short-lived bromine nuclides from precursor selenium
- Simulation of zeolite fixed bed columns used for treatment of liquid radioactive wastes
- Thermodynamics of strontium extraction using substituted crown ethers in mixtures of aliphatic alcohols
Articles in the same Issue
- Cross sections for the formation of long-lived radionuclides 10Be, 26Al and 36Cl in 14.6 MeV neutron induced reactions determined via accelerator mass spectrometry (AMS)
- The ionic radii of Rf4+, Db5+ and Sg6+
- On-line gas chromatographic studies of Rf, Zr, and Hf bromides
- Effects of pH and uranium concentration on the removal of uranium from drinking water by ion exchange
- Complexation of thorium(IV) with desmethyldesferrithiocin
- Partitioning of minor actinides from HLLW using the DIAMEX process. Part 1 - Demonstration of extraction performances and hydraulic behaviour of the solvent in a continuous process
- Partitioning of minor actinides from HLLW using the DIAMEX process. Part 2 - ´´Hot´´ continuous counter-current experiment
- On-line gas-phase separation of short-lived bromine nuclides from precursor selenium
- Simulation of zeolite fixed bed columns used for treatment of liquid radioactive wastes
- Thermodynamics of strontium extraction using substituted crown ethers in mixtures of aliphatic alcohols
