Determination by Neutron Activation of Gallium and Germanium in Iron Meteorites
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John T. Wasson
and Jerome Kimberlin
Summary
A procedure is given for the simultaneous determination by neutron activation of gallium and germanium in iron meteorites or other similar materials. Germanium is separated from interfering activities by solvent extraction from 8 Ν HCl into carbon tetrachloride followed by distillation as GeCl4. The chemical yield is determined colorimetrically using phenylfluorone. Gallium is separated by repeated solvent extactions into isopropyl ether, and the yield is determined by flame photometry. About 12 man hours are necessary to process six to eight samples, not including the time necessary to reduce the counting data. The detection limits for a thermal-neutron flux of 1012 cm-2 sec-1 are about 0.02 ppm germanium and 0.0001 ppm gallium.
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- Paper Electrophoresis of Protactinium in Sulphuric Acid Medium
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Articles in the same Issue
- Kinetics of the Isotopic Exchange between 1-Iodo-2,4-Dinitronaphthalene and Iodides in Acetone
- Über den 36Cl- und 82Br- Isotopenaustausch in festen Co- und Rh-dihalobis-(äthylendiamin)- halogeniden und den Einfluß von Röntgen- und γ-Strahlen
- Austauschadsorption von Kationen an TiO2 · aq
- Preparation of Sources for Alpha Spectrometry
- Gleichzeitige Bestimmung von 3H und 14C im Proportionalzählrohr
- Distribution of Radioactive Selenium between the Modifications of Selenium in Neutron-Irradiated Red Crystalline Selenium
- A New Nuclide: 52Ti
- On the Szilard-Chalmers Recoil of 60Co and 60mCo in [Co(NH3)6] (NO3)3 and trans- [Co en2 (NO2)2] NO3
- Chemical Effects of Isomeric Transition and (n, γ)-Activation of Bromine Atoms in n-Propyl Bromide
- Reactions of Energetic Carbon Atoms in Methylamine
- Influence of Electron-Accepting and Donating Ambient Atmospheres on the Thermal Annealing of Recoil Damage in Cobalt Chelates-bis-Salicylaldehyde-Triethylenetetramine Co(ni) Chloride, Hydrate
- The Extraction of Molybdenum into Acetylacetone and its Use in the Analysis of Fission Products
- Carboxylierung von Formiat unter der Strahlenwirkung von Radon
- Determination by Neutron Activation of Gallium and Germanium in Iron Meteorites
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- Paper Electrophoresis of Protactinium in Sulphuric Acid Medium
- Extraction of Protactinium by Long Chain Amines from Hydrochloric Acid Solutions
- Effect of Temperature on Rare Earth Separations on Cation Resin Columns with Lactate
- Fluorure double de protactinium et d’argent
- Chemische Reaktionen der Kernrückstoßatome im Bromopentamminrhodium (III)-nitrat und Chloropentamminiridium(III)-chlorid
- The Existence of Curium(VI)