Abstract
A novel aggregation induced emission (AIE) active anthracene based dihydroquinazolinone derivative (probe 1) has been synthesized and characterized by means of spectroscopic methods. The photophysical properties of this probe have been investigated in solvents of different polarity display that fluorescence states are of intramolecular charge transfer (ICT) character. Probe 1 show clear AIE behavior in water/THF mixture on reaching water fraction 95%. The AIE behavior of probe 1 have been exploited for the detection of metal ions in aqueous solution which reveals high selectivity and sensitivity towards Cu2+ ions by colorimetrically and function as a chemosensor in a remarkable turn-off fluorescence manner. Further, the experimental results were investigated by computational means by optimizing the ground state geometries of probe 1 and probe 1-Cu complex using density functional theory (DFT) at B3LYP/6-31G∗∗ and B3LYP/6-31G∗∗(LANL2DZ) levels of theory. Intra-molecular charge transfer was observed in probe 1 while ligand to metal charge transfer (LMCT) for probe 1-Cu complex.
Acknowledgement
The authors extend their appreciation to the Deanship of Scientific Research at King Khalid University for funding this work through Research Group Project under grant number (R.G.P.1/15/38).
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©2019 Walter de Gruyter GmbH, Berlin/Boston
Articles in the same Issue
- Frontmatter
- Anthracene Based AIE Active Probe for Colorimetric and Fluorimetric Detection of Cu2+ Ions
- Influence of Carrier Gas Pressure on the Physical Properties of CdO Thin Films
- The Role of Non-Ionic Surfactants in Solubilization and Delivery of Sparingly Soluble Drug Naproxen Sodium (NS): A Case Study
- Synthesis, Characterization and Corrosion Inhibition of N′-Phenylbenzohydrazide Derivative Metal Complexes: Experimental and Quantum Chemical Studies
- Molecular Interaction of Hemorrheologic Agent, Pentoxifylline with Bovine Serum Albumin: An Approach to Investigate the Drug Protein Interaction Using multispectroscopic, Voltammetry and Molecular Modelling Techniques
- Synthesis and Characterization of ZnO Nanorods as an Adsorbent for Cr(VI) Sequestration
- Adsorption of Methylene Blue Onto Acacia Modesta Carbon: Kinetic and Thermodynamic Study
- Identify the Active Phase of Fe–CN Composites for Oxidation Removal of Rhodamine B with H2O2
- Green Synthesis of Ag–NiO and Investigation of its Catalytic Activity for Degradation of Rhodamine B Dye in Aqueous Medium
Articles in the same Issue
- Frontmatter
- Anthracene Based AIE Active Probe for Colorimetric and Fluorimetric Detection of Cu2+ Ions
- Influence of Carrier Gas Pressure on the Physical Properties of CdO Thin Films
- The Role of Non-Ionic Surfactants in Solubilization and Delivery of Sparingly Soluble Drug Naproxen Sodium (NS): A Case Study
- Synthesis, Characterization and Corrosion Inhibition of N′-Phenylbenzohydrazide Derivative Metal Complexes: Experimental and Quantum Chemical Studies
- Molecular Interaction of Hemorrheologic Agent, Pentoxifylline with Bovine Serum Albumin: An Approach to Investigate the Drug Protein Interaction Using multispectroscopic, Voltammetry and Molecular Modelling Techniques
- Synthesis and Characterization of ZnO Nanorods as an Adsorbent for Cr(VI) Sequestration
- Adsorption of Methylene Blue Onto Acacia Modesta Carbon: Kinetic and Thermodynamic Study
- Identify the Active Phase of Fe–CN Composites for Oxidation Removal of Rhodamine B with H2O2
- Green Synthesis of Ag–NiO and Investigation of its Catalytic Activity for Degradation of Rhodamine B Dye in Aqueous Medium