Home Physical Sciences Fabrication of γ-MnO2-Ce Pillared Montmorillonite for Low Temperature NH3-SCR
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Fabrication of γ-MnO2-Ce Pillared Montmorillonite for Low Temperature NH3-SCR

  • Xiaoyan Huang , Aijuan Xie EMAIL logo , Xingmeng Zhou , Jianwen Xia , Shiping Luo EMAIL logo , Chao Yao and Xiazhang Li
Published/Copyright: February 6, 2018

Abstract

A series of γ-MnO2-Ce/MMT catalyst materials synthesized by homogeneous precipitation method was investigated for the selective catalytic reduction (SCR) of NOx with NH3. X-ray diffraction and specific surface areas were utilized for micro structure and layer spacing investigation. And NH3-TPD, Pyridoxine IR, H2-TPR and XPS were used to investigate Brønsted acid and Lewis acid, redox properties, atomic concentrations and element chemical state for as-prepared catalysts. The results showed that the γ-MnO2-Ce/MMT had superior NOx conversion compared to the bulk particles, among which 6 wt.% γ-MnO2-Ce/MMT displayed the best deNOx of 95.3% for the low temperature selective catalytic reduction of NOx with NH3 (NH3-SCR) under the GHSV of 25,000 h−1, therefore it is a promising catalyst for low temperature NH3-SCR.

Acknowledgments

This work was financially supported by National Natural Science Foundation of China (51674043); Development Fund of Jiangsu Province (BE2016654); Social development Fund of Changzhou City (CE20165022); Key R and D Programs of Jiangsu Province (BE2015103).

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Received: 2017-10-30
Accepted: 2018-01-14
Published Online: 2018-02-06
Published in Print: 2018-11-27

©2018 Walter de Gruyter GmbH, Berlin/Boston

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