Counter-Ion Effect on the Thermodynamics of Cr(III) Exchange by Macroporous Amberlyst-15
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Abstract
In the present study, we have investigated the counter-ion effect on the thermodynamics of Cr(III) sorption by macroporous resin Amberlyst-15. The exchange reaction was studied as a function of concentration of Cr(III) and nature of counter-ions at different temperatures. It was observed that nature of counter-ions have a profound effect on the exchange of Cr(III) ions. The selectivity of Amberlyst-15 towards metal ion sorption follows the order univalent>divalent> trivalent forms. This trend can be associated to the electrostatic interaction of ions with the functional sites of the resin. The equilibrium pH values (pHeq) were observed to decrease with Cr3+/H+ exchange whereas an increase in pHeq was detected during the exchange of Cr3+/Li+, Cr3+/Na+, Cr3+/Ca2+ and Cr3+/Al3+. Different adsorption models such as Dubinin–Radushkevich (D–R) and Langmuir were employed to analyze the sorption data. The maximum exchange capacities (Xm ) and binding energy constants (Kb ) values were determined by using the Langmuir model. The values of both ΔHo and ΔSo were found positive inferring that the exchange process is endothermic accompanied by the dehydration of Cr(III) ions. The thermodynamic parameters revealed that the mechanism of Cr(III) sorption for all the counter ions is entropy driven ion exchange.
References
1. J. Y. Fang, T. H. Wu, C. H. Huang, P. W. Wang, C. C. Chen, Y. C. Wu, T. L. Pan, Clinic. Chimi. Acta 423 (2013) 23.10.1016/j.cca.2013.04.012Search in Google Scholar PubMed
2. S. I. Hughes, S. S. R. Dasary, A. K. Singh, Z. Glenn, H. Jamison, P. C. Ray, H. Yu, Sens. Actuat. B 178 (2013) 514.10.1016/j.snb.2012.12.003Search in Google Scholar PubMed PubMed Central
3. R. Frei, A. Polat, Precamb. Res. 224 (2013) 434.10.1016/j.precamres.2012.10.008Search in Google Scholar
4. S. Mustafa, K. H. Shah, A. Naeem, T. Ahmad, M. Waseem, Desalination 264 (2010) 108.10.1016/j.desal.2010.07.012Search in Google Scholar
5. S. K. Sahu, P. Meshram, B. D. Pandey, V. Kumar, T. R. Mankh, Hydrometallurgy 99 (2009) 170.10.1016/j.hydromet.2009.08.002Search in Google Scholar
6. S. Kocaoba, G. A. Akcin, Monatsh. Chem. 139 (2008) 873.10.1007/s00706-007-0845-5Search in Google Scholar
7. S. Mustafa, K. H. Shah, A. Naeem, M. Waseem, T. Ahmad, S. Khan, Water Air Soil Pollut. 217 (2011) 57.10.1007/s11270-010-0567-xSearch in Google Scholar
8. P. S. Dimick, A. Kney, J. Tavakoli, S. E. Mylon, D. A. Zhao, Sep. Sci. Technol. 43 (2008) 2343.10.1080/01496390802118921Search in Google Scholar
9. N. Viswanathan, S. Meenakshi, J. Hazard. Mater. 162 (2009) 920.10.1016/j.jhazmat.2008.05.118Search in Google Scholar PubMed
10. N. Viswanathan, S. Meenakshi, J. Colloid Interface Sci. 322 (2008) 375.10.1016/j.jcis.2008.03.007Search in Google Scholar PubMed
11. W. Shao, X. Li, Q. Cao, F. Luo, J. Li, Y. Du, Hydrometallurgy 91 (2008) 138.10.1016/j.hydromet.2008.01.005Search in Google Scholar
12. Y. Watanabe, K. Ohnaka, S. Fujita, M. Kishi, A. Yuchi, Anal. Chem. 83 (2011) 7480.10.1021/ac201692bSearch in Google Scholar PubMed
13. B. J. Teppen, D. M. Miller, Soil Sci. Soc. Am. J. 70 (2005) 31.10.2136/sssaj2004.0212Search in Google Scholar
14. F. Kanwal, M. Imran, L. Mitu, Z. Rashid, H. Razzaq, Q. Ain, E-J. Chem. 9 (2012) 621.10.1155/2012/857579Search in Google Scholar
15. S. A. Cavaco, S. Fernandes, C. M. M. Augusto, J. Quina, L. M. Gando-Ferreira, J. Hazard. Mater. 169 (2009) 516.10.1016/j.jhazmat.2009.03.129Search in Google Scholar PubMed
16. V. Sathyaselvabala, P. Panneerselvam, R. Arulmozhli, K. V. Thiruvengadaravi, N. Thinakaran, S. A. Sivanesan, Indian J. Sci. Technol. 2 (2009) 27.10.17485/ijst/2009/v2i11.5Search in Google Scholar
17. K. A. Krishnan, K. G. Sreejalekshmi, R. S. Baiju, Bioresour. Technol. 102 (2011) 10239.10.1016/j.biortech.2011.08.069Search in Google Scholar PubMed
18. M. E. Argun, S. Dursun, C. Ozdemir, M. Kartas, J. Hazard. Mater. 141 (2007) 77.10.1016/j.jhazmat.2006.06.095Search in Google Scholar PubMed
19. S. Marinovic, M. J. Ajdukovic, N. P. Jovic-Jovicic, T. M. Mudrinic, B. M. Nedic-Vasiljevic, P. T. Bankovic, A. D. Milutinovic-Nikolic, J. Serb. Chem. Soc. 82 (2017) 1.10.2298/JSC151222088BSearch in Google Scholar
20. A. E. Nemr, A. Khalid, O. Abdelwahab, A. Ei-sikaily, J. Hazard. Mater. 152 (2008) 263.10.1016/j.jhazmat.2007.06.091Search in Google Scholar PubMed
21. R. S. D. Toteja, B. L. Jangida, M. Sundaresan, B. Venkataramani, Langmuir 13 (1997) 2980.10.1021/la9607114Search in Google Scholar
22. S. K. Milonjic, J. Serb. Chem. Soc. 72 (2007) 1363.10.2298/JSC0712363MSearch in Google Scholar
23. S. S. Tahir, R. Naseem, Sep. Purif. Technol. 53 (2007) 312.10.1016/j.seppur.2006.08.008Search in Google Scholar
24. Y. Li, C. Liu, C. Chiou, J. Colloid. Interface Sci. 273 (2004) 95.10.1016/j.jcis.2003.12.051Search in Google Scholar PubMed
25. L. Tagami, O. A. A. dos Santos, E. F. S. Aguiar, P. A. Arroyo, M. A. S. D. de Barros, Maringa 23 (2001) 1351.Search in Google Scholar
26. R. S. D. Toteja, B. L. Jangida, M. Sundaresan, Indian J. Chem. 30 (1991) 322.Search in Google Scholar
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Articles in the same Issue
- Frontmatter
- Quenching of R6G Fluorescence by Gold Nanoparticles of Various Particle Geometries
- Electrochemical and Quantum Chemical Studies on the Corrosion Inhibition Potential of Camellia sinensis Leaves Extract for Carbon Steel in Produced Water
- Counter-Ion Effect on the Thermodynamics of Cr(III) Exchange by Macroporous Amberlyst-15
- Spectroscopic Properties of Yb3+-Doped Silicate Glasses
- Considerations about the Dependence of PEGylated ZnS Nanoparticles Properties on the Synthesis Method
- Reactive Wetting Controlled by Very Small Vertical Temperature Gradients in a Chemical Transport Mini Reactor
- Spectroscopic Investigations on New Organic NLO crystal – 2-amino-5-chloropyridinium-2,4-dinitrophenolate
- Intermolecular Interaction for Binary Mixtures of Propylene Carbonate with Acetonitrile, Dimethyl Carbonate, Diethyl Carbonate at Different Temperatures: Density and Viscosity
