Influence of Chemical Structure and Temperature on Oxygen Reduction Reaction and Transport in Ionic Liquids
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Abstract
The ORR mechanism is studied in the context of metal-air batteries in three ionic liquids, 1-butyl-1-methylpyrrolidinium trifluoromethanesulfonate ([Py1,4]TfO), 1-ethyl-3-methylimidazolium trifluoromethanesulfonate ([EMIm]TfO) and 1-butyl-2,3-dimethylimidazolium bis(trifluoromethylsulfonyl)imide ([BDMIm]Tf2N). An electrochemical scheme combining four electrochemical techniques (CA, CV at macro-disk electrode, linear sweep voltammetry at rotating disk electrode (LSV at RDE) and CV at microelectrode (CV at ME)) is developed to perform fast determination of oxygen parameters (concentration c* and diffusion coefficient D) of electrolyte at various conditions. The electrochemical study has revealed the influence of acidity of ionic liquid to the reversibility of the O2/O2˙− redox reaction. The influence of temperature (up to 100°C) on the mechanism change of ORR as well as the changes of c* and D in three ionic liquids have been examined using the developed electrochemical method. The result has shown that the T-dependency of c* is much less prominent than that of D.
Acknowledgments
This study was funded by the Federal Ministry Education and Research through the collaborative project AKUZIL (BMBF 03x4630C (G.W.) and BMBF 03x4630A (F.E.)).
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©2017 Walter de Gruyter GmbH, Berlin/Boston
Articles in the same Issue
- Frontmatter
- Influence of Chemical Structure and Temperature on Oxygen Reduction Reaction and Transport in Ionic Liquids
- Entropy-Controlled Cu(II)-Catalyzed Oxidation of N-Acetyl-L-Cysteine by Methylene Blue in Acidic Medium
- Probing Inclusion Complex Formation of Amantadine Hydrochloride with 18-Crown-6 in Methanol by Physicochemical Approach
- Fine Tuning the Optoelectronic Properties of Triphenylamine Based Donor Molecules for Organic Solar Cells
- Corrosion and Corrosion Inhibition of Aluminum Alloys A5052 and A5754 in Sulfuric Acid Solutions by Some Inorganic Inhibitors
- Microstructure and Corrosion Behavior of Electrodeposited NiCo, NiZn and NiCu Nanocrystalline Coatings in Alkaline Solution
- Corrosion Control of Cu-10Al-10Ni and Cu-10Al-10Zn Alloys in Seawater Environment by Some Ethoxylated Tolyltriazole Derivatives
Articles in the same Issue
- Frontmatter
- Influence of Chemical Structure and Temperature on Oxygen Reduction Reaction and Transport in Ionic Liquids
- Entropy-Controlled Cu(II)-Catalyzed Oxidation of N-Acetyl-L-Cysteine by Methylene Blue in Acidic Medium
- Probing Inclusion Complex Formation of Amantadine Hydrochloride with 18-Crown-6 in Methanol by Physicochemical Approach
- Fine Tuning the Optoelectronic Properties of Triphenylamine Based Donor Molecules for Organic Solar Cells
- Corrosion and Corrosion Inhibition of Aluminum Alloys A5052 and A5754 in Sulfuric Acid Solutions by Some Inorganic Inhibitors
- Microstructure and Corrosion Behavior of Electrodeposited NiCo, NiZn and NiCu Nanocrystalline Coatings in Alkaline Solution
- Corrosion Control of Cu-10Al-10Ni and Cu-10Al-10Zn Alloys in Seawater Environment by Some Ethoxylated Tolyltriazole Derivatives
