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Electrodeposition of Alloys; Application of the Markov Chain Model to Intermetallic Compounds
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February 14, 2014
Abstract
Recently a Markov chain model has been proposed to predict the composition of alloys as a function of the electrolyte composition. The essential parameters of this model are selectivity constants, describing the selectivity of the growth centers, the kink site positions, for the ions of the metal components in the electrolyte.
In this paper application of the simple model to deposition of intermetallic compounds will be discussed. The Markov chain model can be successfully applied to the formation of the intermetallic compound NiSn. Whereas the model can describe well the deposition of Ni rich Zn-Ni alloys at low current densities, it fails at high current densities with anomalous alloy composition.
Received: 2013-10-18
Accepted: 2013-1-22
Published Online: 2014-2-14
Published in Print: 2014-3-28
©2014 Walter de Gruyter Berlin/Boston
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Articles in the same Issue
- Frontmatter
- Preface
- Thomas Wolff
- Application of NIR-Photopolymers in the Graphic Industry: From Physical Chemistry to Lithographic Applications
- Investigation of Molecular Solvents and Ionic Liquids with a Dual Probe
- A Versatile Approach for a Variety of Amphiphilic Nanoparticles: Semiconductor – Plasmonic – Magnetic
- Fluorescent Nanocrystals for Biomedical Applications
- The Influence of Sodium Dodecyl Sulfate on the Photoionization of the Ruthenium(tris)bipyridine Dication
- Application of Photochemistry in Synthesis of Smart Nanocomposite Hydrogels
- Stereoselective Di-pi-Methane Rearrangement of a BINOL-Substituted Dibenzobarrelene Derivative
- Photoexcitation in Dimers of Coumarin and 6-Alkylcoumarins
- Thermoresponsive Core-Shell Microgels. Synthesis and Characterisation
- Electrodeposition of Alloys; Application of the Markov Chain Model to Intermetallic Compounds
- Surface Characterization of Electron Irradiated Polymer Brushes
- A Mechanistic Study of Photoinduced Electron Transfer from Triplet Erythrosin to Various Quinones Using Time Resolved Absorption and ESR-CIDEP Measurements
