Oscillatory Oxidation of Malonic Acid by Bromate 3. CO2 and BrO3--Titration

L. Bornmann; H. Busse; B. Hess

doi:10.1515/znc-1973-9-1007

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Oscillatory Oxidation of Malonic Acid by Bromate 3. CO₂ and BrO₃^--Titration

L. Bornmann , H. Busse and B. Hess

Published/Copyright: June 2, 2014

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From the journal Zeitschrift für Naturforschung C Volume 28 Issue 9-10

Abstract

The reaction of malonic acid and bromate in the presence of catalytic amounts of cerious ion under oscillating conditions in sulphuric acid was investigated. After two hours reaction time 26 mM bromate were consumed and 42 mM CO₂ produced. No formic acid was detected. Furthermore, ¹⁴C-tracer experiments suggest that malonic acid is first brominated and subsequently decarboxylated.

: Oscillation; malonic acid; bromate; oxidation; reaction pathway

Received: 1973-6-18

Published Online: 2014-6-2

Published in Print: 1973-10-1

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https://doi.org/10.1515/znc-1973-9-1007

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