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Synthesis, Crystal Structure and Thermal Properties of Silver(I) Bromide Ethylenediamine Coordination Polymers

  • Christian Näther EMAIL logo and Andreas Beck
Published/Copyright: June 2, 2014
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Zeitschrift für Naturforschung B
From the journal Zeitschrift für Naturforschung B Volume 59 Issue 9

Reaction of silver(I) bromide with ethylenediamine (en) leads to the formation of the 1:1 compound poly[AgBr(μ2-en-N,N’)] (I). In the crystal structure the silver atoms of AgBr dimers are connected to two bridging bromine atoms and two nitrogen atoms of different en ligands. The dimers are thus connected by the ligands into layers via μ-N,N’ coordination. In the 2:1 coordination polymer poly[(AgBr)2(μ2-en-N,N’)] (II) a three-dimensional AgBr substructure occur which consists of helical AgBr chains that are connected via peripheral Ag-Br contacts into a three-dimensional network that contains large channels. The en ligands are situated in these channels bridging the Ag atoms. From solution this compound cannot be obtained as a pure phase, since compound I is always formed as the major phase. On heating the 1:1 compound I in a thermobalance the sample mass decreases slowly and several mass steps are observed, which are not fully resolved. If the reaction is stopped at 230°C, pure AgBr has formed. At 115°C only traces of compound II are found. The major phase consists of an as yet unidentified ligand poor compound.

: Keywords: Silver(I) Bromide; Ethylenediamine; Coordination Polymers; Crystal Structures; Thermal Properties
Received: 2004-7-7
Published Online: 2014-6-2
Published in Print: 2004-9-1

© 1946 – 2014: Verlag der Zeitschrift für Naturforschung

Articles in the same Issue

  1. Antiferromagnetic Ordering in GdRhIn5
  2. Crystal Structure and Thermal Behaviour of Er2(SeO4)3 · 8H2O
  3. Synthesis and Crystal Structure of a New Oxysulfide Gd6+xTi4 –xS10 – yO6+y (where x ~ 0.04 and y ~ 0.27)
  4. On the Silicides EuIr2Si2 and Lu5Si3
  5. From Yellow to Black: New Semiconducting Ba Chalcogeno-Germanates
  6. Synthesis and Crystal Structure of the Tetra-nickel Substituted [Ni4(H2O)2(AsW9O34)2]10- Polyoxoanion
  7. Quaternäre Strontium-Kupfer(I)-Lanthanoid(III)-Selenide mit Cer und Praseodym: SrCuCeSe3 und SrCuPrSe3, ein ungleiches Geschwisterpaar / Quaternary Strontium Copper(I) Lanthanoid(III) Selenides with Cerium and Praseodymium: SrCuCeSe3 and SrCuPrSe3, Unequal Brother and Sister
  8. Synthesis, Crystal Structure and Thermal Properties of Silver(I) Bromide Ethylenediamine Coordination Polymers
  9. Pt3Ga: Thermodynamics and Nonstoichiometry
  10. Low Dimensional Materials: Syntheses, Structures, and Optical Properties of Rb2CuTaS4, Rb2CuTaSe4, RbCu2TaSe4, K3Ag3Ta2Se8, and Rb3AgTa2Se12
  11. Chirale Erkennung bei Tris(diimin)-Metallkomplexen, 10. Vergleich der intermolekularen Wechselwirkungs- und Packungsmuster in der Reihe [Cr(bpy)3]n+(PF6)n (n = 0 – 3) / Chiral Recognition among Tris(diimine)-metal Complexes, 10. Comparison of Intermolecular Interactions and Packing Patterns in the Series [Cr(bpy)3]n+(PF6)n (n = 0–3)
  12. “Weak” OH···πHydrogen Bonds in the Structures of Two Phenols
  13. Phase Transitions and Distortion of [BiCl6]3– Octahedra in (C3H5NH3)3[BiCl6] – DSC and Single-Crystal X-Ray Diffraction Studies
  14. Crystal and Molecular Structure of [(η5-C5H4SiMe3)2LuCl]2: A Precursor for the Production of Lu2O3 Films
  15. Syntheses and Characterization of Two New Lead(II) Acetate Complexes, Pb(L)(CH3COO)2, L = 2,2':6',2''-Terpyridine (tpy) and 2,4,6-Tris(2-pyridyl)- 1,3,5-Triazine (trz), Crystal Structure of Pb(tpy)(CH3COO)2
  16. Carbazolylsilane: Synthese und Kristallstrukturen / Carbazolylsilanes: Synthesis and Crystal Structures
  17. The Pd(II) Complex of a N,N’-Diallylbenzimidazol-2-ylidene Ligand
  18. Reduction of 1-Hydroxyimino-1,2,3,4-tetrahydrocarbazoles by Metal and Baker’s Yeast – Syntheses of Aminocarbazole Derivatives
  19. Direct Conversion of an ortho-Allylphenol into a Chlorosulfonyl-3-methyl-1,2-benzoxathiin 2,2-Dioxide
  20. A New Triterpenoid Saponin and Two Neolignans from Ligularia veitchiana
  21. Two New Tirucallane Triterpenes with Six-Membered Hemiacetal from Amoora dasyclada
  22. Crystal Structure of N-3-Pyridinyl-methanesulfonamide and trans-Diiodobis(N-3-pyridinyl-methanesulfonamide)platinum(II)
https://doi.org/10.1515/znb-2004-0908

Articles in the same Issue

  1. Antiferromagnetic Ordering in GdRhIn5
  2. Crystal Structure and Thermal Behaviour of Er2(SeO4)3 · 8H2O
  3. Synthesis and Crystal Structure of a New Oxysulfide Gd6+xTi4 –xS10 – yO6+y (where x ~ 0.04 and y ~ 0.27)
  4. On the Silicides EuIr2Si2 and Lu5Si3
  5. From Yellow to Black: New Semiconducting Ba Chalcogeno-Germanates
  6. Synthesis and Crystal Structure of the Tetra-nickel Substituted [Ni4(H2O)2(AsW9O34)2]10- Polyoxoanion
  7. Quaternäre Strontium-Kupfer(I)-Lanthanoid(III)-Selenide mit Cer und Praseodym: SrCuCeSe3 und SrCuPrSe3, ein ungleiches Geschwisterpaar / Quaternary Strontium Copper(I) Lanthanoid(III) Selenides with Cerium and Praseodymium: SrCuCeSe3 and SrCuPrSe3, Unequal Brother and Sister
  8. Synthesis, Crystal Structure and Thermal Properties of Silver(I) Bromide Ethylenediamine Coordination Polymers
  9. Pt3Ga: Thermodynamics and Nonstoichiometry
  10. Low Dimensional Materials: Syntheses, Structures, and Optical Properties of Rb2CuTaS4, Rb2CuTaSe4, RbCu2TaSe4, K3Ag3Ta2Se8, and Rb3AgTa2Se12
  11. Chirale Erkennung bei Tris(diimin)-Metallkomplexen, 10. Vergleich der intermolekularen Wechselwirkungs- und Packungsmuster in der Reihe [Cr(bpy)3]n+(PF6)n (n = 0 – 3) / Chiral Recognition among Tris(diimine)-metal Complexes, 10. Comparison of Intermolecular Interactions and Packing Patterns in the Series [Cr(bpy)3]n+(PF6)n (n = 0–3)
  12. “Weak” OH···πHydrogen Bonds in the Structures of Two Phenols
  13. Phase Transitions and Distortion of [BiCl6]3– Octahedra in (C3H5NH3)3[BiCl6] – DSC and Single-Crystal X-Ray Diffraction Studies
  14. Crystal and Molecular Structure of [(η5-C5H4SiMe3)2LuCl]2: A Precursor for the Production of Lu2O3 Films
  15. Syntheses and Characterization of Two New Lead(II) Acetate Complexes, Pb(L)(CH3COO)2, L = 2,2':6',2''-Terpyridine (tpy) and 2,4,6-Tris(2-pyridyl)- 1,3,5-Triazine (trz), Crystal Structure of Pb(tpy)(CH3COO)2
  16. Carbazolylsilane: Synthese und Kristallstrukturen / Carbazolylsilanes: Synthesis and Crystal Structures
  17. The Pd(II) Complex of a N,N’-Diallylbenzimidazol-2-ylidene Ligand
  18. Reduction of 1-Hydroxyimino-1,2,3,4-tetrahydrocarbazoles by Metal and Baker’s Yeast – Syntheses of Aminocarbazole Derivatives
  19. Direct Conversion of an ortho-Allylphenol into a Chlorosulfonyl-3-methyl-1,2-benzoxathiin 2,2-Dioxide
  20. A New Triterpenoid Saponin and Two Neolignans from Ligularia veitchiana
  21. Two New Tirucallane Triterpenes with Six-Membered Hemiacetal from Amoora dasyclada
  22. Crystal Structure of N-3-Pyridinyl-methanesulfonamide and trans-Diiodobis(N-3-pyridinyl-methanesulfonamide)platinum(II)
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