A polycrystalline sample of tetragonal GdRhIn5 (HoCoGa5 type, space group P4/mmm) was obtained by induction melting of the elements in a glassy carbon crucible in a water-cooled sample chamber and subsequent annealing at 670 K. X-ray powder data yielded the cell parameters a = 460.65(7), c = 743.52(12) pm. The magnetic and electronic properties of GdRhIn5 have been studied by magnetic susceptibility, electrical resistivity, and 155Gd Mössbauer spectroscopic measurements. Antiferromagnetic ordering is detected at 41.0(2) K. The results are discussed using a simple molecular field approximation.
Received: 2004-5-17
Published Online: 2014-6-2
Published in Print: 2004-9-1
© 1946 – 2014: Verlag der Zeitschrift für Naturforschung
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Articles in the same Issue
- Antiferromagnetic Ordering in GdRhIn5
- Crystal Structure and Thermal Behaviour of Er2(SeO4)3 · 8H2O
- Synthesis and Crystal Structure of a New Oxysulfide Gd6+xTi4 –xS10 – yO6+y (where x ~ 0.04 and y ~ 0.27)
- On the Silicides EuIr2Si2 and Lu5Si3
- From Yellow to Black: New Semiconducting Ba Chalcogeno-Germanates
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- Quaternäre Strontium-Kupfer(I)-Lanthanoid(III)-Selenide mit Cer und Praseodym: SrCuCeSe3 und SrCuPrSe3, ein ungleiches Geschwisterpaar / Quaternary Strontium Copper(I) Lanthanoid(III) Selenides with Cerium and Praseodymium: SrCuCeSe3 and SrCuPrSe3, Unequal Brother and Sister
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- Pt3Ga: Thermodynamics and Nonstoichiometry
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Articles in the same Issue
- Antiferromagnetic Ordering in GdRhIn5
- Crystal Structure and Thermal Behaviour of Er2(SeO4)3 · 8H2O
- Synthesis and Crystal Structure of a New Oxysulfide Gd6+xTi4 –xS10 – yO6+y (where x ~ 0.04 and y ~ 0.27)
- On the Silicides EuIr2Si2 and Lu5Si3
- From Yellow to Black: New Semiconducting Ba Chalcogeno-Germanates
- Synthesis and Crystal Structure of the Tetra-nickel Substituted [Ni4(H2O)2(AsW9O34)2]10- Polyoxoanion
- Quaternäre Strontium-Kupfer(I)-Lanthanoid(III)-Selenide mit Cer und Praseodym: SrCuCeSe3 und SrCuPrSe3, ein ungleiches Geschwisterpaar / Quaternary Strontium Copper(I) Lanthanoid(III) Selenides with Cerium and Praseodymium: SrCuCeSe3 and SrCuPrSe3, Unequal Brother and Sister
- Synthesis, Crystal Structure and Thermal Properties of Silver(I) Bromide Ethylenediamine Coordination Polymers
- Pt3Ga: Thermodynamics and Nonstoichiometry
- Low Dimensional Materials: Syntheses, Structures, and Optical Properties of Rb2CuTaS4, Rb2CuTaSe4, RbCu2TaSe4, K3Ag3Ta2Se8, and Rb3AgTa2Se12
- Chirale Erkennung bei Tris(diimin)-Metallkomplexen, 10. Vergleich der intermolekularen Wechselwirkungs- und Packungsmuster in der Reihe [Cr(bpy)3]n+(PF6)n (n = 0 – 3) / Chiral Recognition among Tris(diimine)-metal Complexes, 10. Comparison of Intermolecular Interactions and Packing Patterns in the Series [Cr(bpy)3]n+(PF6)n (n = 0–3)
- “Weak” OH···πHydrogen Bonds in the Structures of Two Phenols
- Phase Transitions and Distortion of [BiCl6]3– Octahedra in (C3H5NH3)3[BiCl6] – DSC and Single-Crystal X-Ray Diffraction Studies
- Crystal and Molecular Structure of [(η5-C5H4SiMe3)2LuCl]2: A Precursor for the Production of Lu2O3 Films
- Syntheses and Characterization of Two New Lead(II) Acetate Complexes, Pb(L)(CH3COO)2, L = 2,2':6',2''-Terpyridine (tpy) and 2,4,6-Tris(2-pyridyl)- 1,3,5-Triazine (trz), Crystal Structure of Pb(tpy)(CH3COO)2
- Carbazolylsilane: Synthese und Kristallstrukturen / Carbazolylsilanes: Synthesis and Crystal Structures
- The Pd(II) Complex of a N,N’-Diallylbenzimidazol-2-ylidene Ligand
- Reduction of 1-Hydroxyimino-1,2,3,4-tetrahydrocarbazoles by Metal and Baker’s Yeast – Syntheses of Aminocarbazole Derivatives
- Direct Conversion of an ortho-Allylphenol into a Chlorosulfonyl-3-methyl-1,2-benzoxathiin 2,2-Dioxide
- A New Triterpenoid Saponin and Two Neolignans from Ligularia veitchiana
- Two New Tirucallane Triterpenes with Six-Membered Hemiacetal from Amoora dasyclada
- Crystal Structure of N-3-Pyridinyl-methanesulfonamide and trans-Diiodobis(N-3-pyridinyl-methanesulfonamide)platinum(II)