Home Physical Sciences Synthesis of Some New Electron π-Donors Containing Methoxy Groups
Article
Licensed
Unlicensed Requires Authentication

Synthesis of Some New Electron π-Donors Containing Methoxy Groups

  • EMAIL logo , , and
Published/Copyright: June 2, 2014
Become an author with De Gruyter Brill
Author Information Explore this Subject
Zeitschrift für Naturforschung B
From the journal Zeitschrift für Naturforschung B Volume 59 Issue 7

The synthesis of some new electron π-donors carrying four or two methoxy groups is described. The precursor 5,6-dimethoxy-5,6-dihydro[1,3]dithiolo[4,5-b] [1,4]dithiin- 2-thione was synthesized and by coupling reactions the symmetrical 5,6,5’,6’-tetramethoxy-5,6,5’,6’-tetrahydro- [2,2’]bi[[1,3]dithiolo[4,5-b][1,4]dithiinylidene] and unsymmetrical 5,6-dimethoxy-5,6,5’,6’-tetrahydro-[2,2’]bi[[1,3]- dithiolo[4,5-[1,4]dithiinylidene], 2-(5,6-dimethoxy-5,6-dihydro-[ 1,3]dithiolo[4,5-b][1,4]dithiin-2-ylidene)-5,6-dihydro-[ 1,3]dithiolo[4,5-b][1,4]-dioxine and (5,6-dimethoxy- 5,6-dihydro-[1,3]dithiolo[4,5-b][1,4]dithiin-2-ylidene)-6,7- dihydro-5H-[1,3]dithiolo[4,5-b][1,4]dithiepine donors were prepared. They have been characterized spectroscopically and their redox potentials determined using cyclic voltammetry.

Keywords: : π-Donors; Tetrathiafulvalenes; Cyclic Voltammetry
Received: 2004-1-30
Published Online: 2014-6-2
Published in Print: 2004-7-1

© 1946 – 2014: Verlag der Zeitschrift für Naturforschung

Articles in the same Issue

  1. Zu den Zustandssystemen Bi2Ch3/BiX3 und den ternären Phasen auf diesen Schnitten (Ch= S, Se,Te;X= Cl, Br, I). II: Bismutselenidhalogenide Bi2Se3/BiX3 und Bismuttelluridhalogenide Bi2Te3/BiX3 / On the Pseudobinary Systems Bi2Ch3/BiX3 and the Ternary Phases in these Systems (Ch = S, Se, Te; X = Cl, Br, I). II: Bismutselenidhalides Bi2Se3/BiX3 and Bismuttelluridhalides Bi2Te3/BiX3
  2. Polysulfonylamine, CLXX [1]. Wasserstoffbrücken in kristallinen Onium-dimesylamiden: Drei Strukturen mit NH2-substituierten 1,3,5-Triazinium-Kationen (einschließlich Melaminium) / Polysulfonylamines, CLXX [1]. Hydrogen Bonding in Crystalline Onium Dimesylamides: Three Structures Involving NH2-Substituted 1,3,5-Triazinium Cations (Including Melaminium)
  3. Intermolecular Interactions in the Crystal of a New Nickel(II)-cobalt(II)- nickel(II) Trinuclear Complex Containing a Macrocyclic Complex Ligand
  4. Effect of Temperature on the Purity of Product in the Preparation of 1-Butyl-3-methylimidazolium-Based Ionic Liquids
  5. A5Fe3O6] (A = Rb, Cs), Cs[FeO2] und Cs8[Fe2O7]: Neue Oxoferrate der schweren Alkalimetalle / A5Fe3O6] (A = Rb, Cs), Cs[FeO2] and Cs8[Fe2O7]: New Oxoferrates of the Heavy Alkaline Metals
  6. Synthesen und Strukturen von 1,3,5-Trihalogeno-1,3,5-triboracyclohexan-Derivaten / Syntheses and Structures of 1,3,5-Trihalogeno-1,3,5-triboracyclohexane Derivatives
  7. The Organogallium Subhalide R2Ga2I2 as Starting Compound for the Generation of a Transition Metal Gallium Complex – Synthesis of Fe2(CO)6(μ-GaR)3 [R = C(SiMe3)3]
  8. Secondary Interactions in Gold(I) Complexes with Thione Ligands. 2. Three Ionic Camphorsulfonates with Z’ = 2 [1]
  9. Synthese von 6-O-Benzylguanin und seinen Anker-Konjugaten / Synthesis of 6-O-Benzyl Guanine and its Conjugations with Linkers
  10. peri-Interactions in Naphthalenes, 12 [1]. The Significance of Linear and T-Shaped Arrangements in peri-Substituted Naphthalenes
  11. Synthesis of a New Cyclic Peptide, Pseudostellarin G
  12. Triterpene Saponins from Knautia integrifolia var. bidens
  13. Chromenes and Prenylated Benzoic Acid Derivatives from the Liverwort Pedinophyllum interruptum
  14. Hydroxy-Methoxybenzoic Methyl Esters: Synthesis and Antifeedant Activity on the Pine Weevil, Hylobius abietis
  15. Photochemical Reactions of Re(CO)5Br with Ph2P(S)(CH2)nP(S)Ph2 (n = 1,2,3)
  16. Synthesis of Some New Electron π-Donors Containing Methoxy Groups
https://doi.org/10.1515/znb-2004-0716
Keywords for this article
π-Donors; Tetrathiafulvalenes; Cyclic Voltammetry

Articles in the same Issue

  1. Zu den Zustandssystemen Bi2Ch3/BiX3 und den ternären Phasen auf diesen Schnitten (Ch= S, Se,Te;X= Cl, Br, I). II: Bismutselenidhalogenide Bi2Se3/BiX3 und Bismuttelluridhalogenide Bi2Te3/BiX3 / On the Pseudobinary Systems Bi2Ch3/BiX3 and the Ternary Phases in these Systems (Ch = S, Se, Te; X = Cl, Br, I). II: Bismutselenidhalides Bi2Se3/BiX3 and Bismuttelluridhalides Bi2Te3/BiX3
  2. Polysulfonylamine, CLXX [1]. Wasserstoffbrücken in kristallinen Onium-dimesylamiden: Drei Strukturen mit NH2-substituierten 1,3,5-Triazinium-Kationen (einschließlich Melaminium) / Polysulfonylamines, CLXX [1]. Hydrogen Bonding in Crystalline Onium Dimesylamides: Three Structures Involving NH2-Substituted 1,3,5-Triazinium Cations (Including Melaminium)
  3. Intermolecular Interactions in the Crystal of a New Nickel(II)-cobalt(II)- nickel(II) Trinuclear Complex Containing a Macrocyclic Complex Ligand
  4. Effect of Temperature on the Purity of Product in the Preparation of 1-Butyl-3-methylimidazolium-Based Ionic Liquids
  5. A5Fe3O6] (A = Rb, Cs), Cs[FeO2] und Cs8[Fe2O7]: Neue Oxoferrate der schweren Alkalimetalle / A5Fe3O6] (A = Rb, Cs), Cs[FeO2] and Cs8[Fe2O7]: New Oxoferrates of the Heavy Alkaline Metals
  6. Synthesen und Strukturen von 1,3,5-Trihalogeno-1,3,5-triboracyclohexan-Derivaten / Syntheses and Structures of 1,3,5-Trihalogeno-1,3,5-triboracyclohexane Derivatives
  7. The Organogallium Subhalide R2Ga2I2 as Starting Compound for the Generation of a Transition Metal Gallium Complex – Synthesis of Fe2(CO)6(μ-GaR)3 [R = C(SiMe3)3]
  8. Secondary Interactions in Gold(I) Complexes with Thione Ligands. 2. Three Ionic Camphorsulfonates with Z’ = 2 [1]
  9. Synthese von 6-O-Benzylguanin und seinen Anker-Konjugaten / Synthesis of 6-O-Benzyl Guanine and its Conjugations with Linkers
  10. peri-Interactions in Naphthalenes, 12 [1]. The Significance of Linear and T-Shaped Arrangements in peri-Substituted Naphthalenes
  11. Synthesis of a New Cyclic Peptide, Pseudostellarin G
  12. Triterpene Saponins from Knautia integrifolia var. bidens
  13. Chromenes and Prenylated Benzoic Acid Derivatives from the Liverwort Pedinophyllum interruptum
  14. Hydroxy-Methoxybenzoic Methyl Esters: Synthesis and Antifeedant Activity on the Pine Weevil, Hylobius abietis
  15. Photochemical Reactions of Re(CO)5Br with Ph2P(S)(CH2)nP(S)Ph2 (n = 1,2,3)
  16. Synthesis of Some New Electron π-Donors Containing Methoxy Groups
Sign up now to receive a 20% welcome discount
Institutional Access
How does access work?
Winner of the OpenAthens UX Award 2026
Winner of the OpenAthens UX Award 2026
Have an idea on how to improve our website?
Please write us.
© 2026 De Gruyter Brill
Downloaded on 28.3.2026 from https://www.degruyterbrill.com/document/doi/10.1515/znb-2004-0716/html
Scroll to top button