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Dimethyl-, Disilyl- and Digermylsulfide: Different Intermolecular Contacts in the Solid State

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Published/Copyright: June 2, 2014
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Zeitschrift für Naturforschung B
From the journal Zeitschrift für Naturforschung B Volume 59 Issue 6

The compounds (H3C)2S, (H3Si)2S and (H3Ge)2S have been crystallised in situ on a diffractometer and their crystal structures determined by low-temperature X-ray diffraction. The molecules are present as monomers in the crystals. The aggregation of the molecules through secondary intermolecular contacts in the crystal is different: (H3C)2S is weakly associated into dimers by S···S contacts, whereas (H3Si)2S and (H3Ge)2S form Si···S and Ge···S contacts in an ice-analogous aggregation motif. Important geometry parameters are (H3C)2S: C-S 1.794(av) Å , C-S-C 99.2(1)°; (H3Si)2S: Si- S 2.143(1) Å , Si-S-Si 98.4°; (H3Ge)2S Ge-S 2.223(2) and 2.230(2) Å , Ge-S-Ge 98.2(1)◦.

Keywords: Silicon; Germanium; Sulphur; Crystal Structure; Secondary Bonds
Received: 2004-3-22
Published Online: 2014-6-2
Published in Print: 2004-6-1

© 1946 – 2014: Verlag der Zeitschrift für Naturforschung

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https://doi.org/10.1515/znb-2004-0603
Keywords for this article
Silicon; Germanium; Sulphur; Crystal Structure; Secondary Bonds

Articles in the same Issue

  1. Neue Erdalkalimetall-reiche binäre Indide: Ca2In, Sr28In11 und Sr5In3 / New Alkaline Earth Rich Binary Indides: Ca2In, Sr28In11 und Sr5In3
  2. Syntheses and Crystal Structures of the Two New Polychalcogenides [Mn(C6H14N2)3]Se6 and [Mn(C6H14N2)3]2[C6H16N2](TeSe2)2Se
  3. Dimethyl-, Disilyl- and Digermylsulfide: Different Intermolecular Contacts in the Solid State
  4. Neue 3-Imidazolin-1-oxyl-Radikale mit pyridyl und chinolylhaltigen 4-(2-Aminovinyl)-Substituenten und Palladium, Platin und Ruthenium-Komplexe mit diesen 4-Amino-1-azadien-Liganden / New 3-Imidazoline-1-oxyl Radicals with Pyridyl and Quinolyl Containing 4-(2-Aminovinyl) Substituents and Palladium, Platinum and Ruthenium Complexes of these 4-Amino-1-aza-diene Ligands
  5. Square Planar Complexes of Cu(II) with an N2O Donor Set of a New Schiff Base Ligand: Synthesis and Structural Aspects
  6. Polysulfonylamine, CLXIX. Intermolekulare Wechselwirkungen in kristallinen Di(organosulfonyl)aminen. Teil 1. Di(4-brombenzolsulfonyl)amin: Zwei Konformationspolymorphe und Strukturverwandtschaft eines Polymorphs mit dem entsprechenden 2,4-Dimethylpyridinium-Salz / Polysulfonylamines, CLXIX. Intermolecular Interactions in Crystalline Di(organosulfonyl)- amines. Part 1. Di(4-bromobenzenesulfonyl)amine: Two Conformational Polymorphs and the Structural Relationship of one Polymorph to the Corresponding 2,4-Dimethylpyridinium Salt
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  12. Reduction of Carbonyl Compounds with NaBH4 under Ultrasound Irradiation and Aprotic Condition
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