Startseite Crystal Structures of the Supramolecular Aggregates of the Methyl and Chloro Substituted Gallanes MexGaCl3-x
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Crystal Structures of the Supramolecular Aggregates of the Methyl and Chloro Substituted Gallanes MexGaCl3-x

  • Christian Lustig und Norbert W Mitzel EMAIL logo
Veröffentlicht/Copyright: 2. Juni 2014
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Zeitschrift für Naturforschung B
Aus der Zeitschrift Zeitschrift für Naturforschung B Band 59 Heft 2

The crystal structures of the complete series of compounds of the general formula MexGaCl3−x have been determined. New polymorphs of GaCl3 and MeGaCl2 were found. All chloro compounds MexGaCl3−x (x = 0, 1, 2) are dimers with Ga2Cl2 four-membered rings. (GaCl3)2 and (MeGaCl2)2 are aggregated into layers with the same aggregation motif (each molecule connected to four neighbouring molecules), (Me2GaCl)2 is associated in a ladder-like structure (each molecule connected to two neighbouring molecules), GaMe3 forms weakly Ga···C bound pseudo-tetramers aggregated into layers by further Ga···C contacts (each molecule has two shorter Ga···C’ and C···Ga’ and two weaker Ga···C’ and C···Ga’ contacts).

Keywords : Gallium; Crystal Structure; Supramolecular Chemistry; Aggregation
Received: 2003-12-15
Published Online: 2014-6-2
Published in Print: 2004-2-1

© 1946 – 2014: Verlag der Zeitschrift für Naturforschung

Artikel in diesem Heft

  1. Zur Reaktion von 2,3-Dihydro-1,3-diisopropy1-4,5-imidazol-2-yliden mit Bromderivaten der Meldrumsäure [1, 2] / On the Reaction of 2,3-Dihydro-1,3-diisopropy1-4,5-dimethylimidazol-2-ylidene with Bromine Derivatives of Meldrum’s Acid [1, 2]
  2. Polyol Metal Complexes, 45 [1]. D-Glucopyranosides as Ligands in Nickel Complexes
  3. Crystal Structures of the Supramolecular Aggregates of the Methyl and Chloro Substituted Gallanes MexGaCl3-x
  4. DFT and G2MP2 Calculations of the N-N Bond Dissociation Enthalpies and Enthalpies of Formation of Hydrazine, Monomethylhydrazine and Symmetrical and Unsymmetrical Dimethylhydrazine
  5. Triethoxysilane, Tetraethoxysilane and Hexaethoxydisiloxane – Three Complementary Reagents for the Synthesis of Hydrogen-Rich Silylarenes
  6. Dimeric Methylzinc Bis(2-pyridylmethyl)amide – Synthesis, Molecular Structure and Reaction with Dimethylzinc
  7. Synthese und Struktur der Nitridokomplexe (Ph3Sb)2Cl3Os≡N-RhCl(COD), (Me2PhP)2(PhCN)Cl2Re≡N-RhCl2(C5Me5), [(Me2PhP)3(PhCN)ClRe≡N-OsCl2(CO)3][OsCl3(CO)3] und [(Me2PhP)3(PhCN)ClRe≡N-ReCl4-N≡ReCl(NCPh)(PMe2Ph)3][OsCl4(CO)2] / Synthesis and Structure of the Nitrido Complexes (Ph3Sb)2Cl3Os≡N-RhCl(COD), (Me2PhP)2(PhCN)Cl2Re≡N-RhCl2(C5Me5), [(Me2PhP)3(PhCN)ClRe≡N-OsCl2(CO)3][OsCl3(CO)3], and [(Me2PhP)3(PhCN)ClRe≡N-ReCl4-N≡ReCl(NCPh)(PMe2Ph)3][OsCl4(CO)2]
  8. Ternary Rare Earth Metal Silicides RE2RE’3Si4 with Orthorhombic Sm5Ge4 or Tetragonal Zr5Si4 Type Structure
  9. Synthesis and Structural Relationship of the Ternary Indides Sc3Ni2.10(5)In3.60(5), Sc3Ni2.14(2)In3.76(2), ScPd0.981(2)In and Sc3Rh1.594(9)In4
  10. Tris(2-isocyanocarbonsäureester)-Halbsandwich-Komplexe [(Aren)M(CNCHR1CO2R2)3]2+ (M = Ru, Rh, Ir) / Tris(2-isocyanocarboxylic Acid Ester) – Halfsandwich Complexes [(arene)M(CNCHR1CO2R2)3]2+ (M = Ru, Rh, Ir)
  11. Palladium(II) Complexes with Benzoxazol-2-ylidene Ligands: Crystal Structures of trans-Chloro(benzoxazol-2-ylidene)- bis(triphenylphosphine)palladium(II) Chloride and cis-Diiodo(benzoxazol-2-ylidene)(triphenylphosphine)palladium(II)
  12. High-Pressure Synthesis, Crystal Structure, and Properties of the New Orthorhombic Rare-Earth meta-Oxoborates RE(BO2)3 (RE = Dy – Lu)
  13. Four Isotypic Highly Coordinated Lanthanide Complexes of the Tripodal Ligand Bis[(2-pyridyl)methyl][(1-methylimidazol-2-yl)methyl]amine
  14. Carbamoyl and Thiocarbamoyl Derivatives of 3-Aminopropyl-dimethyl-phosphine Oxide
  15. The Crystal Structures of [N,N’-Bis(3-methoxysalicylidene)-1,3- diaminopropane]nickel(II) and -copper(II)
  16. Dialkoxy-Substituted, C1-Symmetric Metallocenes: Synthesis and Catalytic Behavior in the Propylene Polymerization Reaction
  17. Isolation and Structure of a New Ceramide from the Basidiomycete Hygrophorus eburnesus
  18. Pubesamides A, B, and C, Three New N-Benzoyltyramide Derivatives Isolated from Casimiroa pubescens
  19. RETRACTION NOTICE: Synthesis with Enaminones: Novel and Facile Synthesis of Indenopyrimidine, Indenopyridine, Fluorenone, and Indenopyran Derivatives
https://doi.org/10.1515/znb-2004-0204
Schlagwörter für diesen Artikel
Gallium; Crystal Structure; Supramolecular Chemistry; Aggregation

Artikel in diesem Heft

  1. Zur Reaktion von 2,3-Dihydro-1,3-diisopropy1-4,5-imidazol-2-yliden mit Bromderivaten der Meldrumsäure [1, 2] / On the Reaction of 2,3-Dihydro-1,3-diisopropy1-4,5-dimethylimidazol-2-ylidene with Bromine Derivatives of Meldrum’s Acid [1, 2]
  2. Polyol Metal Complexes, 45 [1]. D-Glucopyranosides as Ligands in Nickel Complexes
  3. Crystal Structures of the Supramolecular Aggregates of the Methyl and Chloro Substituted Gallanes MexGaCl3-x
  4. DFT and G2MP2 Calculations of the N-N Bond Dissociation Enthalpies and Enthalpies of Formation of Hydrazine, Monomethylhydrazine and Symmetrical and Unsymmetrical Dimethylhydrazine
  5. Triethoxysilane, Tetraethoxysilane and Hexaethoxydisiloxane – Three Complementary Reagents for the Synthesis of Hydrogen-Rich Silylarenes
  6. Dimeric Methylzinc Bis(2-pyridylmethyl)amide – Synthesis, Molecular Structure and Reaction with Dimethylzinc
  7. Synthese und Struktur der Nitridokomplexe (Ph3Sb)2Cl3Os≡N-RhCl(COD), (Me2PhP)2(PhCN)Cl2Re≡N-RhCl2(C5Me5), [(Me2PhP)3(PhCN)ClRe≡N-OsCl2(CO)3][OsCl3(CO)3] und [(Me2PhP)3(PhCN)ClRe≡N-ReCl4-N≡ReCl(NCPh)(PMe2Ph)3][OsCl4(CO)2] / Synthesis and Structure of the Nitrido Complexes (Ph3Sb)2Cl3Os≡N-RhCl(COD), (Me2PhP)2(PhCN)Cl2Re≡N-RhCl2(C5Me5), [(Me2PhP)3(PhCN)ClRe≡N-OsCl2(CO)3][OsCl3(CO)3], and [(Me2PhP)3(PhCN)ClRe≡N-ReCl4-N≡ReCl(NCPh)(PMe2Ph)3][OsCl4(CO)2]
  8. Ternary Rare Earth Metal Silicides RE2RE’3Si4 with Orthorhombic Sm5Ge4 or Tetragonal Zr5Si4 Type Structure
  9. Synthesis and Structural Relationship of the Ternary Indides Sc3Ni2.10(5)In3.60(5), Sc3Ni2.14(2)In3.76(2), ScPd0.981(2)In and Sc3Rh1.594(9)In4
  10. Tris(2-isocyanocarbonsäureester)-Halbsandwich-Komplexe [(Aren)M(CNCHR1CO2R2)3]2+ (M = Ru, Rh, Ir) / Tris(2-isocyanocarboxylic Acid Ester) – Halfsandwich Complexes [(arene)M(CNCHR1CO2R2)3]2+ (M = Ru, Rh, Ir)
  11. Palladium(II) Complexes with Benzoxazol-2-ylidene Ligands: Crystal Structures of trans-Chloro(benzoxazol-2-ylidene)- bis(triphenylphosphine)palladium(II) Chloride and cis-Diiodo(benzoxazol-2-ylidene)(triphenylphosphine)palladium(II)
  12. High-Pressure Synthesis, Crystal Structure, and Properties of the New Orthorhombic Rare-Earth meta-Oxoborates RE(BO2)3 (RE = Dy – Lu)
  13. Four Isotypic Highly Coordinated Lanthanide Complexes of the Tripodal Ligand Bis[(2-pyridyl)methyl][(1-methylimidazol-2-yl)methyl]amine
  14. Carbamoyl and Thiocarbamoyl Derivatives of 3-Aminopropyl-dimethyl-phosphine Oxide
  15. The Crystal Structures of [N,N’-Bis(3-methoxysalicylidene)-1,3- diaminopropane]nickel(II) and -copper(II)
  16. Dialkoxy-Substituted, C1-Symmetric Metallocenes: Synthesis and Catalytic Behavior in the Propylene Polymerization Reaction
  17. Isolation and Structure of a New Ceramide from the Basidiomycete Hygrophorus eburnesus
  18. Pubesamides A, B, and C, Three New N-Benzoyltyramide Derivatives Isolated from Casimiroa pubescens
  19. RETRACTION NOTICE: Synthesis with Enaminones: Novel and Facile Synthesis of Indenopyrimidine, Indenopyridine, Fluorenone, and Indenopyran Derivatives
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